Interviews with plenary lecturers of the XIII SBPMat Meeting: Sir Colin Humphreys (University of Cambridge, U.K.).

Professor Sir Colin Humphreys.

Sir Colin Humphreys, PhD from Cambridge and a BSc from Imperial College, is Professor of Materials Science and Director of Research in the Department of Materials Science and Metallurgy at the University of Cambridge (United Kingdom). His research covers three main areas: gallium nitride  (GaN) materials and devices, advanced electron microscopy, and ultra-high temperature aerospace materials. He has published hundreds of papers on electron microscopy and given many plenary and invited lectures throughout the world. He has received national and international medals for his research in electron diffraction and microscopy and on gallium nitride.

He founded a spin-off company (CamGaN) to exploit the research on gallium nitride of his group on low-cost LEDs for home and office lighting. The company was acquired in February 2012 by Plessey, which manufactures LEDs based on this technology. He is the founder and director of the Cambridge Centre for Gallium Nitride, a center with world-class growth and characterization facilities where research is carried out from fundamental studies on GaN to applications in LEDs and lasers. He also founded and directs the Cambridge/Rolls-Royce Centre for Advanced Materials for Aerospace, which developed materials that now fly in Rolls-Royce engines.

He is a fellow of the Royal Society, the self-governing Fellowship of many of the world’s most distinguished scientists drawn from all areas of science, engineering, and medicine, and of the Royal Academy of Engineering. He is also a fellow of Selwyn College, one of the Cambridge University 31 autonomous units in which students live, eat, socialise and receive some teaching sessions. In 2010 he was Knighted (receive a special honor and the title of Sir from the Queen of England) for services to science.

Professor Humphreys has authored over 600 peer reviewed papers with over 9,400 citations and his h-index is 43.

In his limited spare time he writes books on science and religion, such as “The Mystery of the Last Supper: Reconstructing the Final Days of Jesus”, which has recently been translated into Russian, German, Portuguese, Japanese and Greek.

Read our interview with the plenary speaker.

SBPMat newsletter: – Why do you think gallium nitride is one of the most important semiconductor materials? Which are the main challenges in the field of gallium nitride for materials scientists and engineers?

Sir Colin Humphreys: – I think gallium nitride is one of the most important semiconductor materials because of the huge range of potential applications and the benefits to mankind which will result from these applications. The main challenges to realising these applications are reducing the cost of GaN devices and improving the efficiency still further.

SBPMat newsletter: – Which are the principal contributions you have done for the development of Materials Science and Engineering?

Sir Colin Humphreys: – The principal contributions I have made for the development of Materials Science and Engineering are solving some fascinating problems in basic science and also developing materials for industry. For example, I direct a Rolls-Royce Centre in Cambridge on Advanced Materials, and some of the materials we have developed are now flying in Rolls-Royce engines. In addition, I direct the Cambridge Centre for Gallium Nitride, and the low-cost GaN LEDs on silicon that we developed are now being manufactured in the UK by Plessey.

SBPMat newsletter: – Brazil is making efforts to transfer technology to the industry. You have founded a spin-off company and research centers, in both cases having good technology transfer results. Based on these experiences, what would you say to the Brazilian Materials community about making technology transfer real?

Sir Colin Humphreys: – First, scientists and engineers have to have an idea for a new or better product. In order to convince industry, it is important that the scientists and engineers make prototype devices to show to industry. If the scientists and engineers decide to set up their own company, it is usually helpful to bring in a CEO from outside to run the company because most scientists and engineers are not so good at running a company. The choice of the CEO is critical. It is also possible to set up a company for virtually nothing, set up a website for virtually nothing, etc. It is really important to get lots of good advice. I was fortunate in setting up two companies, in that I got a lot of good advice for free because there are a lot of people around Cambridge in the UK that have set up companies and can give good advice. Finally, making technology transfer real is good fun, but also hard work! You may have lots of set-backs, but keep persevering! Also, be enthusiastic about your product, if you are not enthusiastic, no-one else will be! You have really to believe in what you are doing.

GaN LEDs on a 6-inch Si substrate.

SBPMat newsletter: – If possible, tell us a little about the topic of your plenary talk at SBPMat meeting.

Sir Colin Humphreys: – In my plenary talk at João Pessoa I plan to start by showing some striking atomic-resolution electron micrographs showing single silicon impurity atoms in graphene, and showing that they can occupy two different sites. I will also show images of dancing silicon atoms in graphene (I know Brazilians are experts in dancing!). I will then move on to talk about Gallium Nitride (GaN) and how this amazing man-made material is likely to save more energy and CO2 emissions than solar, wind-power and biomass together! I will describe how advanced electron microscopy and atom probe tomography have been used to solve the fascinating problem of why GaN LEDs are so bright when the dislocation density is so high. I will also describe how growing GaN LEDs on large area silicon substrates can substantially reduce the cost of LEDs, and this cost reduction is likely to enable GaN LEDs to be the dominant form of lighting in our homes, offices, streets, etc, in the near future. In addition, I will show how GaN-based power electronic devices are 40% more efficient than silicon power electronic devices, so replacing Si power electronics by GaN would save another 10% of electricity, on top of the 10-15% electricity savings from using GaN LEDs. So GaN could potentially save 25% of the world’s electricity consumption, which is amazing.

