Featured scientist: Yvonne Primerano Mascarenhas.

Posted on Sunday 31 de March de 2019

During the opening of the XVIII B-MRS Meeting in Balneário Camboriú (SC), on the night of September 22 of this year, Yvonne Primerano Mascarenhas, a retired professor of the University of São Paulo (USP), will give the Memorial Lecture Joaquim da Costa Ribeiro, an honor granted every year by B-MRS to a researcher with outstanding trajectory in Brazil. In the memorial lecture, Prof. Yvonne will talk about the evolution of crystallography (study of the structure of crystalline materials) in Brazil, a story she can personally narrate in the first person.

In fact, Professor Yvonne was the person who introduced and developed, since the early 1960s, the structural and molecular X-ray crystallography, now widely used in research, development and innovation in Brazil. The technique allows to fully know how the atoms and molecules that make up the organized structure of crystalline materials are arranged in space.

Yvonne Primerano was born on July 21, 1931 in Pederneiras, a small town in the State of São Paulo. When she was 10 years old, after living some years in the city of São Paulo, the family moved to the city of Rio de Janeiro because of the father’s work. Rio de Janeiro was the Capital of the country, and besides being safe at that time, it offered the family a warm reception and a wide range of possibilities, mainly in culture and education.

Yvonne’s secondary education was at Colégio Mello e Souza, a renowned private school in Rio. Due to her fondness for literature, in the last cycle of secondary school she opted for the so-called “classical course,” which reinforced the study of philosophy and literature and more superficially approached the natural sciences. However, it was in these chemistry classes taught by a great teacher – Albert Ebert – that Yvonne was captivated by the diversity of molecules created by nature and with the possibility of synthesizing them in the laboratory.

After graduating from secondary school, Yvonne chose to study chemistry, and after working hard for the university entrance exam, in order to fill the gaps of her humanistic education, in 1949 she entered the bachelor’s degree course in Chemistry at the University of Brazil, currently the Federal University of Rio de Janeiro (UFRJ). There, once again, a special teacher intervened in her professional trajectory. It was Elisario Távora, professor of the Crystallography discipline. Professor Távora had just returned from the United States, where he had completed his doctorate from the Massachusetts Institute of Technology (MIT) under the guidance of Professor Martin Julian Buerger – renowned crystallographer, author of innovations in techniques and instruments in the area. Thus, Yvonne, through Távora, had contact with the state of the art in crystallography techniques; mainly techniques based on X-ray diffraction, which led her to perceive the potential of the area. In young Yvonne’s mind, the idea was that studying the structure of molecules by X-ray diffraction might be a good idea.

Yvonne then felt she needed to learn more Physics, and in 1951 she started to study in this area her second degree at the current State University of Rio de Janeiro (UERJ). In 1954, she had two bachelor’s degrees and a solid baggage in Physical Chemistry. That year she married the physicist-chemist Sergio Mascarenhas, with whom she would form a family, and become a standard-bearer couple in the history of materials research in Brazil.

At the University of Brazil, Yvonne met Professor Joaquim da Costa Ribeiro and participated in the scientist’s research work. At that time, Costa Ribeiro – who a few years earlier had discovered the thermo-dielectric effect while studying Brazilian natural materials – was one of the very few researchers, along with Professor Bernhard Gross, who worked in Material Physics in Brazil. In fact, at that time research resources and efforts in the country were concentrated in nuclear and high energy physics.

In 1956, after living in Rio de Janeiro for fifteen years, Yvonne returned to live in the interior of the state of São Paulo. This time, she settled in São Carlos, a city of about 40 thousand inhabitants, with her husband and the couple’s first two children (a little boy and pregnant with a baby girl). The reason for moving to São Carlos was because the couple had been hired as full-time professors at a unit of USP that had been recently created in São Carlos, the School of Engineering of São Carlos (EESC).

