Author: Verónica Savignano

Anniversary of CAPES Materials Area. Part 2.

Posted on Thursday 27 de February de 2014

A little more than four months after the creation of CAPES Materials Area, with Professor Lívio Amaral as pro tempore coordinator, in 12 and 13 of June 2008, the first meeting of postgraduate programs of the new field took place in the headquarters of CAPES, Brasilia. Discussions basically involved the presentation of ten programs already linked to CAPES Materials Area (from UCS, UFC, UFPE, UFRGS, UFRN, UFSC, UNESP – Bauru, UNESP – Ilha Solteira, USP-Lorena and USP São Carlos), meetings with some of the directors from CAPES and the presentation of new programs (from FATEC, FEEVALE, UFMT and UFSCar- Sorocaba). Some programs linked to other areas in CAPES (from UFVSF, UFPR and UFS) have also been invited, to assess a possible change of area. At the end of the event, there was a discussion about creating what they called “the document of the Materials Area”.

This document was finalized in the second meeting of postgraduate programs, which took place in the 5th and 6th of March 2009 at Puc-Rio. At this time, the meeting was summoned by Professor Lívio Amaral, together with SBPMat, presided then by Professor Fernando Lázaro Freire Junior. Discussions included presentation of SBPMat and work teams about the creation of the document.

Professor Carlos Graeff, coordinator of the Materials Area at CAPES, lecturing at USP in November, 2013. Photo supplied by Carlos Graeff.

In April 2009, Professor Lívio Amaral left the coordination of the Materials Area to take over as Evaluation Director at CAPES. Regarding the actions performed during his coordination, which lasted a year and two months, Professor Amaral states that theytake this time to essentially identify the postgraduate programs in the field of Materials; from this, they try to consolidate the Materials Area and include it among the other CAPES areas, in a way that could be understood by the community”. On the other hand, Amaral regrets not being able to stimulate, neither in existing programs nor in new initiatives, “the imperious need to have much more research and human resources formation in Biomaterials”, subarea which, according to the Professor, is still very critical in the country. “All you have to do is go to a MRS meeting, either American or European, and it is easy to observe the increasing research in Biomaterials”, demonstrates Amaral.

On August 12th, 2009, CAPES president, Professor Jorge Guimarães, announced through Normative Regulation 097 that Professor Carlos Frederico de Oliveira Graeff had been assigned to fulfill the role of Materials Area coordinator until 2010, concluding the period of three years started by Lívio Amaral. Graeff still remains the coordinator until June 2014, being assigned for the role for three more years.

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APPENDIX 1: About CAPES Materials Area.

The main tasks of CAPES are: evaluate and promote creating of new postgraduate programs; evaluate existing programs applying grades; evaluate scholarships and other financial support requests for students and teaching staff and for scientific events organization. Besides, CAPES coordinators are the most important interface between academic community and CAPES.

The Materials Area at CAPES is composed by a coordinator and two deputy coordinators. The job of the second deputy coordinator has been recently created, around 2013, to follow up in more detail programs of professional masters. Besides, the Evaluation Direction at CAPES has one or more technicians that help in the coordinators with internal procedures and the interface of CAPES with the community.

Coordinators in the area are chosen by the president at CAPES, after consulting post-graduate programs and technical and scientific societies connected to the area.

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Professor Carlos Graeff, coordinator of the Materials Area at CAPES, lecturing at USP in November, 2013. Photo supplied by Carlos Graeff.

APPENDIX 2: Interview with Professor Carlos Graeff, CAPES Materials Area coordinator from 2009 to 2014.

SBPMat Bulletin: – Could you summarize the quantitative and qualitative evolution of postgraduate courses in Materals in Brazil, since the creation of CAPES Materials Area?

Carlos Graeff: – The area was created in 2008 with the adhesion of 10 programs. We are 29 today, that is, we have increased 290% in 6 years. This is quantitative date, but, most importantly, the area has diversified. It is a multidisciplinary area and with new programs, new frontiers of knowledge have been embraced with interfaces related to biological and medical fields, as well as agriculture, to name a few. Besides, another important feature of this evolution was the expansion of covered areas with postgraduate programs, especially in places with no high level education programs in the field, as the Central-west and Northeast Brazilian regions.

SBPMat Bulletin: – What were the main actions and facts  during your coordination?

Carlos Graeff: – The main mark of our administration was transparency. We had a series of meetings with coordinators and, as the area is still relatively small, we could make a serious of decisions collectively, mostly relating to the evaluation of postgraduate programs. Regarding new courses, we always tried to invite new members, specialists, to the evaluation committees, for a fair examination of requests.  This measure also brought improvement of the existing knowledge concerning CAPES role. A recurring issue is related to unawareness of CAPES work; when bringing a representative number of professors to the assessment processes, there is a tendency to strengthen the relationship between the scientific community and CAPES. I hope that this interview can contribute in that sense.

