Special feature: Sirius, the latest generation Brazilian Synchrotron.

Before the end of this decade, the Brazilian Synchrotron Light Laboratory (LNLS), located in Campinas (SP), will be receiving researchers from Brazil and from the rest of the world to use the Sirius, the fourth generation Brazilian synchrotron that will replace or supplement the UVX – the current second generation Brazilian synchrotron, which has been operating since 1997 and is the only synchrotron in Latin America.

Highly appreciated by the scientific community of Materials Science, and by many other areas, synchrotrons are the best sources of beams of X-rays and ultraviolet light, two very useful types of radiation in the study of matter. The process of producing radiation is achieved by the acceleration of electrons moving near the speed of light and subjected to deviations in its path. When diverted, the electrons lose some of their energy in the form of synchrotron light, which is filtered by monochromators that will release radiation by selectively passing the desired wavelength. Therefore, the X-ray beams or ultraviolet light are carried to the experimental stations or light lines, around the accelerator, which have various scientific instruments. The users of the synchrotron make use of the radiation to analyze its interaction with matter through the scientific instruments to obtain information about the structure and properties of the materials at micro and nanoscale.

Sirius, as its name suggests the brightest star in the night sky, will be able to generate extremely bright light beams (up to a billion times higher than the brightness of UVX) – a very important feature that will allow to perform more and better experiments.

This high-brightness radiation, together with advanced scientific instruments and powerful computers to quickly process large amounts of data, will allow performing a wide range of experiments that will generate scientific and technological results in sectors such as Agriculture, Biology, Geology, Energy and Health, and of course in the Materials Science area.

Synchrotron light sources in construction and operating around the world. Map provided by LNLS-CNPEM.

About 300 people are currently working on the project and construction of Sirius, a large-scale and complex project that involves many challenges. One is the development of the synchrotron light source. As a matter of fact, Sirius is one of the first fourth generation light sources in the world (there is only one more currently under construction in Sweden, but neither one operating). There are many challenges, such as developing a system for the monitoring, diagnosis and correction so that the sensitive electron beam trajectory remains stable. Even the construction of the building itself must meet very specific conditions, in order to ensure an almost complete absence of vibration, however small.

This large-scale Brazilian undertaking, whose value is estimated at 1.3 billion reais, is being conducted by LNLS, which developed the UVX and has taken care of its operation, maintenance and upgrades for 19 years. The general management and direction of the team is under the responsibility of the current director of LNLS, Antonio José Roque da Silva. Full Professor of the University of São Paulo (USP), Roque da Silva has an undergraduate and master’s degree in Physics from Unicamp, and a doctorate (PhD), also in Physics, from the University of California, Berkeley. He is the author of over 120 scientific papers published in indexed journals, many of them related to materials science studies. According to Google Scholar, his publications have over 4,400 citations.

The SBPMat Newsletter interviewed Roque da Silva on the technical characteristics of Sirius, the possibilities it offers to the materials science community, the progress of the project and the future of UVX, among other issues.

SBPMat: Newsletter – Sirius will be a high brightness synchrotron light source. What is the importance of brightness for research in Materials Science and Technology?

Antonio José Roque da Silva: – For a given frequency of radiation, its brightness is directly proportional to the flux (number of photons per unit time) and inversely proportional to the product of the beam size times the beam divergence angle). The latter quantity is the beam emittance. Therefore, the lower the emittance, the higher the brightness.

The high-brightness affects the analysis of the materials in different ways:

a.  The higher the brightness of the light produced by the synchrotron, the higher the number of samples that can be analyzed within a time period; This allows performing experiments with temporal resolution, which allows to monitor the progress of reactions or processes, e.g., as a function of time.

b.  Higher brightness means a better signal-to-noise ratio of different analysis techniques.

c.  Low emittance, hence higher brightness, allows probing smaller spatial scales by analytical techniques. This opens study opportunities using nanometer-sized beams, important in areas such as nanotechnology, and other areas.

d. Higher brightness allows the emergence of new techniques or to explore them more effectively. This occurs, for example, with the Coherent Diffraction Imaging technique. Higher brightness will greatly benefit imaging techniques, tomography and microscopy.

The first 13 beamlines that will be installed in Sirius. Data provided by the LNLS-CNPEM.