In addition to saving energy and carbon emissions, if aluminium is added to GaN, then deep-ultra-violet (UV) light is emitted and this can kill all bacteria and viruses. So such deep-UV LEDs could be used for water purification in the world, saving millions of lives. Finally I will talk about how optimised quality LED lighting can improve the health of all of us and the exam results of school children! My talk will range from basic science through to applications.

From sunrise to sunset, some attractions for your spare time in João Pessoa.

Behind, João Pessoa city. Ahead, coral reefs at Picãozinho, 1,500 meters far from Tambaú beach. Foto: Cacio Murilo.

João Pessoa is the third Brazilian oldest city, being the capital of the state of Paraiba located in the Northeast of the country. It has a population about 770,000, while its metropolitan area comprises 8 satellite cities with 1,223,000 inhabitants. With a hot humid climate, João Pessoa has an average annual temperature around 26o C, reaching 29o C between September and October.

João Pessoa is known as the “Sun Door” or as “the city where the sun rises first”, having the easternmost point of Brazil. It has also a very beautiful sunset which can be admired at the sound of Ravel´s Bolero, in the “Praia do Jacaré”. It is also one of the greenest cities of the world, due to the presence of two reserves of Atlantic Forest inside the city.

João Pessoa has an important local culture. The architectonic-historic collection is very rich with baroque buildings from the XVI century, which worth a visit.

“Cabo Branco” Science, Culture and Art Station. Foto: Cacio Murilo.

Another touristic point is the “Cabo Branco” Science, Culture and Art Station, located at the easternmost point of the Americas (Ponta do Seixas), which is both an educational and cultural institution as well as a national landmark. The complex, inaugurated in 2008, was created by Brazilian architect Oscar Niemeyer and is one of his latest projects.

But the main touristic attractions of João Pessoa are its 18 beautiful beaches of green warm water – with a water average temperature of 28oC. Seven of these beaches are located in urban areas, with easy acces, very inviting for a nice swim.

XIII SBPMat meeting: registrations, program highlights and thanks in the message from the chairs.

Dear readers,

We hope to see you at the XIII Brazilian Materials Research Society Meeting, held on 28 September to 02 October, 2014, in João Pessoa, PB, Brazil. This year the meeting has 2,141 accepted abstracts and, up to this moment, almost 2,000 inscriptions from Brazil and other 27 countries.

The XIII Meeting is comprised of 19 Symposia following the format used in tradicional meetings of Materials Research Societies, involving topics as synthesis of new materials, computer simulations, optical, magnetic and electronic properties, traditional materials as clays and cements, advanced metals, carbon and graphene nanostructures, nanomaterials for nanostructures, energy storage systems, composites, surface engineering and others. A novelty is a symposium dedicated to the innovation and technology transfer in materials research. The program also includes 7 Plenary Lectures presented by internationally renowned researchers.

This year, the B-MRS will present the results of two important actions from our society. The first one is the meeting of the B-MRS directory with the University Chapters (UC) already established and the students who want to establish other UC´s. The second one is the launch of the IOP publication on behalf of the B-MRS, Materials Science Impact, reporting advances in Materials Research in Brazil.

The Opening Ceremony will be followed by the Memorial Lecture “Joaquim Costa Ribeiro”, Progresses in Materials Research in Brazil by Professor José Arana Varela. During the Closing Ceremony the symposium coordinators will honor students with the “Bernhard Gross Award” for the best poster and the best oral presentation of each Symposium.

On behalf of Organizing Committee, we would like to thank the Brazilian Materials Research Society staff and board, the hired agencies, the symposium coordinators, the program, local and national committee members, for their commitment and great effort to make this Meeting possible.

We hope that the participants will have a very pleasant Meeting with stimulating exchange of scientific informations and establishment of new collaborations.

Ieda M. Garcia dos Santos and Severino Jackson Guedes de Lima

Meeting Chairs

Interviews with plenary lecturers of the XIII SBPMat Meeting: Robert Chang (Northwestern University, USA).

Prof. Chang and other developers of Nanocos, a card game that encourages students to learn science concepts and their role at the nanoscale.

Robert Chang is a Professor of Materials Science and Engineering at the first materials science academic department in the world, created more than 50 years ago at Northwestern University, where he is also director of the Materials Research Institute.

He holds a Bachelor of Science in Physics from Massachusetts Institute of Technology (MIT) and a Ph.D in Plasma Physics from Princeton University. He spent 15 years performing basic research at Bell Labs (Murray Hill). During the past 28 years at Northwestern University, he has directed several National Science Foundation (NSF) centers and programs in materials research and education.

Prof. Chang was the president of the Materials Research Society (MRS) in 1989. He is the General Secretary and Founding President of the International Union of Materials Research Societies (IUMRS). He has received many distinctions for his work, such as the Woody Award from MRS in 1987, the Siu Lien Ling Wong Fellow from the Chinese University of Hong Kong in 1999, and the NSF Director’s Distinguished Teaching Scholar Award in 2005. He is fellow of the American Vacuum Society and MRS, and honorary member of Materials Research Societies of India, Japan and Korea.