Besides working in this interface with post-graduate programs, I am a full member of Conselho Técnico-Científico da Educação Superior, where I led the work team with the topic “technical products”. There is an increasing demand for stronger interaction between academic society and society in general, that is, for applied research or technological development. In fact, creating the Materials and Biotechnology Areas at CAPES was basically inspired by this approximation. However, to evaluate programs that work with this interface there is a need for tools that might measure and qualify products such as patents, prototypes, etc. Therefore, it is essential that CAPES successful in assessing intellectual production well (in the case of Materials, basically articles in scientific journals) can be extended to technical production. The discussions have been very productive and we hope that soon they will reflect both on the CAPES evaluation process.

SBPMat Bulletin: – Can you comment on the “Qualis” (CAPES system for evaluation of scientific journals) of Materials Area?

Carlos Graeff: – One of the debates in the area was how to generate a Qualis that would attend multidisciplinary. Qualis is a broadly discussed tool in academic community in general, but especially in more dynamic areas of knowledge, considering its role is one of the most important: to qualify main intellectual products generated by postgraduate programs, scientific papers. The most used method uses impact factor. However, impact factor reflects the size and dynamics of different academic communities. For instance, when we compare average impact factors in Engineering with those of Natural Sciences (Physics, Chemistry, and Biology), they are inferior. We do not want to discuss the reasons for this difference which is even more remarkable if, for instance, we enter the realm of humanities. But this difference exists and, therefore, we should take this into consideration in order to avoid distortions in the evaluation process of, for instance, postgraduate research with strong inclination to research in Materials Engineering against Materials Chemistry. Our proposal, therefore, separates journals in big groups: Materials Science, Materials Engineering and correlate areas. By doing this, we try to achieve fairness while comparing papers generated by groups of engineers or physicists that work with Materials. Obviously, our proposal needs some adjustment, but I believe we have taken a step further in this direction.

SBPMat Bulletin: – In your opinion, which are the challenges faced by the area in the next few years?

Carlos Graeff: – Brazil is going through an important time in industry where it suffers with increasingly stronger competition, due to a great opening of our market and the integration with global economy. An important path is the sophistication of our products and processes, and Materials area has a lot to contribute to a stronger and more competitive industry. Nanotechnology is increasingly more emphasized and there are expectations that it might generate a series of new products, which is a fundamental subject of Materials field. Therefore CAPES and SBPMat play an important part in this matter. Actions in this direction are being discussed both at CAPES and SBPMat. Besides great national issues, there is still a lot of room to grow in the area.  There are, for instance, the great and urgent challenges of creating a postgraduate program in the North Brazilian region, the only region with still no offer for Materials courses.

SBPMat Bulletin: – Feel free to add anything else.

Carlos Graeff: – I am honored with the generous invitation from Professor Livio Amaral to conduct the implementation of Materials Area at CAPES. I have learned a lot and I could follow changes that CAPES have been through in the last years, focusing in system improvement. We will soon have significant changes in the assessment process, among them, a new tool to collect and support evaluation called Sucupira Platform. This initiative has been taken with enthusiasm and skillfulness of Professors Amaral and Guimarães. So I would like to end thanking both of them.

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Featured paper: Luminescence measurements to identify defects in zinc oxide thin films.

Posted on Thursday 27 de February de 2014

The scientific paper by members of the Brazilian community in Materials research featured this month is:

Fernando Stavale, Niklas Nilius, and Hans-Joachim Freund. STM Luminescence Spectroscopy of Intrinsic Defects in ZnO(0001̅) Thin Films. J. Phys. Chem. Lett., 2013, 4 (22), pp 3972–3976. DOI: 10.1021/jz401823c.

Luminescence measurements to identify defects in zinc oxide thin films.

Zinc oxide (ZnO) is a very common material in everyday life. It can be found in screws, sunscreen, catalyzer for methanol synthesis and sophisticated optoelectronic devices, such as computer flexible screens, to name just a few. However, in order to enable some promising applications, such as transistors and new devices, it is important to control electrical properties of this semiconductor material, which are related to specific defects in its atomic structure.

Within this context, three scientists from institutions in Germany and Brazil identified specific defects in zinc oxide films through an original approach, taking advantage of luminescence capability (emission of light not resulting from heat) of zinc oxide. Researchers prepared zinc oxide thin films with different types and amounts of specific defects. Systematically, scientists measured luminescence of each film and, thus, they managed to relate peaks on the measurements with various types of defects in crystal nets. The results of this study were published in periodical The Journal of Physical Chemistry Letters (JPCL).

“In this study, we developed extremely high quality thin films of zinc oxide and we altered the amount of specific defects using thermal desorption, photo-desorption induced by laser and reduction by treatment in hydrogen controlled environment” – says Fernando Stavale, researcher for Centro Brasileiro de Pesquisas Físicas (CBPF), who signs the article as main author.

