Featured paper: Designing structures to manipulate light.

[Paper: Oxide-cladding aluminum nitride photonic crystal slab: Design and investigation of material dispersion and fabrication induced disorder. Melo, EG; Carvalho, DO; Ferlauto, AS; Alvarado, MA; Carreno, MNP; Alayo, MI. Journal of Applied Physics 119, 023107 (2016). DOI: 10.1063/1.4939773.]

Designing structures to manipulate light

Photonic crystals are nanostructures capable of manipulating visible light and other forms of electromagnetic radiation by organizing its structure in periodic patterns.

In addition to the natural materials with these characteristics, such as opal, photonic crystals are man-made and are generally classified as metamaterials. Its characteristics (shape, size and composition) are designed to control light waves. Through nanofabrication processes these become tangible structures and are used in many “nanophotonic” devices. Nevertheless, producing these structures is by no means a simple task.

The authors of the article. From left to right, at the laboratory: Prof. Marcelo Nélson Paez Carreño, Emerson Gonçalves de Melo, Maria Elisia Armas Alvarado and Prof. Marco Isaías Alayo Chávez. At the insets: Daniel Orquiza de Carvalho (left), André Santarosa Ferlauto (right).

With a study based on computer simulations, a team of Brazilian scientists headed by researchers from the Polytechnic School of the University of São Paulo (EPUSP) presented scientific contributions that can be used to improve the production of photonic crystals to enhance their performance of manipulating light. According to Emerson Melo, the first author of a paper on the study that was recently published in the prestigious Journal of Applied Physics (JAP) “the work presents a detailed analysis of the effects caused by nanofabrication processes on the optical properties of planar photonic crystals produced on silicon dioxide-cladding aluminum nitride”.

“The idea emerged from the opportunity of combining the excellent optical and physical characteristics of aluminum nitride (AlN), such as transparency over a wide wavelength range (from the near infrared to the ultraviolet range), its non-linear effects, great stability and temperature variations, with the advantages provided by photonic crystals, such as the construction of high-efficiency waveguides, curves and resonant cavities in nanoscale dimensions, in addition to the various optical effects of photonic crystals, such as very low group velocity and low-intensity nonlinear effects of the materials”, adds Emerson,  who is a doctoral student in Microelectronics – Photonics in EPUSP, within the Group of New materials and Devices of the Microelectronics Laboratory of the Department of Electronic Systems Engineering. Emerson`s doctoral research, whose advisor is Professor Marco Isaías Alayo Chávez, enquires into the study, production and characterization of nanophotonic devices such as waveguides, resonant cavities, optical modulators and switches in aluminum nitride photonic crystals.

The study that resulted in the paper published in the JAP began with an experimental stage. Thin films of aluminum nitride and silicon dioxide (SiO2) were manufactured by the EPUSP group, and with the research collaboration from UFMG and UNESP they were analyzed by the Variable Angle Spectroscopic Ellipsometry (VASE) technique to determine the dielectric functions, which was later used as the theoretical research data.

On the left, a diagram of a photonic crystal structure with some of the manufacturing defects studied. On the right, a diagram of the unit cell of the ideal photonic crystal designed by the scientists.

Then, the EPUSP group designed a photonic crystal, ideal in terms of performance and manufacturing possibilities, consisting of a layer of aluminum nitride between two silicon dioxide layers, with round holes arranged in a repeating pattern along the “sandwich” material. Using analytical and numerical methods, the USP researchers simulated some of the “side effects” of the photonic crystal manufacturing processes of this type (e.g., variations of size and location of holes) and theoretically analyzed how these imperfections affect the performance of the photonic crystal.

The theoretical research of Emerson and the other researchers of EPUSP focused on the imperfections generated in the two main stages of the nanofabrication process normally used in photonic crystals such as the one studied: electron-beam lithography and plasma-assisted dry etching. “The results presented allow to assess that the electron-beam lithography process has greater effect on the performance of devices that explore the dispersion of electromagnetic radiation through the photonic crystal, such as prisms, optical switches and modulators”, says Emerson. “However, the quality of the dry etching process has a more profound impact on the characteristics of devices into which linear or exact defects are introduced in the periodic network of the photonic crystal to insert harmonic modes within the photonic band gap. In this case, the dry etching has to be extremely well controlled for manufacturing the devices where waveguides and resonant cavities are among its main elements”.

