People from SBPMat community: Prof. Aloísio Nelmo Klein.

Aloísio Nelmo Klein
Aloísio Nelmo Klein

Aloísio Nelmo Klein was born on December 5, 1950 in Passo do Faxinal, a small village populated by German descendants in the state of Rio Grande do Sul (south of Brazil). During his childhood in this rural environment, he cultivated a special taste for solving technical problems of everyday life, quite like his father. Still a child, he started working on steel and constructing mechanisms for toys. At the age of 14, he moved to the nearby town of Cerro Largo to complete his secondary studies in a boarding school. In 1969, he moved to Viamão, on the outskirts of Porto Alegre, about 500 kilometers from his home, after successfully passing a selection process to study technical education at the competitive Technical School of Agronomy (ETA). This environment sparked a strong interest in Physics, Chemistry and Mathematics. He graduated from ETA at the end of 1971.

Klein graduated in Physics from the Federal University of Rio Grande do Sul (UFRGS) in 1976. He received his master`s degree in Mining, Metallurgical and Materials Engineering at this same university in 1979. In 1983, he defended his PhD thesis in Engineering, in the area of powder metallurgy and sintered materials from the Technical University of Karlsruhe (Germany), now the Karlsruhe Institute of Technology (KIT).

Klein has been a professor at the Federal University of Santa Catarina (UFSC) in Florianópolis since 1979. He was one of the leaders in introducing Materials Science and Engineering at this institution. He has been in charge of the Laboratory of Materials (LabMat) since 1984, a well-known multidisciplinary space, mainly due to its research and development work carried out with companies. Relying on the team and infrastructure consolidated around LabMat, Klein led the creation and was the first coordinator of the postgraduate program in Materials Science and Engineering (PGMAT) at UFSC, responsible for producing masters and doctors since 1994, and also the Materials Engineering course at UFSC, which began its activities in 1999.

Throughout his career, Klein has made relevant contributions to the development of equipment and processes for manufacturing materials from powders and the applications of plasma technologies, considering that some of these developments have been successfully introduced in the market through partnerships with companies.

Klein has been an active participant in SBPMat since it began. He was part of the committee responsible for creating the society in 2001, and was also the scientific director on two occasions (2004-2005 and 2010-2011) and member of the Deliberative Council and coordinator of the annual meetings of the society in 2006 and 2012, both held in Florianópolis.

Klein also participated in the creation, in 1993, and governance of the Ceramic Center of Brazil (CCB), dedicated to certifying the quality of ceramic products.

CNPq Productivity Fellow – Level 1 A – Professor Aloísio Klein is the author of more than 60 patent applications filed in offices in Brazil, Europe, the United States, China, South Korea, Japan, Taiwan, Singapore and Australia, and at least 8 of these patents have already been granted (the others are under examination). According to the SCOPUS database, Klein is also the author of more than 130 published articles, which have more than 700 citations.

Regarding the training of human resources, Professor Klein has already supervised 41 master’s and 27 doctoral students, as well as dozens of undergraduate and postdoctoral studies, and has mediated more than 100 UFSC student participation abroad for internships , exchanges and postgraduate courses.

Many of his works have been honored with awards from Finep, Brazilian Ceramic Association, Brazilian Metallurgy and Materials Association and UFSC, in addition to other entities.

Here is an interview with the researcher.

SBPMat Bulletin: – Tell us what led you to become a scientist and eventually work in the Materials area.

Aloísio Klein: – The technical area always fascinated me, especially as my father who had no advanced education, was so interested in solving technical problems and fixing things, including watches, musical instruments, guns, cars, tractors, agricultural tools and so forth. I was still a child when I started to be interested in this and lend a hand.  I helped making toys like for instance wheelbarrows with steering, brakes, springs, and traction levers, things that did not exist 55 years ago. Before primary school, I helped to make helical springs for toys, rolling the steel wire, quenching and tempering in the fire, surrounded by charcoal. The temperature reading was done by the color of the heated object. At the age of 14, I entered the São Jose Seminary boarding school in Cerro Largo (RS), where I stayed for 5 and a half years. It was an excellent school, the teachers were well prepared. The principles and values I had acquired from my family and where I was born and raised were further reinforced in the Seminary – which I still hold. I learned other things at the boarding school, which were very important in the future: how to live in a group environment and learn how to share, despite having little; help those in need and so forth. Furthermore, Greek and Latin classes gave me the opportunity to learn how to express myself well orally and in writing. In fact, I have never regretted having studied there, because I learned humility and how to deal with the work environment. I believe that living in boarding school helps develop the ability to get along in groups and understand early on that this is really important. After leaving the Seminary I went to study at ETA (Technical School of Agronomy) in the municipality of Viamão (RS). This was a state school, where you could live (boarding school) and study for free, which is why I pushed myself to study there. ETA was a disputed public school (as were most public schools at the time!). There were about 20 candidates per vacancy in 1969, when I was accepted.  The years I spent at ETA were excellent. However, the disciplines that interested me the most were not those related to Agronomy, they were Physics, Chemistry and Mathematics. I graduated from ETA in December 1971 and in March 1972 I started the Physics course at the Institute of Physics at the Federal University of Rio Grande do Sul (UFRGS).  I graduated in December 1976 and started a master’s degree in the post-graduate program in Mining, Metallurgy and Materials Engineering at UFRGS in March 1977, which I conclude in January 1979. On February 5 of 1979 I was hired as a professor in the Department of Mechanical Engineering at the Federal University of Santa Catarina (UFSC). Also in November of 1979 I went to Karlsruhe, Germany, to enter the PhD program in Materials, in the Subarea of Powder Metallurgy and Sintered Materials. In August 1983, after completing my doctorate, I resumed my duties at UFSC. And in March 1984, I became the coordinator of the Materials Laboratory (now LabMat) A post I still hold and which I will pass on to my successor, already prepared for this, once I retire.