Characterization technique

In order to make the experiments, scientists used a scanning tunneling microscope (STM) in ultra high vacuum with a few peculiarities designed to generate luminescence, collect the emitted photons and obtain the measurements (spectrum) of luminescence. With this configuration, the STM is known as  photon-scanning tunneling microscope. According to Stavale, one of the main scientists in the field of development and application of this technique is Professor Niklas Nilius, correspondent author of the JPCL paper, with whom Stavale has directly worked for three years during his post-doctoral research at  Fritz-Haber Max-Planck Society, in Berlin, specifically at Physico-chemical Department led by Professor Hans-Joachim Freund, last author of the JPCL article. “The photon-scanning tunneling microscope has been employed in unprecedented manner to characterize metallic acids at the department directed by Professor Freund” – says Stavale. “The technique is still underused in Brazil and it is an essential part of the projects I develop with my research team at CBPF, situated in Rio de Janeiro” – he adds.

One of the most important features in photon-scanning tunneling microscopy is the use of electrons which are emitted by the tip of the STM to excite samples and, in the case of zinc oxide, to generate the desired luminescence. This phenomenon of emitting light generated by the impact of electrons over the material is called cathodoluminescence.

Experiment scheme in which the tip of the tunneling microscope can be observed, in the photo, exciting the zinc oxide film. The graph shows a spectrum of the oxide cathodoluminescence. At the back , the tunneling microscopy image of a zinc oxide film, with density of 20 layers (~5 nm) shows monoatomic steps and specific defects in the film’s surface. Vacancies of oxygen and zinc, specific defects, correspond to the areas indicated by arrows. The dark areas with hexagonal shape correspond to the areas where the film is noncontinuous, with depth of up to eight atomic layers.

This systematic work allowed scientists to infer that some peaks of luminescence of zinc oxide are due to defects such as vacancies of oxygen and zinc (dots in the lattice containing “vacancies”, instead of the expected oxygen and zinc atoms). “These specific defects are related to electrical properties often observed in zinc oxide, known as n-type doping” – Stavale adds.

The context of the work

The experiments of the JPCL article were conceived and conducted by Brazilian national Fernando Stavale in 2012, during his last year of post-doctoratal research with the group led by Professor Nilius, at Fritz-Haber of Max-Planck Society. Stavale joined the group in 2010 with financial support from Humboldt Institute in Germany. “For three years we have investigated for the first time the role of several dopants, such as chromium, europium and lithium in zinc and magnesium oxides, combined with ultra-thin films, raised in ultra-high vacuum with tunneling microscopy and local cathodoluminescence” – says Stavale about his post-doctoral studies.

The interpretation of results and the JPCL article redaction were performed in 2013 when Fernando Stavale became a CBPF researcher and Niklas Nilius became a Professor at University of Oldenburg, Germany.

Interview with Professor Jose Arana Varela, honored with the Bridge Building Award from American Ceramic Society.

Posted on Thursday 27 de February de 2014
Professor Arana Varela (to the left) receiving the award. Photo by American Ceramic Society.

On the last January 27th, in Daytona Beach (Florida, United States), during the 38th edition of International Conference and Exposition on Advanced Ceramics and Composites, the Bridge Building Award of the American Ceramic Society was given to a Brazilian for the first time, Professor José AranaVarela, president of our SBPMat from 2010 to 2011. The honor annually distinguishes people from outside the United States who have notably contributed to the field of engineering ceramics.

Graduated in Physics from University of São Paulo in 1968, Arana Varela also has a Master’s Degree in Physics for the Instituto Tecnológico de Aeronáutica (ITA), becoming a Master in 1975. He took his PhD from 1977 to 1981 at University of Washington (United States), conducting research in the field of ceramic materials.

Currently, Arana Varela is Full Professor at Universidade Estadual Paulista Julio de Mesquita Filho (UNESP) and president-director of the executive board of São Paulo Research Foundation (Fapesp), as well as member of the council for competitivity and innovation at São Paulo Federation of Industries (FIESP). Professor Arana Varela is also full member of the Brazilian Academy of Sciences (ABC), among other associations, and member of the editorial body for the journals Ceramics International, Science of Sintering, Cerâmica and Materials Research. Besides, he coordinates the innovation division at the Multidisciplinary Center for Development of Ceramic Materials.

His scientific papers gather over 6,500 citations. In the last 13 years, he has been the author of more than 500 articles, published in international journals. Up to this moment, he has advised and co-advised assignments for over 30 masters and over 40 doctoral theses.

Throughout his career, he has received more than 20 awards from organizations such as American Ceramic Society, Sociedad Española de Cerámica y Vidrio, CNPq, Associação Brasileira de Metalurgia e Materiais and Associação Brasileira de Cerâmica.

A brief interview with the researcher can be seen below:

SBPMat Bulletin: – Tell us a little bit about your story: which were the opportunities and choices that led you to become a researcher in the field of ceramic materials?

