Featured scientist: interview with Leonardo Mathias Leidens, winner of the national award for undergraduate research works.

Leonardo Mathias Leidens.
Leonardo Mathias Leidens.

When he answered the telephone on that May afternoon, Leonardo Mathias Leidens, 24 years old, thought it was a hoax. The president of CNPq (the Brazilian federal organization dedicated to the promotion of science and technology) was giving him the news that his undergraduate research (iniciação científica in Portuguese) had been chosen as the best in Brazil in the area of Exact, Earth and Engineering Sciences, in the sixteenth edition of the Prêmio Destaque na Iniciação Científica e Tecnológica.

However, in hindsight, if Leonardo had contained his excitement and looked back at that moment, he would have realized that the prize was in fact a likely consequence of a steady path through scientific knowledge, and a well-deserved recognition of his competency and dedication.

Leonardo was born in 1995 in Caxias do Sul, municipality of the Brazilian State of Rio Grande do Sul, of about 500 thousand inhabitants and an important industrial pole. After attending a public school in the city, always with excellent school performance, in 2013 Leonardo joined the undergraduate course in Chemical Engineering of the University of Caxias do Sul (UCS), a community university headquartered in Caxias do Sul, which has its campi in eight municipalities of the region.

In the first half of 2014, Leonardo found an opportunity to start doing science. He became a scientific initiation fellow, under the guidance of Professor Carlos A. Figueroa, leader in the UCS of a group of fundamental and applied research in Surface Science and Engineering, which would later receive the name of “Epipolé Group.” In this group, and always with the same advisor, Leonardo worked in several studies concerning the adhesion of amorphous carbon films as a scholarship holder of the university and then of the CNPq programs for undergraduate research. As a result of this work, Leonardo has today nine scientific papers (one of them as first author) published in international peer-reviewed journals, including some of the best journals in the area of surfaces and thin film.

In August 2016, Leonardo left the country for the first time to attend two semesters at the École Supérieure des Industries Chimiques (ENSIC), in the city of Nancy (France), after being selected as a fellow of BRAFITEC, a Brazilian federal program that supports the mobility of engineering students between institutions in Brazil and France. In this period, in addition to attend the courses, Leonardo presented, for the first time, a work in an international scientific event, the E-MRS 2017 Spring Meeting, held in the French city of Strasbourg.

After this enriching experience abroad, in mid-2017, Leonardo returned to Caxias do Sul and resumed his academic activities at UCS, including the undergraduate research in the Epipolé Group. In December 2018, he completed his bachelor’s degree in Chemical Engineering with a 3.96 average out of a maximum of 4 in all of the subjects studied. As a result, on graduation day, Leonardo was awarded the Academic Laurel by the Rector of UCS.

Due to his experience in more than four years as an undergraduate research fellow, Leonardo decided to pursue a doctorate without undertaking masters studies (Masters degree is the usual step before PhD in Brazil). Thus, earlier this year, he became a doctoral candidate of the Postgraduate Program in Materials Engineering and Science (PGMAT) of UCS, again under the guidance of Professor Figueroa.

On July 23, Leonardo will receive his CNPq award at the ceremony to be held in the city of Campo Grande (State of Mato Grosso do Sul) during the 71st Annual Meeting of the Brazilian Society for the Progress of Science (SBPC).

See our interview with Leonardo.

box englishB-MRS  Bulletin: Could you tell us briefly how and when you started and developed your interest in science/research? And your desire to become a scientist?

Leonardo Mathias Leidens:  Curiosity has always been a perceivable characteristic of my personality. The will and concern to know the origin of “everything”, the whys and how things work led me to science, even if in a somewhat unconscious way. My parents always encouraged me to read and this was essential in the search for answers to my questions and in the development of creativity. More than that, as a child, I loved to work on simple experiments I learned on TV shows (unfortunately, the internet was not widely available in the 90s) or to create my own awkward experiments when I got a children’s chemistry kit (but with the simple instructions I would soon lose interest). Curiously, it took me quite a while to realize that combining all these things I did naturally and enjoyably could shape my career. It took a few years until, in high school, the penny dropped, and from there on I set out to achieve a new goal: to become a scientist. I entered the Chemical Engineering course with the intention of participating in Undergraduate Research activities and follow the academic career.