If Rio de Janeiro had provided Yvonne the possibility of a solid preparation, São Carlos now offered both members of the Mascarenhas couple a series of benefits: belonging to an important university, teaching and research activities concentrated in one place (in Rio de Janeiro, Sergio worked in four different places) and, no less relevant, two wages enough to support the family. All of this in the practicability of a small city, saving several hours of driving to work every day. In addition, the couple would be free to develop research in the area that most interested them in that context: the application of Physics and Chemistry to the study and development of materials.

At EESC, a happy coincidence put Professor Yvonne, once again, on the path of structural crystallography. Forgotten in a corner, there was a medical X-ray machine that had been purchased by a French researcher who had spent some time at the institution. The device had not being used and was of no use to the engineering school. Professor Sérgio Mascarenhas then talked to the manufacturer and was able to exchange it for an X-ray diffraction instrument, which was used in the couple’s first experimental work in São Carlos. From these works, it became clear to Professor Yvonne that knowing the structure of materials was essential to know and modify their properties.

Between 1959 and 1960, the Mascarenhas spent 16 months in the city of Pittsburgh (United States) doing research internships with financial support from the Fulbright Commission, which was in Brazil since 1957. Yvonne intended to train in the study of the structure of materials by X-ray diffraction with a group in the Carnegie Institute of Technology. But when she met the group, she was disappointed. It was then that, by chance, she met the Brazilian physicists Ernesto and Amélia Hamburguer, who were at the University of Pittsburgh doing a doctorate and a master’s degree, respectively. The Hamburguers suggested that Professor Yvonne Mascarenhas should try to do an internship in the Crystallography laboratory coordinated by Professor George Jeffrey at the University of Pittsburgh.

After a few weeks attending a Crystallography course taught by Professor Jeffrey, Professor Yvonne Mascarenhas began working in his research group, where, among other projects, she performed the experimental work of her doctoral thesis, which consisted in obtaining the position of the atoms of a material with magnetic properties by means of X-ray diffraction. At that time, applying this technique was a very complex and time-consuming task due to the limitations of the available equipment, including computers. At the end of her internship at the University of Pittsburgh, she had acquired skills and knowledge that qualified her to work with X-ray crystallography.

After returning to Brazil in 1961, Yvonne (who at that time was the only one working with structural crystallography in Brazil) initiated the Crystallography Laboratory of São Carlos (which would become the first structural crystallography laboratory in the country). The implementation of the laboratory infrastructure and the recruitment and training of its multidisciplinary and international team intensified in the 1970s and continued into later years.

In 1963, after processing the experimental results obtained in Pittsburgh, challenging due to the lack of computers at EESC, Yvonne defended her doctoral thesis titled “Determination of crystalline structures by X-ray diffraction: study of Manganous Formate Dihydrate.”

In 1971, Dr. Yvonne P. Mascarenhas obtained the title of Associated Professor at EESC. In 1981, she became a full professor at the Institute of Physics and Chemistry of São Carlos (IFQSC), another USP unit founded in 1971 in the Sao Carlos Campus. When, in 1994, this unit was split into the Institutes of Physics (IFSC) and Chemistry (IQSC), Professor Yvonne P. Mascarenhas remained in IFSC until her compulsory retirement in 2001, when she became collaborating researcher at the institution. Over the ensuing years, Yvonne began to lead projects related to science teaching and diffusion in public elementary and middle level schools.

Throughout her career, Professor Yvonne P. Mascarenhas has accomplished scientific internships as visiting researcher at some of the world’s most renowned institutions: Princeton University and Harvard University (United States), the National Polytechnic Institute of Mexico, and the University of London (United Kingdom).

She has also had several leadership roles, which until today are predominantly performed by men in the Brazilian academic environment. Within USP São Carlos, she has been the department head, the first director of the Institute of Physics of São Carlos (IFSC) and vice-coordinator of the Institute of Advanced Studies – Polo São Carlos, among other positions. In addition, she led the creation of the Brazilian Society of Crystallography (current Brazilian Crystallographic Association), founded in 1971, and was the president of the society.