José Arana Varela: – Our choice of being a scientist in mateirals started during the Master’s at ITA, in  1972. During this period (in 1975), I met Professor O. J. Whittemore from the University of Washington, Seattle, during his visit to Universidade Federal de São Carlos for a year. As my master’s research was related to a physico-chemical view of thermal decomposition of talcum, which is a ceramic material, Professor Whittemore became interested in it and made some remarks regarding ceramic processing (his specialty). Thence the invitation for a doctorate in Seattle (from 1977 to 1981).

SBPMat Bulletin: – In your own analysis, which were your main contributions to the science and technology of materials? Specifically, can you comment on your main contributions to the field of engineering ceramics, the focus of Bridge Building Award?

José Arana Varela: — As the main theme of our doctoral theses was related to sintering models, we performed a simple study about variable effects, such as water vapor and heating rate in densification and microstructure of magnesium oxide ceramic. We created a model to take into account the structural rearrangement in sintering process.

Considering the evolution on application of ceramic materials in Microelectronics, due to functionality of these materials, we started the Electroceramic line in the 90’s. The functionality initially chosen was resistivity variation with electrical field (ceramic varistors) due to its application, mostly with lightning rods and electric circuits protectors. After understanding and contributing with varistor’s system based on zinc oxide (ZnO), we proposed to change the system considering another semi-conductor (stannous oxide). In this case, we developed throughout the years a stannous oxide varistor with properties that were much superior to traditional ZnO varistors.

Other contributions are related to development of thin ceramic films with Perovskite structure, with the purpose of optimizing their dielectric, piezoelectric and ferroelectric properties by using chemical deposition. We have advanced in the knowledge of chemical deposition, which we call polymeric precursors methods. One of the applications of these films are related to the manufacture of ferroelectric memories. With this, our students have worked in characterizing thin films with ferroelectric properties in some systems such as barium titanate, lead zirconate titanate, as well as strontium niobate and tantalate. A patent in ferroelectric memories, licensed to Panasonic, was proposed by a group led by Professor Carlos Paz de Araujo, at University of Colorado.

The latest contribution is related to sensors with nanometric structure, in collaboration with a group led by Professor Harry Tuller at MIT. Recent results were very promising and they showed great sensitivity in nanosensors based on stannous monoxide. It is important to point out that we have recently applied for patent regarding this study.

SBPMat Bulletin: – “Bridge building”, building bridges. Can you share with us a retrospective on the main bridges built throughout your career and the ones you would like to build?

José Arana Varela: — Our bridges have been built from the moment we finished our PhD at University of Washington. I continued to collaborate with Professor Whittemore for decade and I started other partnerships with Professor Gary Messing at Penn State University e then Professor Richard Bradt at University of Alabama.

Concurrently, we had joint projects in Europe with Professor João Baptista at Universidade de Aveiro, Portugal and with Doctor José Fernandez from Institute of Ceramics and Glass in Madrid, related to the subject of Electroceramics. We began to collaborate with groups in Bordeaux, France (Professor Marc Onillon), as well as André Perrin at University of Rennes. The collaborations proceeded with groups led by Professor Paolo Nanni at University of Genoa, concurrently with group led by Professor Danilo Suvorov at Josef Stephan Institute, in Slovenia and Professor Harry Tuller at MIT, in Boston.

SBPMat Bulletin: — Would you like to leave a message for our readers who are developing their academic or industry career as materials researchers?

José Arana Varela: — Science of Materials is fundamental to developing new useful technologies that will resolve society’s greatest problems. Great advancement in knowledge of ceramic materials, mostly their application in production of energy, communication, environmental control, etc., has been increasing in the past 20 years, mainly because of increased collaboration among researchers in different parts of the world. Science of Materials stopped being polarized between the United States and Europe (Germany, England and France) and it relies on contributions from other players in Asia and certainly Brazil. Fundamental knowledge of mass and charge transportation mechanisms, as well as structure of materials in nanometric scale, is essential to new developments and advances in technology.

 

New board of SBPMat directors and members of the council: investiture and first meeting.

Posted on Thursday 27 de February de 2014

On February 14th of this year, at 10 o’clock, the Brazilian Society of Materials Research (SPBMat) had an investiture ceremony for the Seventh Board of directors, for a two-year term beginning in January, 2014. Together with the Board of directors, four new full counselors and a deputy counselor were in role, whose term goes until 2018. The ceremony took place at Golden Park Hotel Viracopos, in the city of Campinas, in Sao Paulo. The new Board of directors and the new counselors were elected by vote at the end of 2013.

New Board of directors on the day of the investiture. From left to right, Rodrigo Bianchi, Marco Cremona, André Pasa, Ieda Garcia dos Santos, Julio Sambrano, Maria Aparecida Zaghete and Roberto Faria (president).

First meeting

The first meeting with the new Board of directors, together with the council occurred on the same day, at 2 p.m.