SBPMat Newsletter: – What are the limitations of UVX synchrotron that will be overcome by Sirius? For example, will there be characterization techniques of materials in the experimental stations of Sirius that cannot be installed in UVX?

Antonio José Roque da Silva: – The major difference between the two machines is the energy range in which they operate. The electrons in the storage ring of Sirius will be accelerated up to the energy of 3 GeV, more than double the energy of UVX. This results in producing higher energy X-rays and enables more in depth studies of materials such as steel, concrete and rock due to the penetration of X-rays up to a few centimeters, against some micrometers of the UVX.

Also because of the energy difference, the number of chemicals that may be studied by soft X-ray spectroscopic absorption is also different. In the UVX less than half of the chemicals can be studied, while almost all elements of the Periodic Table can be studied in the Sirius.

The low brightness and high emittance of UVX greatly limits the most modern synchrotron techniques available to the scientific community of the country. Nanotomography, coherent diffraction imaging, fluorescence nanomicroscopy, nanocrystals analysis, materials research under extreme conditions (high pressures and high temperatures), inelastic scattering, temporal monitoring of various processes, together with nanometer spatial resolution and chemical resolution (for example, important for catalytic processes), among many other techniques, cannot be performed in UVX or are carried out with great limitations, however they can all be carried out, with high standard, in the Sirius.

SBPMat Newsletter: – What will happen to the UVX?  Will it be dismantled?

Antonio José Roque da Silva: –  It should be emphasized that everything that the UVX does today can be done much better in Sirius. In addition to the large number of new experiments that cannot be performed in the UVX, as mentioned earlier. The LNLS has decided that during the commissioning period of the Sirius beamlines, the UVX will be kept operational to ensure that the community is not affected by any discontinuity. However, it is not known if after Sirius becomes fully operational the current machine will be preserved or disabled. We know that the scientific instrument available today in some experimental stations of UVX will be transferred to Sirius. Additionally, the cost and feasibility of maintaining the simultaneous operation of two synchrotron light sources must be assessed, as well as the staff (engineers, technicians, researchers and etc.) needed to operate both sources. It is also necessary to assess the users’ level of demand for the experimental stations of UVX once Sirius is fully operating.

SBPMat Newsletter: – Will the expertise of professionals (scientists, engineers, technicians) and Brazilian companies developed during the construction of UVX be used in Sirius? If yes, in what way?

Antonio José Roque da Silva: – The Sirius project would not be possible without the expertise and skills of the professionals formed by LNLS over the years, particularly during the construction of UVX. This high-capacity and specialized professional body (scientists, engineers, technicians) formed over the past 30 years, is crucial to the success of Sirius. The amalgamation of experienced professionals that originated with the construction of UVX, including the young people, is a key strategy of the LNLS – for Sirius and for the future of the laboratory. From a technical point of view, the knowledge accumulated by our engineers and technicians during the construction and operation of UVX is what allowed to design a state of the art synchrotron such as Sirius. This experience will also be crucial to the operation of the new synchrotron. And the same goes for the scientists. The involvement with the construction and operation of the beamlines and the experimental stations of UVX is an important factor for the projects of the sophisticated beamlines of Sirius. The ongoing involvement of these researchers in training the new users, which is regularly performed by LNLS, is also fundamental, and which dates back to the beginning of the construction of UVX. We highlight that all of this knowledge acquired over the years also depends on a strong interaction with the international community of synchrotrons. The LNLS is strongly inserted in this community.

From a perspective of companies, the number of companies involved in the construction of the UVX was small. The UVX was not only designed by the LNLS but also mostly built within the LNLS. However, some companies which were important partners of UVX, as for instance Termomecânica, are also participating in the construction of Sirius. But LNLS successfully structured specific programs to involve Brazilian companies in the development and construction of various components for Sirius. These programs are in partnership with research funding agencies like FAPESP and FINEP. The development of partnerships with Brazilian companies will also be important for the future. Finally, the knowledge created by the Brazilian companies that cooperated (and that will continue to cooperate) with the project is extremely important and exceeds the limits of the project itself. This is why we consider Sirius to be a “structuring” project, whose developments will be reflected in new technologies, new products and processes that will bring benefits to the Brazilian high-technology supply chain.