Here are some of the many tributes and honors she has received: Distinguished Women in Chemistry or Chemical Engineering Awards of the International Union of Pure and Applied Chemistry (2017), the title of emeritus professor of the Brazilian National Council for Scientific and Technological Development, CNPq (2013), the admission to the Brazilian National Order of Scientific Merit in the Grand Cross Class by the Presidency of Brazil (1998) and the Simão Mathias Medal of the Brazilian Chemical Society (1998). In addition, the researcher has been a full member of the Brazilian Academy of Sciences since 2001.

Over the six decades of working in structural crystallography, Yvonne Primerano Mascarenhas has participated in dozens of projects in various areas that need structural information on materials or molecules, interacting closely with materials scientists, engineers, chemists, physicists, biologists, biochemists, physicians and others. During the period, she supervised 40 master’s and doctoral studies, and coauthored more than 180 articles in international scientific journals. The laboratory created by Yvonne (now called Multiuser Laboratory of Structural Crystallography) has directly generated more than 1,000 articles published in scientific journals and has enabled researchers in many Brazilian states and Latin American countries to perform X-ray diffraction.

Sixty years after the first Brazilian works with structural X-ray crystallography, around 200 structural crystallographers work in Brazilian universities, among them, the pioneer Yvonne Primerano Mascarenhas, now at the age of 87, who still actively participates in scientific research.

Here is a brief interview with this leading scientist.

B-MRS Newsletter: Through crystallography, you have revealed information that is essential to many research projects in many areas. Could you tell us which are the most impacting works in the materials area in which you have participated.

Yvonne Primerano Mascarenhas:

Crystal-stucture analysis of deamino-oxytocin – conformational flexibility and receptor-binding. WOOD, SP; TICKLE, IJ; TREHARNE, AM; et al. SCIENCE, 232, 4750, 633-636. MAY 2 1986.

In this work, carried out during an internship at the Department of Crystallography of Birkbeck College, University of London, we were able to contribute to the elucidation of oxytocin, an important hormone produced by the pituitary gland, which in the case of women plays an important role in the stages of childbirth and lactation.

Characterization of Polyurethane Resins by FTIR, TGA, and XRD. Trovati, Graziella; Ap Sanches, Edgar; Neto, Salvador Claro; et al. JOURNAL OF APPLIED POLYMER SCIENCE, 115, 1, 263-268. JAN 5 2010.

The measurements performed on the diffractograms of the various types of polyurethane allowed the quantitative determination of the crystallinity percentages of the different samples and related them with other spectroscopic results.

Structural transition and pair formation in Fe3O2BO3. Mir, M; Guimaraes, RB; Fernandes, JC; et al. PHYSICAL REVIEW LETTERS, 87, 14, 147201. OCT 1 2001.

The structural determination of the material under study by low temperature X-ray diffraction allowed us to characterize a low temperature crystallographic transition that is important to understand the magnetic properties of the studied material.

Crystallographic and spectroscopic characterization of a molecular hinge: Conformational changes in bothropstoxin I, a dimeric Lys49 phospholipase A2 homologue. da Silva Giotto, MT; Garratt, RC; Oliva, G; et al. PROTEINS-STRUCTURE FUNCTION AND BIOINFORMATICS 30, 4, 442-454. MAR 1 1998.

The determination of the molecular structure of this enzyme, which is one of the components of rattlesnake venom, allowed to better understand its biological action.

Crystal structure of perdeuterated violuric acid monohydrate – X ray diffraction analysis. Craven, BM; Mascarenhas, Y. ACTA CRYSTALLOGRAPHICA, 17, 4, 407. 1964

This publication was the result from work done at the University of Pittsburgh during my first internship abroad. The substance under study is a barbiturate that crystallizes with a water molecule. The structural determination revealed the presence of a bifurcated hydrogen bond that had already been predicted theoretically but was experimentally observed for the first time in this crystal.

Location of cerium and lanthanum cations in CeNaY and LaNaY after calcination. Nery, JG; Mascarenhas, YP; Bonagamba, TJ; et al. ZEOLITES, 18, 1, 44-49. JAN 1997

This is one of a series of works carried out in collaboration with the Petrobras research center (CEMPES) to analyze changes produced in a series of zeolites that are used as catalytic cracking of petroleum. The results obtained allowed to better understand the mechanisms of catalysis and to suggest other modifications aiming at higher yields.