SBPMat Bulletin: – What do you believe are your main contributions to the Materials area?

Aloísio Klein: – Throughout my career at UFSC, I coordinated many research projects, most of them in partnership with companies. Most of the projects had more technological than scientific goals. This was not by chance but out of conviction. I have always believed (and still do) that science is one of the main driving forces for the development of a nation, in addition to education and quality schools. It is from scientific knowledge that new processes are developed, new engineering functions, new materials and other products, that is, innovation results from scientific knowledge. These projects have always been proposed considering a larger group of people as a team, around 8 to 12 professors (in addition to students and engineers) in order to integrate the knowledge-based specializations necessary for the high-quality development of projects. In addition to colleagues from the departments of Mechanical Engineering, Electrical Engineering and Chemical Engineering, professors from the Physics and Chemistry departments were involved, resulting in a multidisciplinary team. However, the project is successful if the multidisciplinary team interacts interdisciplinarily in order to have a synergistic effect. It’s useless merely dividing the money and the tasks. This aspect has never been very easy to manage. Achieving this has always been much more difficult than the technical-scientific part, because a team is made up of individuals, each with his/her particularities, ambitions, egos, and so on. I personally believe that learning to deal with this was very useful to arrive at the LabMat we have today at UFSC.

Due to developing projects with defined technological goals, many patents have been achieved over the last 30 years, currently included in my curriculum, totaling about 65 patent letters, including processes and products (new components, materials and equipment). In addition to the patents, I am also the author/co-author of 135 international articles in journals and 203 articles in Annals of Conferences. I have mentored about 64 IC students, 41 master’s students, 27 doctoral students and 20 post-doc fellows.

In addition, I led the creation of a postgraduate course in Materials Science and Engineering (PGMAT) which began its activities in 1994, currently a 6 score in Capes, and the undergraduate course in Materials Engineering, which began its activities in 1999, currently with a maximum score in Capes. In fact, success means work and in 2010, as a sign of recognition, I was awarded the prize for outstanding researcher at the Technological Center of UFSC.

I think my main contributions (generally with the participation of doctoral or master’s students) are related to the development of processes and new materials and equipment such as:  a) Conceptual project of the extraction process of organic binders and sintering assisted by DC plasma components produced via injection molding, known as “Plasma Assisted Debinding and Sintering – PADS”. b) Conceptual design of the Hybrid Plasma Reactor. This reactor, besides the anode-cathode system to open the electric discharge, has a set of electrical resistances to maintain the control of the thermal cycle independent of the energy used in the plasma. Then, the energy of the ions and electrons in the plasma environment can be adjusted to assist the reactions of interest, while the additional heat needed to achieve the programmed thermal cycle is supplied by the resistive heating system. The coexistence of these two systems in the same environment, without the electric discharge in the electrical resistances, is very important. This (thermal cycle not dependent on plasma energy) allowed a significant advance in the use of plasma to assist various processes, such as thermochemical and metallurgical treatments, including the processing of materials from powders (powder metallurgy and ceramic processing). c) Conceptual design of plasma nitriding equipment that allows cleaning organic waste and its nitriding in the same thermal cycle, for example, used in parts containing oil residues, such as sintered parts after calibration and machined parts. d) The in situ generation of phases of interest in powder metallurgy, such as the generation of turbostractic graphite from the disintegration of sintered steel carbides, leading to the development of new types of dry self-lubricating sintered steels.  e) Development of new types of non-cobalt hard metal, in which nickel alloys generated in situ during sintering are used as metallic binder phase. f) The constant effort to integrate multidisciplinary teams and work in partnership with the productive sector in my projects. The partnership with EMBRACO, for example, has been going on uninterruptedly for 28 years and will certainly continue after my retirement, given that the successor is fully engaged in this partnership.