He is (co)author of 400 peer reviewed journal articles, with near 13,000 citations, and h-index of 56.

Read our interview with the plenary speaker.

SBPMat newsletter: – Under your viewpoint, which are your main contributions in the field of Materials Science and Engineering?

Robert Chang: 1. Plasma processing of semiconducting materials;

2. Carbon based materials, such as diamond, fullerene, and carbon nanotubes, and their related devices;

3. 3rd generation solar cells;

4. Infrared plasmonics and sensors;

5. Thin film oxides for electronic and photonic devices.

Top publications below.

H. Cao, Y. G. Zhao, S. T. Ho, E. W. Seelig, Q. H. Wang, and R. P. H. Chang. Random Laser Action in Semiconductor Powder. Phys. Rev. Lett. 82, 2278 (1999); DOI:http://dx.doi.org/10.1103/PhysRevLett.82.2278.

Michael D. Irwin, D. Bruce Buchholz, Alexander W. Hains, Robert P. H. Chang, and Tobin J. Marks.p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells. PNAS, vol. 105 no. 8, 2783–2787 (2008); doi: 10.1073/pnas.0711990105.

Q. H. Wang, A. A. Setlur, J. M. Lauerhaas, J. Y. Dai, E. W. Seelig and R. P. H. Chang. A nanotube-based field-emission flat panel display. Appl. Phys. Lett. 72, 2912 (1998);http://dx.doi.org/10.1063/1.121493.

Quanchang Li, Vageesh Kumar, Yan Li, Haitao Zhang, Tobin J. Marks, and Robert P. H. Chang. Fabrication of ZnO Nanorods and Nanotubes in Aqueous Solutions. Chem. Mater., 2005, 17 (5), pp 1001–1006. DOI: 10.1021/cm048144q.

SBPMat newsletter: – And what about your main contributions to science education, especially in Materials Science?  

Robert Chang: – Over the past 20 years, I have led the development of the Materials World Modules program to teach pre-college students about Materials and Nanotechnology: materialsworldmodules.orgnclt.usgsasprogram.orgimisee.net.

SBPMat newsletter: – Please give us a short teaser about your plenary talk at SBPMat meeting. What do you intend to broach?  

Robert Chang: – Mobilizing world-citizens to solve global problems together!

SBPMat newsletter: – Feel free to leave other comments to our readers from the Materials research community, if you want so.  

Robert Chang: – Materials and nanotechnology research and education are the driving force of all future technologies, including energy, environment, health, and security.

SBPMat newsletter. English edition. Year 1, issue 8.

 

Brazilian Materials Research Society (SBPMat) newsletter

News update from Brazil for the Materials community

 

English edition. Year 1, issue 8. 

Greetings, .

XIII SBPMat meeting (João Pessoa, September 28th to October 2nd)

Less than a month left until our meeting at João Pessoa!

– Registration: here.

–  Some options of lodging, rental of cars, transfers and tours: on the home page of the site of the event. Here.
Detailed technical program: here.


We interviewed the German physicist Karl Leo, specialist in organic semiconductors. Beyond being the author of more than 550 papers with more than 23,000 citations and 50 families of patents, the scientist has already participated of the creation of 8 spin-off companies. In his lecture at the XIII SBPMat Meeting, Karl Leo will speak on highly efficient organic devices, as OLEDs and solar cells. See our interview with Karl Leo.

We also interviewed the Portuguese physicist Antonio Luis Ferreira Martins Dias Carlos, of the University of Aveiro, who will perform a lecture in our meeting in João Pessoa on luminescence applied to nanomedicine. In the interview, the professor shared with us his most prominent works in the field of Materials. He also told us about some challenges in the area of luminescence for medical applications, both in medical imaging and intra-cellular temperature mapping, and cited examples of applications of luminescent materials that have already been used in the diagnosis and treatment of various diseases. See our interview with Luis Dias Carlos.

Featured paper with Brazilian participation

By making small adjustments in the technique of thin film deposition known as magnetron sputtering, a group of scientists obtained the control of the direction of magnetization in the manufacture of spin valves, devices formed by nanometric layers of magnetic and non-magnetic materials used, for example, in the reading of data of hard disks. This work of spintronics, conducted by researchers from Brazil and Chile, has been recently published in Applied Physics Letters.  Read the story.

History of Materials research in Brazil

We celebrate the Graduate Program in Materials of University of Caxias do Sul for its 10 years of existence, with a report and photos on the history of the program and its interaction with the local industry. See here.

Reading recommendations

– Contribution of nanotecnology to medical imaging for diagnostics of problems of small intestine (Nature Nanotechnology). Here.
– With a AC-TEM, scientists test and observe, live, electric properties of graphene and their relation with structure  (Nanoletters). Here.
Xerox does R&D in graphene, and company’s patent nº 2,000 is on graphene nanosheets. Here.
– Material for ceramic blocks for civil construction developed in the Brazilian State University of Maringá uses residues (silt) from local laundries. Here.
– Flexible, resistant and biodegradable, spider web developed by Brazilian researchers can find diverse applications. Here.