At the meeting, members of the board and council were appointed to take part in SBPMat’s commitee. For the Events Commitee, Professor Marco Cremona, Professor Iêda Maria Garcia dos Santos and Professor José Alberto Giacometti were assigned; for the SBPMat Bulletin Commitee, Professors Fernando Lázaro Freire Junior, André Avelino Pasa and José Antonio Eiras; and for University Chapters Commitee, Professors Rodrigo Fernando Bianchi, Antonio José Felix de Carvalho, Iêda Maria Garcia dos Santos, Maria Aparecida Zaghete and Waldemar Augusto de Almeida Macedo. As responsible for creating the document “Materials Science Impact” together with Institute of Physics, Professors Roberto Mendonça Faria, Marco Cremona and Julio Ricardo Sambrano were chosen. It is important to highlight that other SBPMat associates besides the initial members can be included.

During the meeting, scientific directors were assigned their duties.

See current members of the Board and Council and learn about our directors and their roles.

Concurso para professor adjunto na UFPE em Engenharia de Reabilitação.

Posted on Tuesday 18 de February de 2014

O Departamento de Engenharia Biomédica da UFPE está realizando concurso para professor adjunto, com regime de dedicação exclusiva para a área de Engenharia da Reabilitação. Solicitamos a ampla divulgação do mesmo.

INSCRIÇÕES: As inscrições ocorrerão no período de 12 de Fevereiro a 14 de Março de 2014, exceto sábados, domingos e feriados, para entrega da documentação exigida.

Edital de Condições Gerais: Edital Nº 05/2014,

http://www.ufpe.br/progepe/images/progepe/documentos/CCD/edital%2005%202014%20professor%20adjunto.pdf

Edital Complementar: Biomédica: Engenharia de Reabilitação

www.ufpe.br/progepe/images/progepe/documentos/CCD/edital%20complementar%20ctg%20eng%20biomedica%20reabilitacao.pdf

UFPE – Universidade Federal de Pernambuco (www.ufpe.br)

Research center studies material applied as ozone gas sensor (Text by CDMF and INCTMN)

Posted on Tuesday 18 de February de 2014

Developing multifunctional materials, that is, chemical compounds synthesized in labs, which may be applied in several areas, is a research field increasingly explored in the chemistry departments of universities around the world. The Center for the Development of Functional Materials (CDMF), located at Universidade Estadual Paulista (UNESP), jointly with researchers from Universidade de São Paulo (USP), Universidade Federal de São Carlos (UFSCar) and Instituto de Pesquisas Energéticas e Nucleares (IPEN) have developed an original study using the chemical compound silver tungstate (Ag2WO4) as a resistive sensor to detect small amounts of ozone gas, providing an alternative to environmental solutions.

Luis Fernando Silva, researcher at CDMF, under the supervision of Professor Elson Longo, has investigated the properties of silver tungstate as an ozone gas sensor. Ozone (O3) is an oxidant gas, used in many technological applications, such as the food industry, drinking water treatment, medicine, microelectronics cleaning processes, among others. “Ozone has been successfully used to disinfect effluents, allowing a more efficient drinking water treatment. However, when there are high amounts of this gas in the atmosphere, it becomes harmful, especially to human health, causing serious conditions as headaches, burning and stinging in the eyes, difficulties to breath and lung damages”, he said.

In 2013, researchers from CDMF identified a way to stimulate the growth of nanoparticles of silver in the silver tungstate compound itself. Thereby, the material developed a number of properties that may be used in different sectors, such as health, environment, and technology.

Encouraged by this breakthrough, the researchers studied silver tungstate as a resistive gas sensor. “The preliminary results qualified this compound as a great gas sensor. In one of our trials, we identified that silver tungstate displayed an excellent performance detecting ozone. That was the first time in which this compound was used as a resistive gas sensor”, explained the researcher. The obtained results were published on the journal Nanoscale, a renowned source on the subject.

Silva also explains that following this work, the main goal will be examining the sensibility of silver tungstate when detecting other gases, such as nitrogen dioxide (NO2), ammonia (NH3), ethanol (C2H6O), or even humidity. “These are parameters that enable the potential commercialization of this material”, he stated.

The initiative results from the interaction between CDMF and the INCTMN (National Institute of Science and Technology for Nanotechnology Materials).

Exposition to ozone gas

Ozone is a gas found in the higher layers of the atmosphere, acting as a filter against the solar ultraviolet radiation that comes down to Earth. The gas is not natural where living beings live, presenting a negative impact to health. It is formed by the reactions between gases created by combustions, as in vehicles, for example.

The World Health Organization (WHO) recommends avoiding the exposition to ozone gas above 120 ppb (parts per billion). Based on this date, the constant detection and measurement of the levels of ozone contained in the atmosphere or in certain environments remains indispensable.

SBPMat newsletter – first issue

Posted on Monday 3 de February de 2014

 

Brazilian Materials Research Society (SBPMat) newsletter

News update from Brazil for the Materials community

 

English version – First edition

Greetings, .

SBPMat’s news

XIII SBPMat meeting: symposia.

See the list of the symposia approved for this year’s meeting. Here.