It is equally important to mention the intense participation in analysis committees and other activities that are important for the development of science and technology, such as: 1) Member (1989 to 1995) of the technical group of the PADCTII new materials subprogram (MCT/FINEP/CNPq); 2) Two times member of the CA-MM – Advisory Committee on Mines, Metallurgy and Materials of CNPq (1997 to 1999) and (2007 to 2009); 3) Member (1997 to 2001) of the technical group in Sciences and Engineering of Materials (CEMAT) of the PADCT III new materials sub-program of the Ministry of Science and Technology;  4) Member of the evaluation and monitoring committee program of the PRONEX / MCT (1998 to 2003); 5) Member (2007 to 2010) of the study group of the CGEE (Center for Management and Strategic Studies) – Prospective study in Materials;  6) Member of the evaluation committee of the postgraduate courses in the Materials area. Trienal 2010 – CAPES; 7) A total of 32 invited lectures throughout my career as researcher (in companies, conferences and research institutions); 8) I was able to send more than 100 students abroad (undergraduate, master’s and doctorate) to carry out internships, exchanges, masters and doctorates; 9) Ad hoc consultant, mainly the development-funding agencies CNPq, CAPES, FINEP, FAPESC and DAAD (Germany); 10) I participated in the creation and was a full member of the deliberative council of CCB (Ceramic Center of Brazil) from 1993 to 2003; 11) I was vice president of the Ceramic Center of Brazil from 1996 to 2001; 12) I participated in the creation of CTC (Criciuma Ceramics Center, now called CTCma); 13) I led the creation (1994) and was the first coordinator of the postgraduate program in Materials Science and Engineering of UFSC ( PGMAT); 14) I led the creation (1999) and was the first coordinator of the undergraduate course in Materials Engineering at UFSC.

SBPMat Bulletin: – Please leave a message for the readers who are starting their scientific careers.

Aloísio Klein: – The career of researcher is possibly the best career in the world. When we have ideas, society approves the resources so that we can develop our ideas. Even when an idea did not work out, we advanced and reformulated the idea with the acquired knowledge. The environment we work in is a very good environment. There are a lot of smart people and a lot of young people, smart and qualified, full of enthusiasm. When we have a good idea, we soon have plenty of people willing to participate in its development. We’re never alone. When we go to a conference, we also find a very select group of people where you can exchange high level ideas, not only with senior people in the area, but also with very creative and intelligent young people. No competent young person is not funded to attend a conference.

Application submission to the Young Researcher Award for post-docs is open.

YRA-2017The application submission for the “2017 Young Researcher Award” is open until March 31. The award, launched by SBPMat, is now in partnership with E-MRS (European Society of Materials Research).

Postdoctoral fellows, SBPMat members with paid annuity fees, who defended their doctorates as of 2010 can apply. Up to four postdocs will be selected. The winners will be announced on May 15.

The award winners will participate, with lodging expenses paid, in two invitation-only international events: “Forum for the Next Generation of Researchers 2017” (Strasbourg, France, 18-19 November 2017) and “6th World Materials Summit” (Strasbourg, France, 20-21 November 2017).

In the Forum for the Next Generation of Researchers, the SBPMat award winners will be part of a select international group of young researchers and will interact with each other and with world-renowned senior scientists. The program includes activities developed by pairs of young researchers from different countries, their poster presentations and talks from senior scientists.

The World Materials Summit is an event that in addition to the young researchers, brings together representatives of science, business and politics, invited by the event organization to discuss social and economic challenges that Materials Science and Technology can help solve. The theme of this edition will be “materials innovation for the world economy and for a sustainable society.”

 

More information about the award, in the announcement, is available HERE.

Information on how to pay SBPMat’s 2017 annuity and the advantages and reasons to join, HERE.

Registration fee exemption from the E-MRS Meeting for SBPMat students: list of selected students.

With regard to an agreement between SBPMat and E-MRS (European Materials Research Society), the following students, SBPMat members, were selected to receive registration fee exemption from the E-MRS 2017 Spring Meeting (Strasbourg, France, May 22 – 26, 2017), in a selective process in which their registration applications were received by January 31:

  • Fábio Baum (doctoral student in Materials Science, Federal University of Rio Grande do Sul, Brazil)
  • Leonardo Mathias Leidens (undergraduate student in Chemical Engineering, University of Caxias do Sul, Brazil)
  • Luciana Daniele Trino (doctoral student in Materials Science and Technology, Sao Paulo State University Júlio de Mesquita Filho, Brazil)
  • Navadeep Shrivastava (doctoral student in Physics, Federal University of Maranhão, Brazil).

SBPMat congratulates those selected and wishes them a great event.

vencedores da isenção
From the left of the reader: Fábio Baum (UFRGS), Leonardo Mathias Leidens (UCS), Luciana Daniele Trino (UNESP), and Navadeep Shrivastava (UFMA).

Join SBPMat: message from the president.

Dear SBPMat members and materials researchers.

We are starting an early payment campaign for the 2017 annuity, with a special discount until March 31. The reason for this personal message is to emphasize the importance of SBPMat having a large and stable number of members.

We have all seen SBPMat’s tremendous progress, in which over these last 15 years it has already carried out international scientific meetings, bringing together students and scientists from Brazil, catalyzing international cooperation, in addition to many other initiatives.

The strength of our Society depends on the contribution of its members, fundamentally with its research performance and participation in our Annual Meetings, but also its effective membership. In any scientific society, membership is its greatest asset. In addition to collecting resources, to help run the society, a large membership helps attain sponsorships.

Our website highlights additional reasons for becoming a member or renewing membership annuity, as well as information on how to go about it.

Farewell and I hope to count on your support.

Osvaldo N. de Oliveira Jr.