 

Opportunities

Postdoctoral positions at the Center for Research, Technology and Education in Vitreous Materials (CeRTEV), in São Carlos, Brazil. Here.

Upcoming events in the area

– 13th European Vacuum Conference + 7th European Topical Conference on Hard Coatings + 9th Iberian Vacuum Meeting. Here.

– 19th International Conference on Ion Beam Modification of Materials. Here.

– XIII SBPMat Meeting. Here.

– International Symposium on Crystallography – 100 years of History. Here.

– Congresso Brasileiro de Engenharia Biomédica (CBEB). Here.

– MM&FGM 2014 – 13th International Symposium on Multiscale, Multifunctional and Functionally Graded Materials. Here.

– X Brazilian Symposium on Glass and Related Materials (X-BraSGlass). Here.

To suggest news, opportunities, events or reading recommendations items for inclusion in our newsletter, write to comunicacao@sbpmat.org.br.
Unsubscribe here.

 
Cannot see this message? Click here.

An anniversary at the materials research community: 10 years of PGMAT – UCS.

Faculties and students receiving lab equipment through a window in 2007.

This August records the 10th anniversary of one of the 31 Brazilian graduate programs in the field of Materials: the Graduate Program in Materials Engineering and Science of the University of Caxias do Sul (PGMAT – UCS in Portuguese).

PGMAT-UCS history dates back to the year of 2003, when Israel Baumvol, physicist and researcher in the area of Materials, was invited by authorities of UCS to lead the creation of a graduate program in this field of knowledge. Baumvol was, at the time, retiring from his position as professor at the Brazilian Federal University of Rio Grande do Sul (UFRGS).

In August, 2004, after conducting a selection process that had 85 applicants for 15 vacancies, PGMAT-UCS started the activities of its Master’s Degree course under the coordination of professor Baumvol. The program then had some laboratories that already existed at the university and a few professors with PhD, and offered the only graduate course at the university in the area of Sciences and Engineering.

Nowadays, the program has more than 20 laboratories and an all its professors hold PhDs. Since 2012, PGMAT also offers a doctoral program, which currently has 19 students.

The same room is today the Laboratory for Surface Characterization at the Nanoscale and has a GDOES analyser, among other instruments.

Another achievement of the program was the signing of an agreement with the European School of Engineers in Material Engineering (EEIGM, in the French acronym) for double degree. Two Masters have graduated with this double degree program after performing academic activities at UCS and EEIGM, headquartered in Nancy, France.

Regarding scientific production, more than 300 articles were published in international journals by faculty and students of the program in its 10 years of existence.

Impact of the research on the industry

From the beginning, the PGMAT-UCS team has pursued the interaction with local companies, based on the affinity that Science and Engineering of Materials have with almost all industrial segments. Thus, already in 2003, the UCS faculty involved in creating the program had visited companies of Caxias do Sul to appraise their needs.

On several occasions throughout its history, PGMAT-UCS could count on resources of companies and entities of the industrial sector, especially the Union of Metallurgical, Mechanics and Electric Equipment Industries of Caxias do Sul (SIMECS), which complemented the public funds in the purchase of equipment for the laboratories of the program.

Inauguration of the Laboratory for Surface Engineering and Thermal Treatments in 2007: local industry was there. Speaking, professor Baumvol.

In 10 years of existence, PGMAT-UCS has graduated 90 Masters. Among them, 45% work in local companies, 10% are academics and 30% are ongoing or concluded their Doctorate degree.

In some cases, the own Master’s research works were essential to the development of new products in the region. This was the case with the Celtrav®, a high-performance material to be used in springs and stops, which composes the product portfolio of the company Travi. A Masters research at PGMAT was also important in developing a coating for ornaments used by the footwear manufacturer Grendene. According to the company, about 18 million pairs of shoes with these ornaments were sold in 2013.

Young entrepreneurs who founded companies from works developed at PGMAT are also among the students and graduates of the program.  Plasmar Tecnologia, one of these spin-off companies, currently provides service for hundreds of industries in the region with plasma-based surface treatments that improve the performance and the cycle life of molds, matrices and other parts and components. The other example is Fineza, a company recently created, dedicated to manufacturing and commercializing products for housing and kitchen with decorative coatings that had been optimized in a PGMAT master’s thesis.

Featured paper: Accurate engineering in spin valves manufacturing.

The scientific paper by members of the Brazilian community on Materials research featured this month is:

T. E. P. Bueno, D. E. Parreiras, G. F. M. Gomes, S. Michea, R. L. Rodríguez-Suárez, M. S. Araújo Filho, W. A. A. Macedo, K. Krambrock and R. Paniago.Noncollinear ferromagnetic easy axes in Py/Ru/FeCo/IrMn spin valves induced by oblique deposition. Appl. Phys. Lett. 104, 242404 (2014). DOI: 10.1063/1.4883886.

Accurate engineering in spin valves manufacturing

The production and characterization of spin valves is the theme of  a collaborative work between Brazil and Chile, whose results were published recently in the prestigious journal Applied Physics Letters (APL).

Spin valves are devices consisting of three or more layers of nanometric thickness composing a sandwich of magnetic and non-magnetic materials. Sensors consisting of such structures fulfill a fundamental role in reading the information written on the hard disc drives, among other applications.