Featured paper with Brazilian participation
Signed by 19 authors, the paper highlighted this month by our newsletter is about nitrogen-doped graphene nanoribbons, synthesized by CVD in one single process. In the article published in Advanced Functional Materials, the scientists show that nitrogen increases the semiconductor behavior and the chemical reactivity of the nanoribbons, expanding the possibilities of application in electronics, in addition to generate a particular morphology in its borders. A part of the work was carried out in the Federal University of the State of Pernambuco (UFPE).  Here.

History of Materials research in Brazil
Six years ago, CAPES (the government agency linked to the Brazilian Ministry of Education in charge of promoting high standards for post-graduate courses in Brazil) included “Materials” in its table of knowledge areas. Know more about this story in the article we have prepared, based on an interview with Professor Lívio Amaral, one of the men behind its creation. Here.

SBPMat’s community people

A former president of SBPMat, José Arana Varela, is the first Brazilian researcher to receive the Bridge Building Award from the American Ceramic Society. Here.

Reading recommendations
Science journalism stories based on papers published in journals with high impact factor.

  • Nanoparticle system that deliver several drugs against cancer into different parts of the cell (based on paper from Advanced Functional Materials). Here.
  • Nanoparticles detect tumors based on the amplification of signals from the microenvironment (based on paper from Nature Materials). Here.
  • Study led by a Brazilian scientist shows metamaterials that perform mathematical operations with electromagnetic waves (based on paper from Science). Here.
  • New technique integrates graphene with other materials, forming a two-dimensional seamless sheet (based on paper from Science). Here.

Books, presentations, multimedia material, etc.

  • Review of book “Nanotechnology for the Energy Challenge“. Here.
  • Review of book “Biopolymer Nanocomposites“. Here.

Innovation: in the market or nearly there.

  • Rubber made of dandelion for tires: multi-disciplinary study carried out by Fraunhofer Institute and the manufacturer Continental. Here.

Anniversaries.

  • 100 years after the discovery of X-ray crystallography, 2014 is the International Year of Crystallography. Here.

Upcoming events in the area.
  • VI Curso do Método Rietveld de Refinamento de Estrutura. Here.
  • 10º Encontro Brasileiro sobre Adsorção. Here.
  • 13th International Conference on Modern Materials and Technologies (CIMTEC 2014). Here.
  • 1st International Conference on Polyol Mediated Synthesis. Here.
  • 13th European Vacuum Conference + 7th European Topical Conference on Hard Coatings + 9th Iberian Vacuum Meeting. Here.
  • 19th International Conference on Ion Beam Modification of Materials. Here.
  • XIII Encontro da SBPMat. Here.
To suggest news, opportunities, events or reading recommendations items for inclusion in our newsletter, write to comunicacao@sbpmat.org.br.
Unsubscribe here.

 

CAPES’s Materials Area Anniversary. Part 1.

Posted on Thursday 30 de January de 2014

At the end of January, 2014, the Brazilian community of Materials research celebrates an anniversary: the Materials Area of CAPES reaches its sixth year of existence. CAPES is the government agency linked to the Brazilian Ministry of Education in charge of promoting high standards for post-graduate courses in Brazil.

In fact, it was on January 30th, 2008, that CAPES’s published a press release announcing the introduction of changes to its table of areas. Such table lists the areas of knowledge and it is used in the evaluations of the post-graduation programs in Brazil. The changes disclosed in such note included the insertion of the Materials Area, which up until then did not exist, and which from then on would be a part of the Multi-disciplinary greater area, which had been recently created.

One day prior to such disclosure, an official letter from CAPES’s Evaluation Office had been sent to all coordinators of post-graduation programs previously identified as possibly being grouped into the new area. The official letter informed that a recent meeting of CAPES’s Superior Board had approved the creation of the new Materials area of evaluation, and also that physicist Lívio Amaral, a professor from the UFRGS (Federal University of the State of Rio Grande do Sul) had been appointed as the pro-tempore coordinator. In addition, the official letter asked the coordinators who deemed it to be in the interest of their programs to become connected to the new area of evaluation, to inform CAPES of their decision.

Background

In September, 2012, professor Amaral had taken part in a meeting at the headquarters of CNPq (Brazilian Council for the Scientific and Technological Development) called by Professor Celso de Melo, who was a director in the council. The theme of the meeting was the Materials Science and Engineering area, and the Advisory Boards of such body. The other participants of the meeting were the professors Glória de Almeida Soares (from COPPE-UFRJ), Elson Longo (from UFSCar) and João Marcos Alcoforado Rebello (from COPPE-UFRJ).

A document signed by the participants of the meeting pointed some problems with the evaluation of research projects in the Materials Area. To sum it up, due to the fact that there was no Advisory Board for the Materials Area at that time, the projects and other requests pertaining to Materials Science or Engineering were often appraised with debatable parameters or sent from area to area until someone was found who could evaluate them, a situation which significantly increased the number of appeals received by the CNPq and the time to reply to the requesting researcher. To solve such issue, the document proposed initially the creation of a committee with representatives from the several areas of knowledge involving Materials and also that the scientific societies with any relation to Materials were to be called to the debate, to find a solution fully backed by the technical and scientific community.