SBPMAT President

B-MRS newsletter. Year 4, issue 1.

 

Brazilian Materials Research Society (SBPMat) newsletter

News update from Brazil for the Materials community

English edition. Year 4, issue 1.

XVI B-MRS Meeting
The submission deadline for symposium proposals was extended until February 12. Click here. 

Visit the event website for firsthand information: important dates, plenarists who have confirmed attendance, sponsors who have confirmed participation, cost of registration fees, team contact info. Click here.

Featured paper

A scientific team headed by researchers from the Brazilian Institute for Space Research (INPE) bypassed, applying a simple method, a characteristic of topological insulators that limits the possibilities of studying these promising materials for technological applications. The study was reported in a paper published in APL Materials. See our news story.

People from the community

We interviewed three young PhDs from the Materials community whose doctoral works were recognized in December, in the 2016 Capes Thesis Award: Antonio Cláudio Padilha, Fernanda Fiegenbaum and Flávio Camargo Cabrera. They talked about the award-winning doctoral theses and left messages for students doing research in this area. Here are the interviews.

We also interviewed Gleison Adriano da Silva, recently graduated in Physics from the Federal University of Amazonas, who won the scientific initiation research award from CNPq in 2016, and also other distinctions for his work on the synthesis and characterization of nanostructured semiconductor materials. Learn more about this young researcher and his award-winning work. 

Professor Elvira Fortunato (New University of Lisbon, Portugal) will receive the 2017 Czochralski Award, awarded by the European Materials Research Society (E-MRS) together with Polish scientific societies. Click here for more information.
Events
  • II Escola de Verão: Desenvolvimento de Fármacos e Medicamentos. Porto Alegre, RS (Brazil). February 13 – 17, 2017. Site. 
  • XXXVII Escola de Verão em Química – UFSCar. São Carlos, SP (Brazil). February 13 – 17, 2017. Site. 
  • Pan-American Polymer Science Conference (PanPoly). Guarujá, SP (Brazil). March 22-24, 2017. Site.
  • 9th International Conference on Materials for Advanced Technologies. Suntec (Singapore). June 18 – 23, 2017. Site. 
  • XXXVIII Congresso Brasileiro de Aplicações de Vácuo na Indústria e na Ciência (CBRAVIC) + III Workshop de Tratamento e Modificação de Superfícies (WTMS). São José dos Campos, SP (Brazil). August 21-25, 2017. Facebook. 
  • IUMRS-ICAM 2017. Kyoto (Japan). August 27 – September 1, 2017. Site.
  • XVI B-MRS Meeting/ XVI Encontro da SBPMat. Gramado, RS (Brazil). September, 10 – 14, 2017. Site.
Featured images
Have you noticed that the background of the SBPMat website has beautiful scientific images? They were provided by the Center for the Development of Functional Materials (CDMF), but the space is open to receive images of all members of the SBPMat community. Write to comunicacao@sbpmat.org.br and propose an image made by you, attaching the file and informing what is shown in the image and what technique was used to carry it out. 


To unsubscribe, click here

 

Featured paper: Adhesive tape to help unlock secrets of topological insulators.

[Original paper: Preservation of pristine Bi2Te3 thin film topological insulator surface after ex situ mechanical removal of Te capping layer. C. I. Fornari, P. H. O. Rappl, S. L. Morelhão, T. R. F. Peixoto, H. Bentmann, F. Reinert, and E. Abramof. APL Materials, volume 4, issue 10 (2016). doi 10.1063/1.4964610. Link para o artigo: http://aip.scitation.org/doi/full/10.1063/1.4964610]

Adhesive tape to help unlock secrets of topological insulators

A study led by researchers at the National Institute for Space Research (INPE) has made a very useful contribution to further advance the understanding of topological insulators, discovered over a decade ago, with promising characteristics to be used in quantum computers and in other applications. The research was reported in a paper recently published in the journal APL Materials.

The research idea began in 2009, when it was confirmed and published that bismuth telluride (Bi2Te3) is a three-dimensional topological insulator, that is, an insulating material with robust conductive states on the surface. Bismuth telluride had been theoretically predicted as a three-dimensional topological insulator in 2007. The experimental confirmation resulted from the observation of its surface topological states using a technique known as ARPES (angle-resolved photoemission).

Na montagem, fotos dos autores do artigo. Começando pela esquerda do leitor: Celso Fornari, Paulo Rappl, Sérgio Morelhão, Thiago Peixoto, Hendrik Bentmann, Friedrich Reinert e Eduardo Abramof.
The authors of the paper. From the left: Celso Fornari, Paulo Rappl, Sérgio Morelhão, Thiago Peixoto, Hendrik Bentmann, Friedrich Reinert and Eduardo Abramof.

The INPE research team then decided to study the properties of bismuth telluride using ARPES. They saw the possibility of starting the research with an equipment available at the Associated Laboratory of Sensors and Materials (LAS) of INPE, which could be used to begin investigations on the manufacturing of topological insulators without requiring new investments. “The Molecular Beam Epitaxy (MBE) equipment installed in LAS/INPE is dedicated to the growth of IV-VI compounds and has a source charged with Bi2Te3 alloys, which is used to dope these compounds,” explains Celso Israel Fornari, the corresponding author of the APL Materials article.