The operation of spin valves is based on an effect called “giant magnetoresistance”, which was the reason behind the Nobel Prize in Physics in 2007. The giant magnetoresistance of spin valve consists of a large change in the electrical resistance in response to the action of a magnetic field. This resistance depends on the relative orientation among the magnetization of the magnetic material layers.

The magnetization of a magnetic material is determined by the orientation of the spins of its electrons. Electrons have two intrinsic features: electric charge and magnetic moment, the latter known as spin. Explore the degree of freedom of the electron spin in addition to its charge led to the emergence of a new field of research called spintronics.

Then, on giant magnetoresistance of spin valves, when the layers of magnetic material have the same direction of magnetization, the device reduces its electrical resistance and becomes a better conductor of electricity. When the magnetic layers acquire opposite directions of magnetization, a significant increase of electrical resistance occurs.

For better understand this effect and, later, the results presented in the article of APL, it is important to remember that the magnetization is a vector physical quantity and that, therefore, besides having an intensity, it has a direction (parallel, perpendicular) and an orientation (indicated by the arrowhead representing the vector). Usually, metallic multilayers composed of magnetic materials separated by a non-magnetic layer, as spin valves, have the magnetization of ferromagnetic layers coupled, says Thiago Bueno, first author of the APL article and PhD student in Physics at the Brazilian Federal University of Minas Gerais (UFMG), supervised by professor Roberto Magalhães Padilla. This coupling can result in parallel magnetization (called “collinear”) with same or opposite orientations, and also in non-collinear magnetization.

Ferromagnetic layers “making a sandwich” with a non-magnetic layer of ruthenium. The red and green arrows represent the direction and the way of magnetization of layers composed by Py and FeCo, respectively. (a) Parallel magnetizations with equal orientation; (b) Parallel magnetizations with opposite orientation; (c) Perpendicular magnetizations.

However, to magnetize the magnetic layers of the spin valve does not occur homogeneously in all directions; they feature the so-called magnetic anisotropy. “The magnetic anisotropy is an important magnetic property, because it establishes an easy direction of magnetization,” says Thiago Bueno. “This property is determined by a number of factors, including the types of materials, the thickness of layers, and the details of the method of sample manufacturing”.

On the work that originated the APL article, the team of scientists has made some adjustments to the method of spin valves manufacturing, obtaining interesting results on the properties of these devices.

Controlling the direction of magnetization

“This work was only possible due to the great collaboration between the parties along the preparation of samples of excellent quality, accurate experimental measures, interpretation of the data, until the publication of the results,” says Thiago Bueno.

Initially, at the Brazilian Center for Development of Nuclear Technology (CDTN in Portuguese) the team has made thin films composed of multi-layers with thickness of a few tens of nanometers. The films were obtained through the technique known as magnetron sputtering, in which argon ions are accelerated against the targets that contain the materials to be deposited, ripping off its atoms. With the aid of magnetrons, these atoms are deposited on a substrate, forming the layers of films. “Through this technique it is possible to obtain films with well-determined chemical composition, thickness and structural morphology,” says Thiago Bueno.

Oblique deposition scheme with 5 sputtering sources (magnetrons) producing an angle of 72 between them. The (β) angle between the direction of deposition and normal direction of the film is estimated at 38° for all sources.

In this study, the scientists set up an oblique deposition scheme by putting the magnetrons making an angle of 72o between them and inclined towards the sample. Using the oblique deposition scheme, scientists made spin valves with ferromagnetic layers up to 10nm-thickness, composed of metallic alloys (Py and FeCo), and separated by a non-magnetic layer of ruthenium (Ru) of thickness between 1nm and 3.5nm. The devices were characterized in the Physics Department at UFMG using ferromagnetic resonance (FMR), an extremely sensitive technique that provides relevant information on the magnetization of materials.

After the interpretation of experimental results, which involved researchers from the Pontifical Catholic University of Chile, the scientists concluded that the oblique deposition induced non-parallel magnetization directions (non-collinear) on ferromagnetic layers of manufactured spin valves.  “The angle between the easy axes, approximately equal to the angle between the magnetrons, was determined by the manufacturing geometry”, reinforces the author, Bueno. “One of the main contributions of our work is the demonstration that it is possible to manufacture spin valves where the axes of easy magnetization of ferromagnetic layers (Py and FeCo) are non-collinear,” he sums up.

According to the doctoral student, at the beginning of the work the authors already knew the oblique deposition effects in ferromagnetic/anti-ferromagnetic bilayers. With this study, the team took a step further and has investigated these effects in a more complex structure, the spin valve.

“We believe that our work will compel other researchers into manufacturing these devices, seeking new magnetic configurations between layers of the spin valve “, says Bueno.

Interviews with plenary lecturers of the XIII SBPMat Meeting: Luís Carlos (Universidade de Aveiro, Portugal).

Prof. Luís Carlos.