B-MRS Newsletter: At the XVIII B-MRS Meeting you will give the Memorial Lecture “Joaquim da Costa Ribeiro.” At the end of the event, B-MRS will award students the “Bernhard Gross” Award. You have personally met these two pioneers of materials research in Brazil (Costa Ribeiro and Gross). Could you briefly tell us about your relationship with them?

Yvonne Primerano Mascarenhas: To talk about these individuals in a small paragraph is quite insufficient. Costa Ribeiro and Gross were our mentors in our first research and scientific education activities. We interacted with both scientists during our undergraduate years at the then University of Brazil, currently UFRJ. We had a strong research contact with Bernhard Gross, who visited São Carlos periodically until his death, guiding our activities both experimental and theoretical and guiding some young physicists who had joined our laboratory. Costa Ribeiro supported us quite a bit since our arrival in São Carlos, both with letters of recommendation to the director of EESC, as well as yielding a Wulf electrometer that allowed us to immediately start the dielectrics research. He later spent several years outside Brazil as the representative of Brazil at the Atomic Energy Commission in Vienna and died prematurely a few years after his return to Brazil.

B-MRS Newsletter: You have four children who were raised while you were developing an important scientific career, including holding leadership positions. You usually declare that you did not believe your professional life was undermined because you were a woman. Could you tell us how you managed to reconcile family and professional life at a time when there was no maternity leave in Brazil, and women used to be fired when becaming mothers?

Yvonne Primerano Mascarenhas: Living in a small town enables one to have a great family relationship with children, relatives and friends. So I believe that the decision to move from Rio de Janeiro to São Carlos played a very important role in my professional performance. In addition, I have always valued the help I received from the excellent people who supported me in my domestic needs and in the care of my children. I was very lucky to have this invaluable help from several people who were in my life sharing responsibilities in an interpersonal exchange of much love and respect.

B-MRS Newsletter: Please leave a message for our younger readers who are starting a career as scientists or are contemplating this possibility.

It is never too much to remind them that the economic and social situation of our country will only improve when we can improve the cultural and scientific level of our people, as well as establish notions of responsible, ethical and moral conduct that lead to the good use of our potential natural resources (agriculture, mineral reserves and industrial and commercial processes) and the proper use of taxes collected from the population. In order to do so, the commitment of our young people is crucial both in the educational area and in the exercise of citizenship. I am well aware that it is a great demand, but I am sure that with well-focused effort on these goals, they will be able to achieve great results.

SBPMat´s community people: interview with Roberto Mendonça Faria.

Posted on Friday 26 de February de 2016

The interviewee of this edition of the newsletter of the Brazilian Materials Research Society Newsletter (SBPMat) is Professor Roberto Mendonça Faria, who has just handed over the SBPMat Presidency after four years in office (although he promises to remain active in the society).

Roberto Mendonça Faria was born in Adamantina, a small town on the west side of the State of São Paulo (Brazil), on May 1952. At the beginning of his secondary studies, already oriented towards “hard sciences” and stimulated by a great physics teacher, he started to look at science as a potential profession. In 1976, Faria concluded his bachelor’s degree in physics at the São Paulo University (USP).

In the same year, still passionate about physics, in which humanity was taking great steps towards knowledge, Faria began his academic career. He started teaching in undergraduate courses at USP and began his master´s course in physics at the same university. There, supervised by Professor Bernhard Gross, a pioneer in Materials research in Brazil, Faria learnt the pillars of scientific activity and developed a fascination for uncovering mysteries of materials (in this case, the conductivity induced via radiation in a polymer known as Teflon). Right after obtaining the master’s degree, in 1980, Faria began the doctorate course in physics at USP, once again having Professor Gross as supervisor. In 1984, Faria defended his dissertation about dielectric absorption and induced conductivity via radiation in the polymer PVDF.