The work was performed in Fornari’s doctorate, started in 2013 and still underway, under the guidance of the researchers Eduardo Abramof  and Paulo Henrique de Oliveira Rappl, and with funding from Brazilian agencies CNPq (federal) and FAPESP (São Paulo State).

The team knew that in order to analyze the samples, they would have to overcome a challenge intrinsic in topological insulators: in contact with air, the surface of these materials rapidly oxidizes, changing its properties and preventing to perform surface analyzes, fundamental to confirm the topological conductive states. Faced with this limitation, only in situ analyses could be carried out (those made in the manufacturing environment, in this case by coupling, through ultra-high vacuum lines, a surface characterization system to the manufacturing system). However, the situ analyses, besides limiting the possibilities to study the material, were not viable within the doctoral work of Celso Fornari, since he would conduct the measurements using ARPES, in Germany, at the University of Würzburg.

Cross-section SEM-FEG image of a bismuth telluride sample protected with an amorphous tellurium cover. Adapted from the image of the APL Mat article [http://aip.scitation.org/doi/full/10.1063/1.4964610] under license CC BY 4.0 [https://creativecommons.org/licenses/by/4.0]
Cross-section SEM-FEG image of a bismuth telluride sample protected with an amorphous tellurium cover. Adapted from the image of the APL Mat article [http://aip.scitation.org/doi/full/10.1063/1.4964610] under license CC BY 4.0 [https://creativecommons.org/licenses/by/4.0]
The scientific literature also indicated other means to find a way around this limitation, either to protect the topological insulator from oxidation by means of coatings, or removing the oxide layer after it is formed. However, all methods eventually caused distortions in the sample in terms of thickness, surface morphology and material composition.

Therefore, the team had to develop a method to protect the surface of the topological insulator, while ensuring the integrity of the samples. The technique developed by the INPE researchers consists of depositing, at room temperature, a layer of amorphous tellurium, soon after the growth of the bismuth telluride.

In the first stage of the project, the team carefully fabricated bismuth telluride films with thickness ranging from 8 to 170 nm, and coated some of them with amorphous tellurium protective layers of 100-200 nm in thickness. The samples were characterized by various experimental techniques to analyze the substrates, films and protective layers. In particular, the INPE team, together with Professor Luiz Morelhão, from the Physics Institute of USP, analyzed the structure of the samples by X-ray diffraction in the Brazilian Synchrotron Light Laboratory (LNLS). Morelhão also collaborated with the INPE team in developing a computational model to simulate the X-ray diffraction curves. “These analyses were fundamental to identify the optimal growth conditions of bismuth telluride,” adds Fornari.

Secondly, the team faced yet another challenge in developing the film protection method. In fact, in Germany, the protective layer had to be removed from the samples without distorting the topological insulation in order to perform the surface analysis.  Following a method that was already practiced by other scientists, the INPE researchers first planned to sublimate the protective layer within the ultra-high vacuum environment of the ARPES equipment.

Metodo_eng
Protective layer removal method. Adapted from image of the APL Mat paper [http://aip.scitation.org/doi/full/10.1063/1.4964610] under license CC BY 4.0 [https://creativecommons.org/licenses/by/4.0]
However, a discovery made by chance changed the team’s plans. “Two weeks before going to Germany, during the last structural characterizations of the samples, we realized that by removing the samples from the X-ray diffraction equipment, the adhesive tape used for fixation was removing part of the protective layer,” states Fornari. It was then that the idea of using a common adhesive tape to completely remove the protective layer of the bismuth telluride film first emerged, a procedure that had the advantage of not requiring the installation of special tools in the analysis system.

In this procedure, the sample is adhered to a sample holder and an adhesive tape is attached to the protective layer. Removal can be done by pulling the tape or by moving the sample holder, as shown in the diagram on the right.

The method of deposition and subsequent removal of the protective layer developed by INPE team worked extremely well. The tellurium protective layer preserved the bismuth telluride samples from oxidation and contamination for about three months during their oceanic and terrestrial trip. The removal of the layer with adhesive tape, performed inside the ultra-high vacuum chamber of the ARPES equipment, was carried out without generating any distortions in the thickness, morphology or composition of the films, and consequently in their properties.

Atomic force microscopy images (AFM) of the surface of bismuth telluride films, 25 nm thickness. On the left, a film that was protected and had the protective layer removed by the method developed by INPE researchers. On the right, a film that was not coated. Comparison of the images shows that the surface of the film was completely preserved after removal of the protective layer.
Atomic force microscopy images (AFM) of the surface of bismuth telluride films, 25 nm thickness. On the left, a film that was protected and had the protective layer removed by the method developed by INPE researchers. On the right, a film that was not coated. Comparison of the images shows that the surface of the film was completely preserved after removal of the protective layer. Adapted from the image of the APL Mat article [http://aip.scitation.org/doi/full/10.1063/1.4964610] under license CC BY 4.0 [https://creativecommons.org/licenses/by/4.0]
The measurements by ARPES technique were done without any problems at the University of Würzburg, under the supervision of Professor Friedrich Reinert and with the assistance of the researchers Thiago R. F. Peixoto and Hendrik Bentmann. The analyses showed the insulating behavior in the volume and conductor behavior on the surface of the bismuth telluride, as well as the robustness of the films.