“Luminescence applied to nanomedicine” is the subject of one of the plenary lectures that the Materials research community is going to enjoy in our XIII SBPMat Meeting (João Pessoa, Brazil, September 28th to October the 2nd). The speaker will be the Portuguese physicist Luís António Ferreira Martins Dias Carlos, full professor at the University of Aveiro (Portugal), who got his Ph.D. in physics from the University of Évora (Portugal) in 1995 working on photoluminescence of polymer electrolytes incorporating lanthanide salts.

At the University of Aveiro, Luís Carlos created in 2000 a research group in functional organic-inorganic hybrids. The group has established an international network devoted to these luminescent hybrid materials with more than 30 research groups in Europe, China, Japan, Singapore, Brazil and Australia. Also at Aveiro, Luís Carlos has been, since 2009, the vice-director of the Centre for Research in Ceramics and Composite Materials (CICECO), one of the largest European institutes in the Materials and Nano fields.

He is member of the Lisbon Academy of Sciences (Physics section) since 2011. He was visiting professor of São Paulo State University (UNESP), Brazil, in 1999, 2012 and 2013, and of University of Montpellier 2, France, in 2008. He awarded a ‘Pesquisador Visitante Especial’ grant by the CNPq, Science Without Borders Program, Brazil in 2013.

He has co-authored more than 345 papers in international journals, 8 invited reviews, 5 book chapters, and 2 international patents. He has more than 8.050 citations, having h-index of 47. He has given 40 plenary and invited lectures at conferences. He is associate editor of the Journal of Luminescence.

Read our interview with the plenary speaker.

SBPMat newsletter: – Are there nanomedical applications to luminescent materials already on the market/spread in society? Please, give some high-impact examples. 

Luís Carlos: – Undoubtedly yes, there are luminescent materials with important applications in nanomedicine already on the market. I can highlight two examples:

1. Organic complexes based on lanthanide ions (as, for example, cryptates and β-diketonates) are sold as contrast agents for magnetic resonance imaging  (essentially using Gd³+) and luminescent markers (using Eu3+, Sm3+ and Tb3+) for fluoroimmunoassays. The fluoroimmunoassay is an immunological method for clinical diagnosis that is particularly relevant in prenatal and neonatal screening tests, as well as to detect proteins, viruses, antibodies, tumor biomarkers and medicine residues. In this respect, it is worth mentioning the work conducted by several researchers from the INCT INAMI (Brazilian National Institute of Science and Technology on Nanotechnology for Integrated Markers), implementing a prototype in the hospital environment in order to develop methods to diagnose the American cutaneous leishmaniasis, prostate cancer (PSA) and low density lipoprotein (LDL) by fluoroimmunoassay, using recombinant antigens marked with lanthanide ions complexes (for example, Eu3+, Tb3+ and Nd3+). The international market for contrast agents and luminescent markers based on lanthanide ions is valued in many hundreds of millions of US dollars.

2. Luminescent nanoparticles (“quantum dots”, QDs, and nanocrystals incorporating lanthanide ions) have played a major role in the last years thanks to very important applications for diagnosis by optical imaging and therapy techniques. Recent estimates value the international market for luminescent nanoparticles in the medical field in over 20 million US dollars. A notable example in the treatment of tumors is the local hyperthermia. Local hyperthermia, also referred as local thermotherapy, is a type of treatment in which biological tissues (typically cancer cells)  are exposed to temperatures above 45° C, irreversibly damaging them and causing their death (the collateral damage to the healthy tissues surrounding the tumor is usually minimal). Numerous clinical trials with hyperthermia are being currently performed around the world so we can better comprehend and improve the technique. For example, the use of luminescent or magneto-luminescent particles (with magnetic ions such as Iron or Cobalt), vectored to bind to specific points in the cancer cells, enabling the local heating by the absorption of electromagnetic radiation and magnetic induction, respectively, is a new type of local hyperthermia. Precise temperature control in the irradiated area, limiting the effects of high temperature on the rest of the body, still is one of the key challenges for the popularization of the technique.

SBPMat newsletter: –  Could you briefly describe the main challenges in the field of luminescence applied to nanomedicine?

Luís Carlos: – I can point out two examples: improving the imaging techniques for diagnosis and developing luminescent micro/nanothermometers which allow mapping the intracellular temperatures with a resolution of the order of tenths of a degree.

In regard to imaging applications in nanomedicine, emitting centers in the near-infrared region (for example, lanthanide ions such as Nd3+ and Yb3+, QDs and organic dyes) have great advantages over those in the visible region.  For instance, biological tissues present less autofluorescence in the near-infrared window, which enables a better signal-to-noise discrimination and improves the sensibility to detection. Also, in comparison to the ones in the visible region, near-infrared photons interact less with biological tissues, which reduces the risk of disturbance or damage in the observed biological system. Thus, there is no doubt that the synthesis of new luminescent nanoparticles, emitting efficiently in near-infrared (in some cases producing persistent luminescence, i.e., light emissions that last for minutes, hours or even days, after the excitation is over), will lead us to a revolution in fluorescence microscopy, with the development of in vitro and in vivo imaging techniques in near-infrared (whose radiation penetrates deeper into the biological tissue, when compared to visible light).