B-MRS Bulletin: Very briefly, what were the main competencies you have developed over the years as an undergraduate research fellow?

Leonardo Mathias Leidens: Basically, the greatest personal and professional development was the training in the “scientific method,” that is, the initial competency for training a scientist. Asking questions, seeking the state of the art and the answers already available for comparison with the presented reality and questioning/comparing the results became daily activities. In order to be able to develop all these research steps, training in complex equipment, data analysis and the proposal of ideas and projects were skills that I had to developed. In addition, throughout my scholarship I was able to improve languages, such as English (the language of science), as well as writing papers more meticulously and aptly for international journals, congresses, reports and projects.

B-MRS Bulletin: In your view, what were the most important factors that contributed to the achievement of the award-winning work?

Leonardo Mathias Leidens: Initially, it was the group’s trajectory, structure and experience in different approaches to minimize the adhesion problem of amorphous carbon films in ferrous alloys that allowed the work proposal and the result achieved, because with broad knowledge of the material system studied, it was possible to investigate in a meaningful way the problem and the positive modifications generated with the use of the hydrogen plasma. In my view, the success was the integration of basic science (the study of physicochemical mechanism of the treatment) with a real problem (to deposit the coatings under milder and efficient conditions on previously problematic substrates), which made the work complete and interesting in the scientific (knowledge generation) and industrial (applications with energy efficiency appeal) scopes.

B-MRS Bulletin: In another interview, you talk about being a scientist as a lifestyle, not just a profession. Tell us about that lifestyle that attracts you.

Leonardo Mathias Leidens: That expression has, fundamentally, two justifications. First, and as I said earlier, the scientific method was one of the most important learning aspects I have experienced over the years. It is applied not only in research but in various activities. Questioning and verifying everything (by tests and comparisons) are a scientist’s requirement, both inside and outside the laboratory. For example, in a society where never-ending information (of different qualities) is available, rigor becomes necessary to compare, select, and verify just how true or secure the sources are. On the other hand, science as a way of life means living science broadly. Integrating a diverse community, participating in projects and partnerships, and being able to make a difference in any area (no matter how small it looks) is much more than a profession. Finally, being part of a group of people who, with different backgrounds, stories and goals, come together and work for the generation of knowledge and advancement of humanity, even with so many difficulties, attracts me, encourages me and is a source of pride.

B-MRS Bulletin: You are currently in the first year of your doctorate. Have you thought about any project or career path after your PhD?

Leonardo Mathias Leidens: My advisor always suggests planning the next five years (at least)… It’s not always easy, especially in very unstable times. Regarding the doctorate, I would like to participate in a sandwich period at a university abroad because, having lived through this experience during my undergraduate studies, I realize the greater importance it would have in my scientific training as a doctor. Later, I intend to follow in the academic career, as researcher, in some institution here in Brazil or abroad.

B-MRS Bulletin: We invite you to leave some tips for our readers who are carrying out scientific initiation work in the area of Materials, answering the question “How to develop a national outstanding work.”

Leonardo Mathias Leidens: It’s not easy to directly suggest ways to produce a distinguished work because, to a certain extent, this is a consequence of a job well done and not the result of a “formula.” However, to reach the goal, I can say that one must take an active role in the research, proposing, without fear or apprehension, well-founded ideas for a problem of the area, even if at the beginning it is difficult and challenging for a undergraduate student. As we produce our own questions, we are encouraged to seek the answers and if they are not available, offer ways to obtain them Thus, with lots of work, dedication and scientific discussion, it is possible to transform a project into an outstanding work that can contribute to the advancement of a specific area and, more extensively, of society. However, one thing is fundamental: do not get absolutely discouraged when things do not go as planned. When we are on the frontier of knowledge, the result is not always the expected result – but this cannot curb the advance for further attempts.

With regards to me, as an undergraduate researcher in the Epipolé Group, I have always had the opportunity to participate actively in projects and discussions (and not only follow graduate students or do “mechanical” work, although these activities are also part of any undergraduate research grant and are important), even as a student of the initial undergraduate periods, and I enjoyed all these moments. This was instrumental in understanding how science is made and integrate with the group. Although greater responsibilities are created in these interactions, they were instrumental in the growth, encouragement and formation of a basis that allowed me to propose my own ideas, after a period of study and practice. For this, reading many scientific articles was also fundamental, besides being always abreast of the innovations of the area, but not forgetting to pay due attention to the scientific foundations, that is, the fundamental concepts.