“This was the first experimental observation of bismuth telluride films with intrinsic insulating behavior analyzed ex situ,” remarks Fornari. “To date only films with intrinsic insulating behavior and grown within the same vacuum system (in situ) have been reported,” he states.

According to Fornari, the results obtained in relation to the method of deposition and removal of the protective layer indicate that it could be applied to other topological insulating materials, besides the bismuth telluride. Good news to those studying these materials, very promising for quantum computing and spintronics, keen to advance their understanding about these properties, which gained prominence in 2016 with the Nobel Prize in Physics. Good news also for society in general, which will probably benefit from their applications.

Interviews with the winners of the 2016 Capes Thesis Award in the field of materials.

We interviewed three winners of the 2016 Capes Thesis Award who carried out their award-winning research papers in postgraduate programs in Materials. The prize was awarded on December 14, 2016, in Brasilia, at the headquarters of Capes agency, linked to the Brazilian Ministry of Education in charge of promoting high standards for post-graduate courses in Brazil.

The Capes Thesis Award was created in 2005 to distinguish the best doctoral theses in each of the 48 areas of the Brazilian postgraduate programs. The theses defended in Brazil in the year prior to the award announcement can compete for the award. The candidates are registered by the postgraduate programs where the scientific research work was performed. The winners are selected by committees formed by members of the scientific community in each area. The evaluation process considers aspects of originality and relevance for scientific, technological, cultural, social, innovation and value added development to the educational system

In 2016, 774 PhD theses were entered. Of these, 48 were selected to receive awards and 88 received honorable mentions.

Here are the interviews with the winners of the awards in the Materials community.

 

Interview with Antonio Cláudio Michejevs Padilha, winner of the Capes Thesis Award in the “Interdisciplinary” area

foto claudioThesis: “Computational simulation of TiO2-based memristive systems: from the raw material to the device”.

Advisor: Gustavo Martini Dalpian. Co-advisor: Alexandre Reily Rocha.

Institution: Postgraduate Program in Nanosciences and Advanced Materials of the Federal University of ABC.

Antonio Cláudio Padilha graduated in Physics with a bachelor’s degree from the University of São Paulo (USP) in 2007. In 2009, he began the master’s degree in physics at USP, where he studied-developed molecular mechanics/quantum mechanics on pentacene agglomerates and carbon nanotubes, mentored by Professor Maria Cristina dos Santos. He defended his dissertation in 2011 and that same year began his doctorate in Nanosciences and Advanced Materials at the Federal University of ABC (UFABC), also in the state of São Paulo, under the guidance of professors Gustavo Martini Dalpian and Alexandre Reily Rocha. In 2015, he spent three months at the National University of Yokohama (Japan), during the “sandwich period”, in the group of Professor Hannes Raebiger. In the Master’s and PhD program, he received a research grant from the São Paulo Research Foundation (FAPESP). At the end of 2015, back in Brazil, he defended the thesis awarded by Capes. Since last year, Antonio Padilha is an associate researcher (postdoc) in the Department of Physics of York University (UK), in the group of Professor Keith McKenna. He is the author of 5 articles published in peer-reviewed international journals.

SBPMat Newsletter: – In your opinion, what is the most relevant contribution of the award-winning thesis?

Antonio Cláudio Padilha: – The thesis presents a possible alternative mechanism for the operation of a new electronic device known as a memristor. This device is formed by a thin film of insulating material with metallic electrodes placed around it. When a high charge is applied through the electrodes under certain conditions, the electrical resistance of the insulation material changes. Interestingly, this change is stable, making it possible to store information in this system.

Many authors point out that the charge applied could cause the atoms inside the insulator to be displaced from their original positions. Therefore, new phases would form in certain regions, which due to different structures and/or compositions, consequently would have different electrical resistivities. This could explain the different electrical resistances initially observed in the devices.

The project that gave rise to the thesis had the objective to describe the processes occurring within the device from computational simulations. We performed simulations to understand the properties of some of the oxygen-deficient phases of titanium oxide, and we realized that these phases could trap and release charges. This process could also change the properties of the material, leading to different electrical resistances and thereby explaining, through another mechanism, the function of the memristor.

There is still much discussion regarding which of these two mechanisms provides the best explanation of the experimental results. However, I believe that one mechanism does not necessarily exclude the other. Our work intended to show that there is probably no single ingredient that explains how these devices function and that the entrapment and release of charges may explain in part what is observed experimentally.

SBPMat Newsletter: – Please cite the main results generated from the award-winning thesis (papers, patents, products, startups, other awards, etc.).

Antonio Cláudio Padilha: – From the results presented in the thesis, we published 3 papers in international scientific journals. Of these, I would like to highlight my last work, a cooperation result with Professor Hannes Raebiger, from the University of Yokohama in Japan. He spent 11 months as a visiting professor at UFABC and later received me in his group for a 3-month research internship. This research collaboration resulted in another article that is in the process of being published.