The development of luminescent micro/nanothermometers to map the intracellular temperature, particularly in cancer cells, will surely improve our current perception on their pathology and physiology, optimizing early diagnosis and therapeutic processes (as seen above in the case of local hyperthermia).  These non-invasive thermometers are a critical tool for better understanding a set of cellular processes followed by alterations in temperature, such as cell division, gene expression, or changes in the metabolic activity. Finally, the development of luminescent nanothermometers in the near-infrared region,  which are capable of sensing heat and penetrate deeper into the biological tissue, will pave the way for in vivo thermal sensing and imaging (in small animals, in a first stage).

SBPMat newsletter: – Under your viewpoint, which are the main contributions you made to the field of Materials Science and Engineering during your scientific career? Could you please include a selection of 3 or 4 of the most important publications among your work in your answer?

Luís Carlos: – Normally, our latest works tend to seem to be the most important… Regardless, I understand that my main contributions to Materials Science and Engineering are related to the development of i) luminescent organic-inorganic hybrid materials, ii) ratiometric nanothermometers based on the characteristic emission of lanthanide ion pairs (Eu3+/Tb3+ and Er3+/Yb3+) and iii) nanoplatforms combining nanoheaters (metal particles of Gold or Silver) and nanothermometers which allow to increase the local temperature by laser irradiation while simultaneously mapping such temperature increase with precision. The following four papers illustrate these contributions:

Full Colour Phosphors From Eu(III)-Based Organosilicates. L. D. Carlos, Y. Messaddeq, H. F. Brito, R. A. Sá Ferreira, V. de Zea Bermudez, S. J. L. Ribeiro, Adv. Mater. 12, 594–598 (2000)

Nanoscopic Photoluminescence Memory as a Fingerprint of Complexity in Self-Assembled Alkylene/Siloxane Hybrids. L. D. Carlos, V. de Zea Bermudez, V. S. Amaral, S. C. Nunes, N. J. O. Silva, R. A. Sá Ferreira, J. Rocha, C. V. Santilli, D. Ostrovskii, Adv. Mater. 19 341–348 (2007)

A Luminescent Molecular Thermometer for Long-Term Absolute Temperature Measurements at the Nanoscale. C. D. S. Brites, P. P. Lima, N. J. O. Silva, A. Millán, V. S. Amaral, F. Palacio, L. D. Carlos, Adv. Mater. 22, 4499–4504 (2010)

All-In-One Optical Heater-Thermometer Nanoplatform Operative From 300 to 2000 K Based on Er3+ Emission and Blackbody Radiation. M. L. Debasu, D. Ananias, I. Pastoriza-Santos, L. M. Liz-Marzan, J. Rocha, L. D. Carlos, Adv. Mater. 25, 4868–4874 (2013)

Interviews with plenary lecturers of the XIII SBPMat Meeting: Karl Leo (TU Dresden, Germany).

The German physicst Karl Leo studied physics at the Albert Ludwigs University of Freiburg (Gemany) and obtained the “Diplomphysiker” degree with a thesis on solar cells at the Fraunhofer Institute for Solar Energy Systems (Germany).  In 1988, he obtained the PhD degree from the University of Stuttgart for a doctoral thesis performed at the Max Planck Institute for Solid State Research in Stuttgart. From 1989 to 1991, he was a postdoc at AT&T Bell Laboratories (United States). In 1991 he joined the RWTH Aachen University (Germany) as an assistant professor and obtained the Habilitation degree. In 1993 he joined the Dresden University of Technology (Germany) as a professor of optoelectronics. Since 2001 until 2013, he has been also with the Fraunhofer Institute for Photonic Microsystems, being head of department and then director.

He won some of the most prestigious German awards in science, technology and innovation, such as the Leibniz award (2002) and the German Future Prize (2011).

He is the author of more than 550 refereed publications, with more than 23.000 citations, having an H index = 73 (Google Scholar).  He is (co-)inventor of approximately 50 patent families.

Since 1999 he has co-founded 8 spin-off companies, such as Heliatek and Novaled, which have employed more than 250 people and raised more than 60M€.

Prof. Karl Leo with an organic solar cell module on test on the roof of Kaust university, in Saudi Arabia.

Read our interview with the lecturer.

SBPMat newsletter: – Under your viewpoint, which are your main contributions in the field of Materials Science and Engineering? Please think about papers, patents, spin-off companies, products etc.

Karl Leo: – I spent most of the last decades improving organic semiconductors and developing new device concepts for organic semiconductor devices. One example is the development of controlled electrical doping, which allowed much higher electrical conductivities. As a result, we could e.g. realize white organic light emitting diodes which are more efficient than fluorescent tubes. As device principle, we e.g. developed novel vertical transistors which can drive very high currents so that they can be used to drive OLED displays.

SBPMat newsletter: – Please give us a short teaser about your plenary talk at the XIII SBPMat meeting. What do you intend to broach?

Karl Leo: – I will talk about highly efficient organic devices, touching both organic LED and organic solar cells. I will describe the challenges in materials research and the importance of new device concepts.

SBPMat newsletter: – Could you choose some of your main publications (about 3 or 4) on the topics of your plenary lecture to share them with our public?