“This matter of the inclusion of a Materials area in the government fostering agencies had been considered since the mid-90s”, Lívio Amaral states. “That occurred within the context of creation of a Brazilian Materials society, having the MRS as a reference, which ended up occurring in the early 00s. At the time, there was a lot of debate in several situations, such as in the Brazilian Meetings on Condensed Matter Physics of the Brazilian Physics Society”, he adds.

In parallel, professor Amaral had been following-up on that matter within CAPES, where he was the coordinator of the Physics and Astronomy Area. According to Amaral, by means of evaluations conducted every three years, it was possible to verify that several post-graduation programs, regardless of the names they had and by which of CAPES’s areas they were encompassed, were awarding master and doctorate degrees with intellectual production in Materials. “Since, in addition to being department coordinator, I also took part in CAPES’s Technical and Scientific Council, I had the opportunity to take that entire matter to debate in such Council”, the professor  comments.

At that time, Jorge Almeida Guimarães, who would become CAPES’s president in 2004, was the coordinator of the Biological Sciences II Area and, like professor Amaral, took part in the Technical and Scientific Council and was a professor in the UFRGS. “We discussed at length the need to create two new areas, the Materials and Biotechnology areas”, Lívio Amaral tells us.

In addition, Amaral recalls that another favorable coincidence then occurred. CAPES’s president at the time was Professor Abílio Afonso Baeta Neves, who had previously been the dean of post-graduation in UFRGS when the program of post-graduation in Materials Science had been submitted to the university, by initiative from professors of the Physics department, Amaral included, and of the Engineering and the Chemistry departments. “In summary, in that scenario, the discussion regarding new areas, inside and outside the Technical and Scientific Council, was very frequent due to such circumstances”, professor Amaral sums it up.

Meeting of CAPES’s Technical and Scientific Council, at the time of professor Abílio Baeta Neves’s presidency. At the table, the third one from the right is the president; the sixth, the one speaking, is professor Jorge Guimarães; the seventh is profesor Lívio Amaral. (Picture provided by Lívio Amaral)

The decision for the creation

According to Amaral, in July, 2007, CAPES held a meeting in Brasília, to consider the possible creation of a new area of knowledge, to be called “Materials”. Representatives from several post-graduation programs were invited, including professor Lívio, who was at the time the coordinator of UFRGS’s program.

The official letter-invitation sent by CAPES’s Evaluation Office contained: “The agency has been granted to such area the importance it deserves, considering the relevance of the creation of new materials for the current science and technology. CAPES’s Superior Council, in addition, has already authorized this Office to create the area at hand. For such decision, the meeting to be held in July 31st shall be decisive, for it will allow us to conclude if such innovative measure is in the interests of the programs – and of the Brazilian science and technologies. The new area would encompass all programs that – currently divided into different areas of knowledge – highlight this theme, which is a priority for the Country and for applied sciences”.

“The meeting was, therefore, conclusive for the creation of the new area and designed the initial milestones for the same”, Amaral states. Thus, on January 25th, 2008, CAPES’s Ordinance No. 09 was published, which ordinance, in its article 3, created two new areas of knowledge, “Materials” and “Biotechnology”, and designated their pro tempore coordinators.

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List of post-graduation programs that adhered to the Materials area (as of March, 2008).

1. Program of Post-Graduation in Materials – UNIVERSIDADE DE CAXIAS DO SUL

2. Program of Post-Graduation in Materials Science – UNIVERSIDADE FEDERAL  DO RIO GRANDE DO SUL

3. Program of Post-Graduation in Materials Engineering and Science – UNIVERSIDADE FEDERAL DO CEARÁ

4. Program of Post-Graduation in Materials Science – UNIVERSIDADE FEDERAL DE PERNANBUCO

5. Program of Post-Graduation in Materials Science and Technology – UNIVERSIDADE ESTADUAL PAULISTA “JÚLIO DE MESQUITA FILHO” – UNESP-BAURÚ

6. Program of Post-Graduation in Materials Engineering – UNIVERSIDADE DE SÃO PAULO – ESCOLA DE ENGENHARIA DE LORENA

7. Program of Post-Graduation in Materials Engineering and Science – UNIVERSIDADE FEDERAL DO RIO GRANDE DO NORTE

8. Program of Post-Graduation in Materials Engineering and Science – UNIVERSIDADE DE SÃO PAULO – SÃO CARLOS

9. Program of Post-Graduation in Materials Science and Technology – UNIVERSIDADE ESTADUAL PAULISTA “JÚLIO DE MESQUITA FILHO” – UNESP- CAMPUS DE ILHA SOLTEIRA

10. Program of Post-Graduation in Materials Engineering and Science – UNIVERSIDADE FEDERAL DE SANTA CATARINA.

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Featured paper: Changing the properties and morphology of graphene nanoribbons with nitrogen.