These papers also helped me to win an award entitled “2015 Post Graduate Academic Excellence Award” awarded by the Postgraduate Office of the UFABC. This award took into account not only the volume but also the quality of the journals in which the articles were accepted.

SBPMat Newsletter: – In your opinion, which are the main factors for your outstanding research work at the national level (your thesis)?

Antonio Cláudio Padilha: –Without a doubt, the funding I received from the São Paulo Research Foundation – Fapesp – was fundamental for the success of the project. Fapesp was responsible for financing my PhD grant, the grant for my internship in Yokohama in Japan (BEPE internship) and it was also crucial to acquire the basic equipment, both through the technical reserve of my scholarships as well as through related theme projects. Professor Raebiger’s visit to UFABC was also funded by Fapesp.

Another important factor was the National High-Performance Data Pocessing Center in São Paulo – Cenapad-SP. It provided infrastructure in the form of supercomputers capable of running the simulations we needed, and also great support, the work we were able to carry out leaves nothing to be desired in relation to other countries that have numerous resources for science, technology and innovation.

Finally, the innovative environment of UFABC and the excellent faculty at the university were decisive factors to give visibility to the thesis through the award. I am particularly grateful to my advisors for their dedication, Professors, Gustavo Dalpian (UFABC, currently Visiting Professor at the University of Colorado – United States) and Alexandre Reily Rocha (IFT-Unesp, currently at MTI – United States) and my unofficial advisor Professor Hannes Raebiger (Yokohama University – Japan, visiting professor at UFABC in 2015).

SBPMat Newsletter: – Please leave a message to our readers, many who are undergraduate or graduate students.

Antonio Cláudio Padilha: – The research activity is full of ups and downs. We often find ourselves for weeks or even months insisting on experiments or simulations that give completely different results or even wrong results than what we had expected. This can be very disheartening, and when combine this scenario with the lack of recognition, the feeling many of us have is to give up our career and try our luck in another area.

However, persistence and dedication will inevitably be rewarded and recognized, we must be patient. Despite the  difficult times ahead for Brazilian science, nothing will be able to destroy the curiosity and beauty of making new discoveries, inventing new solutions and the impetus to make this country a better place for everyone. This difficult phase for Brazilian science will not go on indefinitely, and when this phase is over, those who have endured the difficulties, in addition to being empowered, will be prepared to take advantage of the opportunities that will arise.

 

Interview with Fernanda Fiegenbaum, winner of the Capes Thesis Award in the “Materials” area.

foto fernandaThesis: “New ionic liquids for the production of hydrogen by water electrolysis”.

Advisor: Roberto Fernando de Souza. Co-advisor: Emilse Maria Agostini Martini.

Institution: Postgraduate Program in Materials Science (PGCIMAT) of the Federal University of Rio Grande do Sul (UFRGS).

Fernanda Fiegenbaum studied Industrial Chemistry at the University of Santa Cruz do Sul (UNISC), in Rio Grande do Sul, between 1998 and 2004. During this period, she carried out research activities in polymer laboratories. In 2005, she joined the Master’s Program in Chemical Engineering (PPGEQ) in the Federal University of Rio Grande do Sul (UFRGS), where she conducted research in the field of polymers, under the guidance of Professor Nilo Sergio Medeiros Cardozo, financed with a CAPES grant. She defended her dissertation in 2007. In 2011  she returned to UFRGS to continue her academic training in the PGCIMAT doctoral program, with a grant from the Research Support Foundation of the State of Rio Grande do Sul (FAPERGS). Under the supervision of Roberto Fernando de Souza and Professor Emilse M.  A. Martini, she developed a research project on the use of new ionic liquids for the production of renewable energies. The thesis was defended in 2015 and that same year Fernanda went to Germany to undertake a postdoctoral internship at the University of Ulm, at the Institute of Electrochemistry. She returned to Brazil and UFRGS in June 2016. She is the author of 4 papers published in peer reviewed international journals and holds a patent application for innovation at INPI.

SBPMat Newsletter: – In your opinion, what is the most relevant contribution of the award-winning thesis?

Fernanda Fiegenbaum: – Currently, finding new environmentally friendly energy sources, that when used do not generate CO2, is an urgent challenge. Hydrogen gas is an energetic vector and its use does not generate pollutants, but it must be produced with a high degree of purity, which has a considerable cost. In my doctoral thesis, I synthesized new ionic liquids based on tetra-alkyl-ammonium-sulfonic acids that were used as electrolytes for the production of hydrogen gas by water electrolysis. The use of this new class of materials showed catalytic effect and compatibility with several materials (carbon, stainless steel) used as low cost electrodes, thereby increasing efficiency and reducing the cost to produce hydrogen gas. Therefore, I believe these results represent the major contribution of my thesis.

SBPMat Newsletter: – Tell us about the main results generated from the award-winning thesis (papers, patents, products, startups, other awards, etc.).

Fernanda Fiegenbaum: – The new acid ionic liquids of the tetra-alkyl-ammonium sulfonic family were patented, BR1020120275333: A process for the production of hydrogen by electrolysis of water using ionic liquids such as tetra-alkyl-ammonium sulfonic acid salts, its derivatives and product.