Featured paper: United atoms, adhered films.

[Paper: Identification of the Chemical Bonding Prompting Adhesion of a-C:H Thin Films on Ferrous Alloy Intermediated by a SiCx:H Buffer Layer. F. Cemin, L. T. Bim, L. M. Leidens, M. Morales, I. J. R. Baumvol, F. Alvarez, and C. A. Figueroa. ACS Appl. Mater. Interfaces, 2015, 7 (29), pp 15909–15917. DOI: 10.1021/acsami.5b03554]

United atoms, adhered films

With an innovative approach on an academic and industrial problem, a study wholly conducted in Brazil has brought significant advances in the understanding of the adhesion of DLC (diamond-like carbon) films on steels. The results of the work, which were recently published in the journal Applied Materials and Interfaces of the American Chemical Society (ACS), can help optimize such adhesion, thus prolonging the life of DLC films and expanding their use in the industry.

The team of scientists was particularly interested in the DLC potential to increase the energy efficiency of internal combustion engines. In fact, if all car engine components were coated with DLC films, the owner of that car would spend 5-10% less fuel and save the environment a good deal of greenhouse gas emissions and other pollutants, among other advantages. The reason for such saving lies in the ultra-low friction of DLC, since friction is the force responsible for wasting fuel while providing resistance to the motion that the parts of the engine make among themselves.

However, DLC has a drawback: it does not adhere to steel, causing quick delamination of the films from the substrate. To work around this problem, both in the laboratory and in industry, it is customary to deposit a layer containing silicon, known as interlayer, over the steel. The DLC film is then deposited on top of it. The result is a “sandwich”, which does not come undone easily.

In the paper published in the ACS journal, the authors experimentally analyzed a “sandwich” consisting of a steel substrate, an interlayer of silicon carbide (SiC) and a DLC film. Both the interlayer and the film were deposited by a quick process that generated thin layers of a few nanometers (up to 10). Mainly, two issues differentiated this study from other similar studies in the scientific literature. Firstly, the team focused in analyzing what happened in two regions corresponding to the interfaces of the interlayer with the film (upper) and with the steel (lower). Secondly, the scientists made a chemical approach on the matter of adhesion.

“This work has identified the chemical structure that generates adhesion in lower (SiCx: H/steel) and upper (a-C:H/SiCx:H) interfaces, which make up the a-C:H/SiCx:H/steel sandwich structure”, said Carlos A. Figueroa, professor at the University of Caxias do Sul (UCS) and corresponding author of the article. “The mechanisms found in the bibliography raised physical or mechanical aspects, but not chemical ones,” said Figueroa, who graduated in chemical sciences from the University of Buenos Aires (UBA) and has a doctorate degree in physics from the State University of Campinas (Unicamp). “However, adhesion is generated by the sum of all individual chemical bonds existing among DLC, the interlayer and steel,” he adds.

Scientists kept a constant film deposition temperature, but varied the interlayer deposition temperature, generating a group of samples deposited at 100° C and another one at over 300° C. After analyzing them by a variety of techniques, especially, X-ray photoelectron spectroscopy (XPS), researchers found that the lower interface of the interlayer, regardless of the deposition temperature, was largely composed of silicon atoms (from the interlayer) bonded to iron atoms (from the substrate). At the upper interface of the interlayer, the team found differences according to the deposition temperature of the interlayer. In the samples deposited at 100° C, oxygen atoms bonded many of the silicon and carbon atoms, preventing the carbon of the film to strongly bond to the silicon of the interlayer, and resulting in a film without good adhesion. In turn, scientists did not find oxygen in the interface of the samples deposited at over 300° C, but bonds between carbon and silicon atoms, which caused the film adhere well to the interlayer.

Schematic illustration of the chemical bonds present in the upper and lower interfaces of the interlayer deposited at 100° C (left) and over 300° C (right). In the center, a real engine cylinder displays, on the left side, a DLC film (in black) delaminated on the interlayer deposited at 100° C and, in the right side, the same film well adhered on the interlayer deposited over 300° C.