In addition to making headway in understanding the role of nanofabrication processes of photonic crystals in the performance of nanophotonic devices, the authors of the paper were able to define a method to design planar photonic crystals with core and cover in thin film dielectric materials. “The methodology includes determining the dielectric function of the material by the spectroscopic ellipsometry technique to analyze the dispersion effects of the materials,  determining the geometrical parameters that maximize the photonic band gap and the analysis of the impacts caused by deviations introduced in the manufacturing process”, explains Emerson.

The research received financial support from the National Council for Scientific and Technological Development (CNPq) and from the Financier of Studies and Projects (Finep).

The authors of the article. From left to right, at the laboratory:.

Interviews with plenary speakers of the XIV SBPMat Meeting: Nader Engheta.

Photo of Prof. Nader Engheta superimposed with some of the images related to his research. Credit: University of Pennsylvania photographer Felice Macera.

Materials created by applying the state-of-the-art in materials science and engineering and nanotechnology can make light and other electromagnetic waves behave in an extraordinary way, becoming very useful for applications in several fields.

To talk about this issue in the XIV SBPMat Meeting, Professor Nader Engheta (University of Pennsylvania, USA) will be in Rio de Janeiro in the end of September. Engheta is a recognized world leader in research on metamaterials – man-made materials created through micro or nanoengineering, and capable of interacting with electromagnetic waves in ways not found in nature.  Metamaterials can sculpt the waves in order to achieve unconventional light-matter interaction.

In Rio de Janeiro, Engheta will talk about extreme scenarios generated from metamaterials: light traveling at full speed through artificial structures, one-atom-thick optical devices, metamaterials that perform mathematical operations, miniaturized circuits – optical rather than electronic – composed by metamaterials, and structures with effective refractive index near zero.

In his childhood in Tehran (capital of Iran), Nader Engheta developed a special curiosity to understand phenomena related to waves. This curiosity propelled him to attend and get a BS degree in Electrical Engineering at the University of Tehran. In 1978, he came to the United States to pursue his post-graduate (master’s and PhD degrees), also in Electric Engineering, carried in the prestigious Caltech (California Institute of Technology), in the United States. In 1982, he got his PhD diploma from Caltech, with a dissertation in the field of electromagnetism. After a post-doctorate at the same institution, Engheta worked as a scientist in the industry for four years, working again with electromagnetism.  Then he joined the faculty of the University of Pennsylvania in Philadelphia in 1987, and was swiftly promoted through the professorial ranks, and now he is the H. Nedwill Ramsey Professor of Electrical and Systems Engineering, with affiliations in the departments of Electrical and Systems Engineering, Physics and Astronomy, Bioengineering and Materials Science and Engineering.

Owner of an H number of 69 according to Google Scholar, Engheta has more than 21400 citations. Besides being author of 28 book chapters and numerous journal articles and conference presentations, Engheta is coeditor of the book “Metamaterials: Engineering and Physics Explorations”, released in 2006 by Wiley-IEEE publisher. In 2012, he chaired the Gordon Research Conference on Plasmonics.

His contributions to science and engineering have received important recognitions and distinctions from several entities, as the international society of optics and photonics, SPIE (“2015 SPIE Gold Medal”), the international union of radio science, URSI (“2014 Balthasar van der Pol Gold Medal”) and the international professional association of electric and electronic engineers, IEEE (“2015 IEEE Antennas and Propagation Society Distinguished Achievement Award”, “2013 Benjamin Franklin Key Award”, “2012 IEEE Electromagnetics Award”, “IEEE Third Millennium Medal”), among many other entities. He is also Fellow of six international scientific and technical organizations, namely, Materials Research Society (MRS), American Physical Society (APS), Optical Society of America (OSA), American Association for the Advancement of Science (AAAS), SPIE, and IEEE.  Engheta also received several teaching awards.  In 2006 the Scientific American Magazine selected him as one of the 50 Leaders in Science and Technology for his development of metamaterial-inspired optical nanocircuitry.

Here follows an interview with Professor Nader Engheta.

SBPMat newsletter: – In your opinion, what are your most significant contributions on issues related to the topic of your plenary lecture? Explain them very briefly and if possible, share references of resulting papers or books, or comment if these studies have produced patents, products, spin-off companies etc.