Karl Leo: –

1. Doped Organic Transistors: Inversion and Depletion Regime. Lüssem, B., Tietze, M.L., Kleemann, H., Hoßbach, C., Bartha, J.W., Zakhidov, A. and Leo, K. , Nature Comm. 4, 2775 (2013).

2. Phase-locked coherent modes in a patterned metal-organic microcavity. Brückner, R. Zakhidov, A., Scholz, R., Sudzius, S., Hintschich, S.I., Fröb, H., Lyssenko, V.G. and Leo, K., Nature Photonics 6, 322–326 (2012).

3. White organic light-emitting diodes with fluorescent tube efficiency. Reineke, S.; Lindner, F.; Schwartz, G. et al., Nature 459, 234 (2009).

SBPMat newsletter: –  Feel free to leave other comments to our readers from the Materials research community.

Karl Leo: – The field of materials research is as exciting as ever, and in the field of organic semiconductors, we are still in the beginning, maybe where silicon was in 1970…

SBPMat newsletter. English edition. Year 1, issue 7.

Brazilian Materials Research Society (SBPMat) newsletter

News update from Brazil for the Materials community

 

English edition. Year 1, issue 7. 

Greetings, .

XIII SBPMat meeting (João Pessoa, September 28th to October 2nd)

– Have you made your registration yet? Take advantage of our discounts up to Aug/15.  Here.

– If you are a student and submitted an abstract that has been approved, you may send your extended abstract up to Aug/08 and apply to compete for the Bernhard Gross Award. Here.

Accommodation options? There are some here.
– 24 companies and institutions already chose to attend our meeting as exhibitors. If your organization also wishes to be a part of the event, contact us at rose@metallum.com.br.


We interviewed the French scientist Jean-Marie Dubois, specialist in quasicrystals (ordered, but aperiodic structures on solid materials) and pioneer in patenting applications for them. He told us a little about his main contributions to the field of Materials and gave a teaser on the theme of his plenary lecture in the XIII SBPMat Meeting: he will talk about quasicrystal structures, found in metallic alloys, polymers, oxides and artificial nanostructures, and their unprecedented properties. In the picture, Jean-Marie Dubois (on the left) and Dan Shechtman, who received a Nobel Prize in 2011 for the quasicrystals, using equal ties, both decorated with the Penrose tiling, an example of aperiodicity.  Read our interview with Jean-Marie Dubois here.

We also interviewed the Italian chemist Roberto Dovesi, one of the creators of CRYSTAL, a computational tool for ab initio quantum calculations used in the study of several solid materials properties. The CRYSTAL code is currently used in over 350 laboratories around the world.  In his plenary lecture in the XIII SBPMat Meeting, Dovesi will attempt to demonstrate that today quantum simulations may be very useful tools to complement experiments.  Read our interview with Roberto Dovesi here.

Featured paper with Brazilian participation

A group of scientists, coordinated by Brazilian researchers, used a Helium Ion Microscope (HIM) located in Silicon Valley, in the United States,  to engrave nanometric periodic patterns in graphene sheets, giving an innovative use to the instrument. The fast, simple and precise technique could be used by the electronics industry to produce graphene semiconductive devices, which could replace the silicon ones. The lead author of the paper published in Applied Physics Letters told us the story behind the study and announced that, soon, Brazil is going to have its first HIM.  Read the story.

Reading recommendations

Science stories based on papers published in journals with high impact factor.

– Ultralight material formed from polymeric, metallic and ceramic microstructures, produced by 3D printers (Science). Read it here.

Friction at the nanoscale: while carbon nanotubes are superlubricants, boron nitride nanotubes display a high level of friction (Nature Materials). Read it here.

– New method for producing perovskite solar cells with good costs and efficiency (Nature Materials). Read it here.

– Scientists propose a model for fullerenols structure and are one step closer to biomedical applications (Chemical Science). Read it here.
Materials news from the Brazilian National Institutes of Science and Technology (INCTs).

3D chips may be quick and cheap. Read it here.
On the market, or almost there.

Oral hygiene products incorporated with silver nanostructures: technology developed in Brazil prevents 99% of bacteria and fungi. More.

For licensing: bionanocomposite for bone grafting tested in vitro and in vivo, developed in Brazil. More.

For licensing: Cesium phosphate filter with functionalized nanotubes, very efficient for heavy metals. More.
Book review

– New book on eco-friendly polymer nanocomposites (types, processes and properties). Read it here.

 

Upcoming events in the area

– 2º Workshop Adesão Microbiana e Superfícies. Here.

– 13th European Vacuum Conference + 7th European Topical Conference on Hard Coatings + 9th Iberian Vacuum Meeting. Here.

– 19th International Conference on Ion Beam Modification of Materials. Here.

– XIII SBPMat Meeting. Here.

– International Symposium on Crystallography – 100 years of History. Here.

– Congresso Brasileiro de Engenharia Biomédica (CBEB). Here.

– MM&FGM 2014 – 13th International Symposium on Multiscale, Multifunctional and Functionally Graded Materials. Here.

– X Brazilian Symposium on Glass and Related Materials (X-BraSGlass). Here.

To suggest news, opportunities, events or reading recommendations items for inclusion in our newsletter, write to comunicacao@sbpmat.org.br.
Unsubscribe here.