SBPMat Newsletter: – Because it is a very complex, high standard and pioneer engineering project, (there is no other operating 4th generation synchrotron in the world), the construction of Sirius has unprecedented challenges, right? As project director, how do you address these challenges?

Antonio José Roque da Silva: – We rely largely on the experience, knowledge and audacity of the team of scientists, engineers and technicians of the LNLS. The courage of this team to face such challenges is among the greatest legacies dating back to the construction of the UVX. The compelling story of the construction of UVX has already been addressed in other SBPMat newsletters [Newsletter Note: see here the first and second part of this story). The culture of “yes, we can do it”, which comes from the beginning of LNLS, it crucial to overcome the challenges. One strategy is to increase the professional personnel, fundamental given the size of Sirius, mixing young people with the more experienced professionals, ensuring to preserve the existing in-house culture and knowledge. In addition to this experience, competence and courage, the continuous interaction with other laboratories is a key factor. We invested heavily in this area, sending LNLS professionals abroad and bringing experts from abroad to visit the laboratory. In this respect, also important is the assessment of our solutions by leading international experts. This is done through evaluation committees that regularly come to LNLS, and through the presentation of our results in conferences and specialized workshops. Also important is the investment made in cutting-edge infrastructure in both manufacturing and metrology. Finally, an important part is in regard to management and coordination of the activities and staff, thereby ensuring the efficient implementation of the necessary processes.

SBPMat Newsletter: – Tell us about the participation of national and international external companies and institutions in CNPEM regarding the development of Sirius.

Antonio José Roque da Silva: – One of the goals of the Sirius project is to stimulate the development of the Brazilian industry, by promoting demands related to technological developments, services, raw materials, processes and equipment. The goal is to apply between 65% and 70% of the project’s funds in the country. We should bear in mind that the project is 100% Brazilian.

Among the already established partnerships, we mention as an example the partnership created with the company Termomecânica of São Paulo, which developed the process to manufacture the raw material for the vacuum chambers of the storage ring and also the hollow copper wires for the electromagnets that allow cooling the water circulating through the pipes (this development dates back to UVX). Another example is the company WEG Indústrias (SC), a traditional electric motors manufacturer, which will manufacture over 1350 electromagnets for Sirius, designed by the technical staff of LNL. This is an exceptional partnership related to the sophisticated development of production processes and which has been extremely successful.

There are also examples of partnerships with smaller companies, such as FCA Brasil (Campinas, SP), for the manufacture of booster vacuum chambers, and with the Company EXA-M Instrumentação do Nordeste (BA), for the development and manufacturing of the devices for heating the vacuum chamber of the storage ring, and with Engecer of São Carlos for the manufacture of special ceramic vacuum chambers.

To increase the participation of national companies in the Sirius project, other systematic initiatives were undertaken. In 2014, negotiations with FINEP and FAPESP culminated in the launching of the first public call to select São Paulo-based companies for the development of 20 technological demands of the Sirius project, with resources of R$ 40 million. These funds were made available under the PIPE/PAPPE grant program, so that each proposal could request up to R$ 1.5 million for its development. Eight companies were selected to develop 13 research projects to carry out the challenges proposed in the bidding process.

In 2015 a second public call for proposals was launched for the development of 13 new technological challenges, with resources amounting to R$ 20 million under the same program. February was the deadline for the submission of bids by the companies, which are currently under analysis by FAPESP. For the second half of 2016 we expect that at least thirteen other companies are approved to develop the challenges of the second FAPESP/Finep call to support the Sirius project.

From an international point of view, as already mentioned, the continuous interaction with several laboratories has been vital to the project. An interesting detail is that today, as we are at the frontier and with several innovative solutions, needless to say there are international groups interested in interacting with the LNLS. That is, Sirius is obviously an important international vector.

SBPMat Newsletter: – What are the funding sources of the project.

Antonio José Roque da Silva: – The project is mainly funded by the Federal Government, through the Ministry of Science, Technology and Innovation, MCTI. It should also be mentioned that the Sirius project was recently included in the Growth Acceleration Program, better known as PAC, and is listed as one of the first MCTI projects to be part of the program.