Besides Figueroa and students of the research group he leads in UCS, also authored the paper researchers from the Institute of Physics at Unicamp, where the XPS measures were made, as well as a scientist from the Federal University of Rio Grande do Sul (UFRGS) that, together with the other authors, participated in the discussion of results.

The work received the support from Brazilian Science funding bodies (Capes, CNPq through INCT National Institute of Surface Engineering, Fapergs), of Petrobras, UCS, the European Commission (Marie Skłodowska – Curie Actions) and Plasmar Tecnologia (a small company that is developing, through a TECNOVA RS project, an industrial equipment to deposit DLC on steel aiming to increase the energy efficiency of car engines).

SBPMat´s community people: interview with Israel Baumvol.

Israel Jacob Rabin Baumvol was born in Rio Grande do Sul, in the city of São Gabriel, in the last day of 1947. When he was a child, he moved to the city of Porto Alegre with his parents and siblings. When he was 19 years old, he entered the Federal University of Rio Grande do Sul (UFRGS) to study Physics. In the following years, in addition to participating in the political activity that occurred in the university against the existing military government, Baumvol dedicated a lot of effort to his studies, trying to reach the academic standard of the bachelor’s degree in Physics of the university. In 1971, he completed the graduation course – without honors, according to him. In the following year, he moved to the city of São Paulo to take a Master’s Degree in the University of São Paulo (USP), in Nuclear Physics and under the orientation of Professor Oscar Sala. In 1975, he returned to UFRGS to undertake his Doctorate, with orientation of Professor Fernando Zawislak, studying composites of perovskite structures. During the doctorate, he became a professor at UFRGS. In 1977, he defended his thesis. For the postdoctoral course, Baumvol chose an institution of industrial research in England, today known as Harwell campus. There, between 1979 and 1981, he worked with techniques of ionic implantation and its applications, mainly the plasma immersion ionic implantation (PIII), and he took part in research contracts with large companies. Due to his expertise in PIII, Baumvol entered the world of the materials for microelectronics, an area in which he made significant scientific contributions and obtained international reputation.

In the United States, Israel Baumvol was an invited researcher of the IBM research center from 1984 to 1988 and, from 1998 to 1999, of the Bell Laboratories, belonging to company Lucent. In France, between 1992 and 1996, he was a visiting professor at the Université Pierre et Marie Curie and at the Université Paris Diderot (Paris 7). In 1997, after coming first in a public entrance examination, he was nominated full professor at Paris 7, but he did not take over the position to stay in UFRGS. From 1995 to 1996, he was a guest professor of the Ruhr Universität, in Germany.

Baumvol was also coordinator of international events held outside Brazil. In 2000 and 2005, he was coordinator (chairman) of international symposia of Physical-Chemistry of silicon oxide and silicon – silicon dioxide interface, organized by the Electrochemical Society. In 2001, he coordinated the International Workshop on Device Technology of the Materials Research Society (MRS), held in Porto Alegre. In 2004, he was meeting chair of the MRS Spring Meeting & Exhibit, that occurs annually in San Francisco (United States).

In 2003, after retiring from his position of full professor of UFRGS, he led the creation of the Materials Science and Engineering Potgraduation Program of the University of Caxias of Sul (UCS), near 130 km far from Porto Alegre, and he was coordinator and researcher of the program until 2014.

From 2002 to 2003, Baumvol presided the Research Support Foundation of the State of Rio Grande do Sul (FAPERGS). More recently, between 2011 and 2013, he was vice-coordinator of the Materials Department in Capes (a federal agency for higher education improvement). Baumvol also coordinated big projects in the Materials segment, such as the first National Network of Research in Nanostructured Materials (2001-2005) and the National Institute of Surface Engineering (2009 to 2010).

Throughout his scientific career, Israel Baumvol has carried out research in subjects related to ionic implantation, thin layer physics and surface modification, in addition to materials for microelectronics.

Baumvol holds the highest productivity level scholarship in CNPq, the Brazilian federal science council. He has authored over 270 peer-reviewed articles, besides books and book chapters. His scientific production has approximately 3,000 citations. He acted as advisor in about 30 Master’s Degree and Doctorate dissertations.