Posted on Thursday 30 de January de 2014

The scientific paper by members of the Brazilian community in Materials research featured this month is:

Josue Ortiz-Medina,  M. Luisa García-Betancourt,  Xiaoting Jia,  Rafael Martínez-Gordillo,  Miguel A. Pelagio-Flores,  David Swanson,  Ana Laura Elías,  Humberto R. Gutiérrez,  Eduardo Gracia-Espino,  Vincent Meunier, Jonathan Owens,  Bobby G. Sumpter, Eduardo Cruz-Silva,  Fernando J. Rodríguez-Macías,  Florentino López-Urías,  Emilio Muñoz-Sandoval, Mildred S. Dresselhaus,  Humberto Terrones,  Mauricio Terrones. Nitrogen-Doped Graphitic Nanoribbons: Synthesis, Characterization and Transport. Advanced Functional Materials 2013, 23, 3755-3762. DOI 10.1002/adfm.201202947.

Changing the properties and morphology of graphene nanoribbons with nitrogen

Multiple layers of graphene with the shape of ribbons (narrow and long) are called graphitic nanoribbons. These materials have been studied to control their properties by various methods, such as doping, in which are introduced atoms of “foreign” elements in the graphene carbon lattice.

In a study led by scientists at Pennsylvania State University with the participation of researchers from institutions in the United States, Mexico, Spain and Brazil, nitrogen-doped graphitic nanoribbons were manufactured by the chemical vapor deposition (CVD) method and showed new features, linked with the introduction of nitrogen, such as highest semiconductor performance, promising for applications in electronic devices, chemical reactivity and a very particular morphology on its edges.  The research was published in the journal Advanced Functional Materials.

“This article showed by the first time that it is possible to make doping with nitrogen on the same synthesis by CVD of graphite nanoribbons, and that you can control the level of doping during synthesis,” highlights Fernando Rodríguez-Macías, foreign visiting professor at the Brazilian Federal University of Pernambuco (UFPE) and one of the authors of the scientific paper. A Mexican national, Rodríguez-Macías came to UFPE in 2012, during his sabbatical year to work as a foreign visiting professor in the Department of Fundamental Chemistry and in the Graduate Program in Materials Science of the University. “I have prolonged my stay for another year to continue until 2014 doing collaborative studies for the production of carbon nanostructures, of bionanotechnology and toxicity of nanomaterials,” says the professor. “I am also teaching preparation and characterization of materials,” he adds.

The doped nanoribbons

The article’s authors showed that different concentrations of nitrogen generate controlled changes in material behavior. In particular, scientists have proven that the more nitrogen introduced into the structure of graphene, the most predominant the semiconductor behavior of nanoribbons. As an explanation to this phenomenon, the researchers suggested, based on theoretical calculations, that nitrogen atoms of doped nanoribbons act as scattering centers of electrons and decrease the conductive behavior of undoped graphene. “The control of doping level allows you to change the electrical properties of the nanoribbons, which can be useful for applications in transistors and other electronic devices,” says Rodríguez-Macías.

In addition, the paper also shows that the reactivity of nanoribbons can change with the doping level. Pure graphene, explains UFPE’s visiting professor, is very inert and has limited interactions with many chemical substances; on the other hand, nanoribbons doped with nitrogen are more reactive, which makes them useful for applications in sensors and catalysis.

As to the morphology, the article’s authors found that the nitrogen-doped nanoribbons have loops on their edges, uniting different graphene sheets. “This morphology is not presented by undoped graphite nanoribbons,” says Rodríguez-Macías.

This figure, sent by Professor Fernando Rodríguez-Macías, shows the nitrogen-doped graphitic nanoribbons in three scales. The scanning electron microscopy (top left corner) shows how these ribbons are made up of several layers and feature a curved surface with roughness. The transmission electronic microscopy (bottom left corner) shows that the nanoribbon layers are graphene sheets. The high resolution transmission electronic microscopy (right) shows that the layers of graphene on the nanoribbons edges form loops uniting different graphene sheets.

Collaborators

Almost all work of materials synthesis of the paper of Advanced Functional Materials was developed at Pennsylvania State University; the characterization was done in collaboration with other researchers and laboratories, reports UFPE’s visiting professor.

The participation of UFPE in the article happened through the doctoral student Miguel Angel Pelagio-Flores in the analysis and theoretical modeling of doped nanoribbons, and through professor Fernández-Macías himself, who, in addition to having participated in the discussion of results and review of the article from his office at UFPE, was doctoral advisor of the first author of the article, Josué Ortiz-Medina, while professor of a Mexican institution, IPICYT. “Ortiz-Medina did most of the experimental work of the article, besides being an important part of the characterization and theoretical studies of these new nanomaterials, when he was in exchange at Penn State in the laboratory of professor Terrones,” contextualizes the professor.

In total, 19 authors sign the article, among them MIT’s Professor Mildred Dresselhaus, reference in carbon science.