Other important resources were provided by the State Government of São Paulo. For example, the land area of 150,000 square meters where Sirius will be installed was acquired by the State Government and granted to CNPEM.

Moreover, FAPESP has been an important partner in the interaction programs with companies and in supporting events and in the acquisition of scientific instruments that will be installed in the experimental stations (beamlines) of Sirius.

SBPMat Newsletter: – At what stage is the project now? What is the forecasted inauguration date of the light source and the first experimental stations?

Antonio José Roque da Silva: – The construction work of the Sirius building is about 20% complete. Part of the superstructure of the main building and part of the metal structure of the cover of the main building has already been built. An important milestone is making the tunnel available to begin assembling the accelerators at the end of 2017.

Several components of the accelerator are in the production phase. All quadrupoles and correctors of the booster have already been manufactured (by WEG) and delivered. Last week the pilot-batch of sextupoles was delivered, and the manufacture of the sextupoles will begin in two weeks. The prototypes of the booster dipoles will be delivered by the end of March, and its production should begin in early May. The Linac linear accelerator is ready and undergoing tests at the Shanghai Institute of Physics. Additionally, other components have concluded the development stage and are awaiting approval to start production, such as the vacuum chambers of the booster and part of the vacuum chamber of the storage ring. The RF booster cavities have been ordered, and the RF cavities of the storage ring will be ordered. Several other subsystems are in the final prototyping or in the initial production phase.

With regard to the experimental stations (beamlines), their projects are entering the technical detailing and construction phase and/or components acquisition. The projects of the Ipê, Carnaúba, Ema and Cateretê lines are now entering a detailed components phase of the experimental stations, technical designs and construction/custom component orders, such as inverters and mirrors which have a delivery time of up to two and a half years. Basically all the important beamline prototypes will be completed by the end of 2016. Overall, the chronogram of Sirius is on schedule, and the first beam and initial commissioning phase is expected in 2018, that way in 2019 the machine can receive the first researchers.

SBPMat Newsletter: – Would you like to add any comments or information?

Antonio José Roque da Silva: – It should be highlighted that Sirius is a result of the evolution of both the internal capacity of the laboratory as well as the maturing of the scientific community in Brazil. The concept of an Open National Laboratory, which is the goal of LNLS to provide an extremely sophisticated and unique equipment to the ST&I community is at the heart of the culture in the laboratory. Its high performance operation requires constant investment to train this highly specialized human resources (scientists, engineers, technicians), for the maintenance of cutting-edge equipment and infrastructure (accelerators, beamlines, experimental stations, support groups, metrology, manufacturing techniques, etc.), for user training, for developing new technologies, excellence in communication and management. The synchrotron project in Brazil, from UVX to Sirius, is something that all Brazilians can and should be proud of, bearing in mind it began from “square one” and in thirty years has placed Brazil in the state of the art, with a significant effect on the formation of human resources, high-level science, innovation, high-technology development and internationalization.

Simulation of the Sirius building (round, on the left) at CNPEM campus. Provided by LNLS – CNPEM.

Opportunities for researchers at the Brazilian Synchrotron Light Laboratory (LNLS).

Location: Brazilian Synchrotron Light Laboratory (LNLS) – Campinas City, São Paulo state – Brazil.

Post details (i.e. permanent): Permanent staff member position.

Salary: to be negotiated depending on applicant’s experience.

Application requirements: 1. Solid experience on synchrotron science using micro and nano-probe x-ray scanning techniques. 2. Ph.D. degree or equivalent in Physics, Biology, Chemistry or a related discipline, with emphasis on the use of micro and nano-probe x-ray scanning techniques. 3. Experience with beamline design and commissioning. 4. Language: Advanced level of English. Portuguese as a plus.

Brief job description: The selected applicants will have to carry out their own research projects with x-ray diffraction and spectroscopy, as well as being involved in the project, construction and future operation of the nanoprobe beamline on Sirius (CARNAÚBA) on the operation of the x-ray diffraction beamlines at the current 2nd generation Light Source. For more information on the current LNLS beamlines, please visit www.lnls.br.

Interested, please send CV, Motivation and Recommendation Letter to elisa.turczyn@lnls.br. In the subject line, put “47834”, otherwise the CV will not be considered.