In 2000, he was chosen Prominent Researcher by FAPERGS; in 2010, he was nominated Commander of the National Order of the Scientific Merit by the Presidency of the Brazilian Republic and in the following year, he was named Professor Emeritus by UFRGS. In May of this year, the “Professor Israel Baumvol Microscopy Center” was inaugurated in UCS.

Here is an interview with the scientist.

SBPMat newsletter: – Tell us what led you to become a scientist and to work in subjects of the Materials field.

Israel Baumvol: – It was the junction of three factors. The first one was the desire to use my knowledge one day to be able to contribute to the progress of the country and its citizens. This desire was developed through reading and great political participation during the graduation course. However, seeing as in Porto Alegre the tradition of basic research was very strong and there was nobody working in applied physics, I had a strict academic formation, that was very good for my future. The second factor was my post-doctorate, for which I chose an institution of industrial research, in England. I went there in 1979 to learn ionic implantation, because the institution was a pioneer in this method. There, I became acquainted with ionic implantation, specially its applications, such as reduction of the friction in metallic components (for example Ti-Al alloys) by means of implantation of species and heavy ionic composites, increase of the resistance to wear and corrosion of steel by nitriding, oxinitriding and nitrocarburizing using the method of ionic implantation by immersion in plasma (PIII). At that time, they were constructing there the first industrial-scale reactor of PIII, with a volume of approximately 30 m3, which was later spread throughout the world, including by companies that manufactured these reactors, such as Eaton and several others, including two companies in Brazil. This environment of applied physics fascinated me due to its possibilities. I participated in many research contracts, such as the one about bone prosthesis for a Japanese manufacturer, another about turbine blades for Rolls-Royce and another on cut blades for the future electric shavers project for Philips. These projects, in addition to fascinating me, had a component that for me was romantic: they were confidential projects. The third and last factor occurred by the end of my post-doctorate. I went to a congress in Germany, where I gave a 50-minute lecture, something very difficult nowadays, when the lectures only last about 20 minutes. When I finished speaking and answering questions, there was a coffee break. Dr. James F. Ziegler came up to me, introduced himself and gave me his business card, in which it was written “Research Director, Thomas J. Watson Research Center, IBM”. He invited me to go there because, during my lecture, he thought that the PIII method could solve a serious problem that IBM had with hard drives. Yet again, the siren song of a confidential project. I accepted the invitation and, for some years, during winter and summer vacations, three to four months per year, I went to IBM – Yorktown. There, I got in touch with something unusual for me, the silicon technology, which was just being born. That was yet another allure and my mind was made, Materials Science and Engineering.

SBPMat newsletter: – What are, in your own evaluation, your main contributions to Materials field?

Israel Baumvol: – I worked in many different subjects in my professional activity, some of them mentioned above. I will highlight three of them. The first one was my participation in the beginning of the PIII technology, which is nowadays widely used in the whole world, also in Brazil, where there are at least four services of PIII processes of steel components for the metal-mechanics industry. The second one is my contribution, throughout ten years of work, to explore and to reach the physical limits of silicon oxide as gate dielectric in the metal oxide semiconductor (MOS) technology. I formed a network of cooperation with academic laboratories in four different countries and with industrial laboratories, including IBM, Motorola, Texas Instruments, Bell-Lucent. We reached the physical limit, 1 nm. From there, the entire network started to work on a substitute for silicon oxide, which was the first change in the MOS technology, after forty years. There was a convergence for hafnium oxide and, eventually, certain hafnium-based double oxides. This material stood out, allowing an increase of processing speed and today it is used as gate oxide in advanced processors. It allowed the continuity of the Moore Law, which was threatened. This research segment led to the formation of a golden generation of PhDs, all around gate oxide, which is a crucial subject for the micro and nanoelectronics.  Many of them are acting professionally in industrial companies, in technology of silicon and in other activities.  Finally, I highlight the creation of a research environment in Materials Science and Engineering and of a post-graduate program in this segment. I started this activity with only one element: Caxias do Sul and its environs possess a large number of industrial companies, small, average and large companies needing research and human resources qualification. Only this, nothing more. Then, from nothing, I gathered some young high-qualified doctors and built the desired research environment, with many excellent laboratories and a very respectable post-graduation program. The impact on the industrial context of the region is notable and very recognized.