In 1985, Faria started lecturing in postgraduate courses at USP. Between 1987 and 1989, he stayed in France on a post-doctorate internship at Université Montpellier 2. In 1990, he obtained the Associate Professor title at USP after defending a thesis about phase transitions in ferroelectric copolymers. In 1999, he became Full Professor of the São Carlos Institute of Physics (IFSC) at USP, where he occupied several management positions throughout the years, such as the head of the Department of Physics and Materials Science (1994-1996), the coordination of the postgraduate program in physics (1997-1998) and the IFSC general direction (2002-2006).

Roberto Faria also was the coordinator of two large scale projects at a national level. The first project was the “Multidisciplinary Millennium Institute of Polymeric Materials”, one of 17 projects selected within the program “Institutes of the Millennium” of the Brazilian Ministry of Science, Technology and Innovation (MCT). This institute gathered around 140 researchers from 17 institutions from Brazil’s five regions, and existed between 2002 and 2008. The second project continued one of the research focuses of the first one – the study of electronic polymers and their applications. Starting in 2009, the Brazilian National Institute for Organic Electronics was approved and established in the context of the Brazilian National Institutes of Science and Technology (INCTs) from the MCT.

Going beyond the frontiers of his scientific area, Faria was the coordinator, between 2010 and 2014, of the São Carlos pole of the Institute of Advanced Studies (IEA) at USP, an organization intended for broad and interdisciplinary research and discussion of fundamental issues on science and culture. In addition, in the context of his interest in contributing with the economical development of his country through research, Faria coordinated the making of the book “Science, technology and innovation for a competitive Brazil”, published in 2012.

In the last few years, Faria has been having an active participation in international scientific entities in the Materials area. In 2014, he was one of the general coordinators of the “Spring Meeting of the European Material Research Society – 2014”, which took place in the French city of Lille. In 2015, he was elected second vice-president of the International Union of Materials Research Societies (IUMRS).

Faria is a member of the Academy of Sciences of the State of São Paulo and the Brazilian Academy of Sciences and belongs to the editorial board of the journal “Materials Science – Poland”. In 40 years of scientific research on polymeric materials, particularly those with electronic activity and their applications in devices, Professor Faria has produced around 180 articles published in indexed journals, having about 2,000 references, and has supervised 47 master´ss and doctorate thesis.

An interview with the researcher follows below.

SBPMat Newsletter: – Tell us what made you become a scientist and work in the field of Materials.

Roberto Mendonça Faria: – Before High School, I imagined I was going to follow my studies in the “hard sciences” area (engineering, physics, chemistry, mathematics, etc.). But I didn’t have any intention to follow a scientific career, even less so to be a scientist. However, in the first year of High School I started to change my mind, stimulated by an excellent physics teacher, Roberto Stark. I graduated in Physics and soon after I was lucky to be supervised by two great masters: Professor Bernhard Gross and Professor Guilherme Fontes Leal Ferreira. As any newly-graduated person in physics at the time, I was passionate about the extraordinary experimental and theoretical advances of the 20^th century physics. However, my first research study was about an apparently modest theme: the interaction of ionizing radiation with thin films of insulating polymers. Under the supervision of Professor Gross, I definitely learnt how to approach a scientific issue and also how to handle the methodological strictness needed to discover the effects and the phenomena arising from the experiments performed. Those first years of research were crucially important to my career. I never again lost the fascination in discovering the properties and the enigmas of the condensed matter, and I’m happy because materials science and engineering is extremely important for the development of Brazil.

SBPMat Newsletter: – In your assessment, which are your main contributions to the field of Materials?

Roberto Mendonça Faria: – There are different ways to measure the contributions made to the advance of scientific and technological knowledge. The most objective and internationally followed view is the bibliometric, conduced by the Journal of Citation Reports (JCR) from Thomson Reuters. This metric has many merits, but it’s too much focused on numbers. Another fact influencing scientific assessments comes from the pragmatism of the present world. Today, it is required that scientific works aim at specific applications. In this context, researches involving more fundamental studies tend to lose the visibility they deserve. That is, many times scientific works of great value have little mentions. An analysis of my production from JCR may lead to the conclusion that my most relevant contributions are connected to applications, but I particularly believe that my greatest contributions are more related to fundamental works in the areas of phase transitions of ferroelectric polymers and electrical transportation mechanisms in electronic polymers.