Four papers were published in high-impact international journals. Moreover, these results were disseminated in several national and international conferences: Greenchemistry 2012, CBCat 2013 and 2015, SBQ 2014, WiCaC 2014 and SIBEE 2015.

SBPMat Newsletter: – In your opinion, what are the main factors that allowed you to carry out outstanding research work at the national level (your thesis)?

Fernanda Fiegenbaum: – There were many factors that enabled the thesis award. But I believe there are some fundamental points.

Foremost and certainly the main factor is with regard to the guidance, support, help and teachings of my advisors, Professors Roberto Fernando de Souza (in memoriam) and Emilse M. A. Martini, which enabled the successful completion of my PhD.

Definitely, my ability to accept new challenges was decisive, for instance, search the literature for the scientific basis on the synthesis of materials and modern techniques of characterization. This search helped increase my understanding about the role of the electrolyte on the process of electrolysis of water and I designed an ionic liquid with the proper properties, but without the undesirable characteristics, such as a toxic and corrosive agent.

The laboratory where I was able to conduct my activities, Laboratory of Reactivity and Catalysis (LRC) of the Federal University of Rio Grande do Sul (UFRGS), has the necessary modern equipment and laboratories adapted to carry out the synthesis, characterization and application of these new ionic liquids. The financial support of various development agencies to the LRC allowed acquiring the reagents and equipment.  Moreover, I had access to the high quality infrastructure of the Institute of Chemistry of UFRGS, Center of Microscopy (CME) and CNANO, support agencies of UFRGS and fundamental for high quality scientific production.

Another important factor was the collaboration of colleagues and other professors at LRC, which I portray as a motivating and supportive relationship that was fundamental to develop my thesis.

SBPMat Newsletter: – Please leave a message to our readers, many who are undergraduate or graduate students.

Fernanda Fiegenbaum: – The message I would like to pass on to those who are starting or continuing their studies is that despite the everyday difficulties and stress, at the end of the day, it is extremely gratifying to participate in the scientific construction of solutions to the great challenges in Brazil and the world. Brazil is a country where cutting edge research is carried out and with excellent researchers and laboratories that compete with “first world countries”. However, we must not forget that continuous support is fundamental to value and give continuity to everything that has already been achieved.  I end with a quote by Marie Skłodowska-Curie: “Nothing in life is to be feared, it is only to be understood. Now is the time to understand more, so that we may fear less.”

 

Interview with Flávio Camargo Cabrera, who won an honorable mention of the Capes Thesis Award in the “Materials” area.

foto flavioThesis: “Natural-rubber-based microfluidic device (lab-on-a-chip)”.

Advisor: Aldo Eloizo Job.

Institution: Post-Graduate Program in Materials Science and Technology (POSMAT) of the Paulista State University “Júlio de Mesquita Filho”, Presidente Prudente campus (UNESP/PP).

Flávio Camargo Cabrera completed his undergraduate studies in Physics (2006 – 2009) at UNESP/PP,  Master’s in Materials Science and Technology (2010-2012) and a PhD in Materials Science and Technology (2012-2015). Starting in the undergraduate scientific initiation up to the doctorate, he developed research projects based on the use of natural rubber, always under the guidance of Professor Aldo Eloizo Job and with FAPESP grants. He is currently associated with POSMAT of UNESP as a CAPES postdoctoral fellow. He is the author of 15 papers published in peer reviewed international journals and one patent application.

SBPMat Newsletter: – In your opinion, what is the most important contribution of the awarded thesis?

Flávio Camargo Cabrera: – The thesis presents a new concept of flexible microfluidic device using natural rubber as an alternative, organic, biocompatible, easy to handle and low cost material, for the preparation of lab-on-a-chip platforms.

The use of new materials opens up a range of new applications based on the properties of these materials. The largest contribution is that it highlights the importance of Materials Science for the development of pre-existing technologies. We believe that with the evolution of preparation techniques and miniaturization, it is possible to develop implantable biological sensors from this new polymeric device concept.

SBPMat Newsletter: – From your perspective, what are the main factors that allowed to carry out a research work highlighted at the national level (your thesis)?

Flávio Camargo Cabrera: –  The interdisciplinarity and partnership between the FCT UNESP, Presidente Prudente campus and the Bioelectrochemistry group coordinated by Professor Frank Crespilho of IQSC (Chemistry Institute of USP in São Carlos), was fundamental to undertake the project. In addition, INEO projects (National Institute for Organic Electronics) and FAPESP financing (Proc. 2011/23362-0) provided conditions for developing the project.

SBPMat Newsletter: – Please leave a message to our readers, many who are undergraduate or graduate students.

Flávio Camargo Cabrera: – When we graduate, we are tempted to fight for survival, the ideal to graduate, publish a paper, achieve indices, seek recognition, and others. Not that this is a bad idea, but you should not let this tendency take away your possibility to stop for a moment, a day, a week, to reflect, think about, allow your dreams and ideas to beyond the limit known as impossible and materialize them, it may be we do not solve the big questions of the universe, but we may serve as an incentive so that one day someone can do it.