Bulletin of SBPMat: – Leave a message for our readers who are initiating their careers of scientists.

Israel Baumvol: – Follow your heart and not convenience. Take advantage of the doctorate, because this is the best time of the career: creative research and free from administrative responsibilities. Do not hesitate in showing your ideas. New ideas are not necessarily bad ideas. Use your post-doctorate to get in touch with the new and the unknown. Do not look for a place that works with the same subject of your doctorate research. Do not hesitate in changing the field, this is very stimulant and constitutes an important factor of individual progress. I pity the professionals who continue working in the subject of their doctorate theses, ten or twenty years after the conclusion. Applied research can very be good research. Get rid of preconceptions, it does not matter if the research is fundamental, or applied or directly industrial. What counts is quality. The only difference is between good quality research or bad quality research.

An anniversary at the materials research community: 10 years of PGMAT – UCS.

Faculties and students receiving lab equipment through a window in 2007.

This August records the 10th anniversary of one of the 31 Brazilian graduate programs in the field of Materials: the Graduate Program in Materials Engineering and Science of the University of Caxias do Sul (PGMAT – UCS in Portuguese).

PGMAT-UCS history dates back to the year of 2003, when Israel Baumvol, physicist and researcher in the area of Materials, was invited by authorities of UCS to lead the creation of a graduate program in this field of knowledge. Baumvol was, at the time, retiring from his position as professor at the Brazilian Federal University of Rio Grande do Sul (UFRGS).

In August, 2004, after conducting a selection process that had 85 applicants for 15 vacancies, PGMAT-UCS started the activities of its Master’s Degree course under the coordination of professor Baumvol. The program then had some laboratories that already existed at the university and a few professors with PhD, and offered the only graduate course at the university in the area of Sciences and Engineering.

Nowadays, the program has more than 20 laboratories and an all its professors hold PhDs. Since 2012, PGMAT also offers a doctoral program, which currently has 19 students.

The same room is today the Laboratory for Surface Characterization at the Nanoscale and has a GDOES analyser, among other instruments.

Another achievement of the program was the signing of an agreement with the European School of Engineers in Material Engineering (EEIGM, in the French acronym) for double degree. Two Masters have graduated with this double degree program after performing academic activities at UCS and EEIGM, headquartered in Nancy, France.

Regarding scientific production, more than 300 articles were published in international journals by faculty and students of the program in its 10 years of existence.

Impact of the research on the industry

From the beginning, the PGMAT-UCS team has pursued the interaction with local companies, based on the affinity that Science and Engineering of Materials have with almost all industrial segments. Thus, already in 2003, the UCS faculty involved in creating the program had visited companies of Caxias do Sul to appraise their needs.

On several occasions throughout its history, PGMAT-UCS could count on resources of companies and entities of the industrial sector, especially the Union of Metallurgical, Mechanics and Electric Equipment Industries of Caxias do Sul (SIMECS), which complemented the public funds in the purchase of equipment for the laboratories of the program.

Inauguration of the Laboratory for Surface Engineering and Thermal Treatments in 2007: local industry was there. Speaking, professor Baumvol.

In 10 years of existence, PGMAT-UCS has graduated 90 Masters. Among them, 45% work in local companies, 10% are academics and 30% are ongoing or concluded their Doctorate degree.

In some cases, the own Master’s research works were essential to the development of new products in the region. This was the case with the Celtrav®, a high-performance material to be used in springs and stops, which composes the product portfolio of the company Travi. A Masters research at PGMAT was also important in developing a coating for ornaments used by the footwear manufacturer Grendene. According to the company, about 18 million pairs of shoes with these ornaments were sold in 2013.

Young entrepreneurs who founded companies from works developed at PGMAT are also among the students and graduates of the program.  Plasmar Tecnologia, one of these spin-off companies, currently provides service for hundreds of industries in the region with plasma-based surface treatments that improve the performance and the cycle life of molds, matrices and other parts and components. The other example is Fineza, a company recently created, dedicated to manufacturing and commercializing products for housing and kitchen with decorative coatings that had been optimized in a PGMAT master’s thesis.