One of the interesting areas I have been working on in the last few years is the organic solar cells. I believe that, with my research group, we gave a significant contribution to the understanding of phenomena involving the transportation of electrical carriers inside the cell. Since 2013 we published two works where we developed an analytical equation which rules the electrical current curve in function of the voltage of a solar cell when under lighting. This analytical equation works very well in special cases and has explained many of the optoelectronic effects of the devices we built and measured in our laboratories. One of the works was published in the Applied Physics Letters journal in 2013, and the other was published on Solar Energy Materials and Solar Cells in 2015.

On the other hand, I always dedicated myself to assembling research laboratories and forming human resources. I also have been contributing with several post-graduation programs, directly and indirectly, and for more than 20 years I have been dedicating myself to strengthening the area of Organic Electronics in the country, especially in the formation of a research network in this area: the National Institute of Science and Technology of Organic Electronics. Whenever possible, I try to encourage projects in partnership with private enterprises and research institutes that aim towards applied projects. In the public policies area, I believe my greatest participation was coordinating a document from CAPES (the Brazilian agency in charge of post-graduate programs) and SBPC (Brazilian Society for the Advancement of Science), called “Science, technology and innovation for a competitive Brazil”, which has contributed to the creation of the Brazilian Company of Industrial Research and Innovation (EMBRAPII).

SBPMat Newsletter: – You have just finished your tenure as President of SBPMat. Share with our readers an analysis of the results achieved by the boards you have headed during the last four years.

Roberto Mendonça Faria: – SBPMat is a relatively new society, but it has an important mission to fulfill for the development of the country. Brazil has an extraordinary richness offered to it by nature. However, the country does not take advantage of this richness because it places little knowledge over its natural resources. There was a revolution in agriculture after the country decided to put knowledge over this blessing that nature has offered to it. Today, agribusiness is one of the pillars, perhaps the strongest one, of our economy. We have to do the same with the raw matters that abound in our territory. The publication “Science Impact – A special report on materials science in Brazil”, in partnership with the Institute of Physics (IOP), was one of the projects that worked and gratified me very much. This type of initiative helps raising awareness that Brazil has a natural gift to be a leader in several materials-related segments and to generate a lot more richness than it currently does.

Another valuable contribution that the two previous SBPMat administrations gave to materials science and engineering in Brazil was the definite consolidation and internationalization of the annual meeting, which always take place at the end of September.

I must highlight that the creation of the bilingual electronic newsletter was a realization that worked, especially because of the capability it has been produced with.

SBPMat Newsletter: – You just took over, for two years, the second vice-presidency of IUMRS. Talk about your plans, expectations…

Roberto Mendonça Faria: – I’m starting this activity. My plans are, first of all, to increasingly insert the Brazilian Materials Science in the international scenario. At the same time, I intend to use the IUMRS support to stimulate materials research in other Latin American countries. Brazil and Latin America have many problems that come from their still deficient economies. I have conviction that research studies in the materials area are valuable instruments to improve the living conditions of these populations. Today, as a member of the SBPMat council, I want to take this discussion not only in Brazil, but in several Latin American countries with the help from IUMRS.

SBPMat Newsletter: – Leave a message for the readers that are starting their scientific careers.

Roberto Mendonça Faria: – I decided to register here that one of the fulfillments (still in progress) that makes our administration proud was the creation of the University Chapters program. I’m going to ask the council to allow me to work with Professor Rodrigo F. Bianchi within this program. I have no doubts that the more researchers we form, the more Brazil will gain with this.

I believe that the work with young people starting scientific activity is one of the most valuable works for a senior researcher. It is our duty to show young people how important the work of “manufacturing knowledge” is for the country, especially in scientific and technological areas. There isn’t one example of a country that has eradicated poverty without the development of strong education and competitive science and technology. Therefore, the message to young people is: believe in your work and always try to make it in the most competent way possible.