Nader Engheta: – I am very interested in light-matter interaction, and in my group we explore different methods in manipulating and tailoring interaction of waves with material structures, both in the optical as well as microwave domains.  I am very excited about all the research topics my group and I have been working on.  Some of these topics include (1) The optical metatronic nanocircuitry, in which we brought the notion of “lumped” circuit elements from electronics into the field of nanophotonics, developing a new paradigm in which material nanostructures may function as optical circuit elements.  In other words, “materials become circuits” working with optical signals.  In this way, nanophotonics can be modularized, in an analogous way as in electronics.  This allows one to perform optical signal processing at the nanoscale, (2) Metamaterials that can do math:  following our work on optical metatronics, we are exploring how properly designed materials (e.g., layered materials) can interact with light in such a way that one can do mathematical operations with light.  In other words, we are exploring the following questions:  Can materials be specially designed to perform analog processing with light at the nanoscale?  As light propagates through such properly designed material structures, would the profiles of the output signals resemble the results of certain mathematical operations (such as differentiation or integration) on the profiles on the input signals?  In other words, can we design materials for specific mathematical operations in order to do “photonic calculus” at the nanoscale?  (3) The extreme scenarios in light-matter interaction: this may include extreme dimensionality, like graphene photonics as the one-atom-thick platform for light manipulation, extreme metamaterials in which material parameters such as relative permittivity and relative permeability attain near-zero values.  This category of materials, which we have named epsilon-near-zero (ENZ), mu-near-zero (MNZ) and epsilon-and-mu-near-zero (EMNZ) materials, exhibit very interesting features in their response to electromagnetic wave interaction.

References:

  • N. Engheta, “Circuits with Light at Nanoscales:  Optical Nanocircuits Inspired by Metamaterials”, Science, 317, 1698-1702 (2007).
  • N. Engheta, A. Salandrino, A. Alu, “Circuit Elements at Optical Frequencies:  Nano-Inductor, Nano-Capacitor, and Nano-Resistor,” Physical Review Letters, 95, 095504 (2005).
  • N. Engheta, “Taming Light at the Nanoscale,”  Physics World , 23(9), 31-34 (2010).
  • A. Vakil and N. Engheta, “Transformation Optics Using Graphene,” Science, 332, 1291-1294 (2011).
  • A.Silva, F. Monticone, G. Castaldi, V. Galdi, A. Alu, and N. Engheta, “”Performing Mathematical Operations with Metamaterials,” Science, 343, 160-163 (2014).
  • M. G. Silveirinha and N. Engheta, “Tunneling of Electromagnetic Energy through Sub-Wavelength Channels and Bends Using Epsilon-Near-Zero (ENZ) Materials,” Physical Review Letters, 97, 157403 (2006).
  • N. Engheta, “Pursuing Near-Zero Response”, Science, 340, 286-287 (2013).
  • A.M. Mahmoud and N. Engheta, “Wave-Matter Interaction in Epsilon-and-Mu-Near-Zero Structures”, Nature Communications, 5:5638, December 5, 2014.

SBPMat newsletter: – Help us visualize the metamaterials developed by your group. Please choose one of your favorite photonic materials and tell us, very briefly, its composition, its main properties and its possible applications.

Nader Engheta: – One of the structures developed by my group is the optical metatronic nanocircuits for mid-IR regime (from 8 to 14 microns), in which we properly tailored and constructed nanorods of Si3N4 with specific widths and thicknesses, separated by a specific gap.  These arrays of Si3N4 nanorods function as collections of optical nanoinductors, optical nanocapacitors and optical nanoresistors in mid IR.  We demonstrated that such structures behave as nanoscale optical circuits, with functionality analogous to electronic filters, but here these material structures operate in the mid IR regimes.  We have shown how these structure operate as optical filters in the mid IR, offering exciting applications for future integrated optical devices and components.

Reference:

  • Y. Sun, B. Edwards, A. Alu, and N. Engheta, “Experimental Realization of Optical Lumped Nanocircuit Elements at Infrared Wavelengths,” Nature Materials, 11, 208-212 (2012)

Later, in collaboration with my colleague Professor Cherie Kagan and her group at UPenn, we extended this work into the near IR regime (from 1 to 3 microns).  In this case, we used the indium tin oxide (ITO) as the material of choice, with proper design and patterning of ITO nanorods. We also demonstrated that such ITO-based optical metatronic circuits function as an interesting platform for optical circuitry and filtering.  This can have exciting possibilities in the silicon photonics.

Reference:

  • H. Caglayan, S.-H. Hong, B. Edwards, C. Kagan, and N. Engheta, “Near-IR Metatronic Nanocircuits by Design,” Physical Review Letters, 111, 073904 (2013).

SBPMat newsletter: – If you want, leave a message or invitation to your plenary lecture to the readers that will attend the XIV SBPMat Meeting.

Nader Engheta: – One of the exciting features of doing science is the joy of search for unknowns and the thrill of discovery.  I always believe that we should follow our curiosity and our passion for discovery. Also, in science and technology it is important to maintain the balance between the complexity and the simplicity in search for solutions to scientific inquiry.

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