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Location: Brazilian Synchrotron Light Laboratory at CNPEM in Campinas/ São Paulo, Brazil.

Responsibilities: The extreme condition research group of LNLS has an immediate open Scientist position for an outstanding experimentalist in high-pressure/temperature and materials research. The successful candidate should be heavily involved in the design and implementation of the EMA beamline at the Sirius Synchrotron (under construction). This beamline is intended for spectroscopy (XAS/XMCD/XES) and scattering (XRD/XRMS/XRS) experiments under extreme pressures by taking advantage of submicron beamsize (down to 0.5×0.5 µm2) with high photon flux (up to 10^14 ph/s). In addition, the scientist must develop his/her own research activities and supervise students and post-docs. He/she also must be involved in high pressure/temperature experiments at our current 2nd generation synchrotron in order to prepare the instrumentation and the Latin American community to take advantage of state-of-the-art instrumentation when Sirius is ready.

Requirements: Ph.D. degree in physics, chemistry, materials science, earth science, biophysics, engineering, or a related field. Post-doc experience in the field is desirable but not obligatory. The successful candidate should meet some of the following qualifications (although quick learning scientist with expertise in other areas could also be considered): High pressure and temperature experiments in diamond anvil cells; X-ray diffraction and/or spectroscopy under high pressure/temperature; Visible/IR laser optics instrumentation; Experiments involving high magnetic fields; Commissioning/operation/use of a synchrotron hard x-ray beamline. Fluent English.

Interested, please send CV, Motivation and Recommendation Letter to elisa.turczyn@lnls.br. In the subject line, put “62220”.

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SBPMat´s community people: interview with Fernando Galembeck.

To Fernando Galembeck, Director of the Brazilian Nanotechnology National Laboratory (LNNano) from 2011 to 2015, the interest in research started to appear during his adolescence, when, working in his father’s pharmaceutical lab, he realized the economic importance that new products, resulting from efforts in scientific research, had on the company. Currently aged 72, Fernando Galembeck, looking back at his own scientific path, can tell us several stories in which the knowledge produced by him, jointly with his collaborators, is not only transmitted through scientific papers, theses and books, but has taken form as licensed patents and new or improved products.

Galembeck received his Degree in Chemistry in 1964 from the University of São Paulo (USP). After graduating, he stayed at USP, teaching (1965 – 1980) and, simultaneously, conducting his doctoral studies in Chemistry (1965 – 1970) with a research work on the metal-metal bond dissociation. Once his doctoral studies were completed, he held post-doctoral fellowships in the United States, at the universities of Colorado, in the city of Denver (1972-1973) and California, in the city of Davis (1974), working in the field of Physical Chemistry of biological systems. In 1976, back at USP, he had the chance to create a colloids and surfaces laboratory in its Chemistry Institute. From that moment, Galembeck has been increasingly involved in the development of new materials, especially the polymeric ones, and their manufacturing processes.

In 1980, he started teaching at the University of Campinas (UNICAMP), where he became a Full Professor in 1988, position he held until his retirement in 2011. At Unicamp, he held management positions such as University Vice-Dean, as well as Director of the Institute of Chemistry and Coordinator of its graduate studies program. In July, 2011, he took over the recently created LNNano, at the Brazilian Center for Research in Energy and Materials (CNPEM).

Throughout his career, in Brazil, he held management functions at the Brazilian Academy of Sciences (ABC), Ministry of Science, Technology and Innovation (MCT), National Council for Scientific and Technological Development (CNPq), São Paulo Research Foundation (FAPESP), Brazilian Chemical Society (SBQ), Brazilian Society for the Progress of Science (SBPC) and Brazilian Society for Microscopy and Microanalysis (SBMM), among other entities.

Holder of a 1A-level fellowship for research productivity at CNPq, Galembeck is the author of almost 250 scientific paper published on international peer reviewed journals, which count with over 2,300 citations, as well as 29 deposited patents and over 20 books and chapters in books. He has advised almost 80 Master’s and Doctoral researches.

He has received numerous awards and distinctions, including the 2011 Anísio Teixeira Awards, from CAPES, the Brazilian agency for the improvement of graduate courses; the 2011 Telesio-Galilei Gold Medal, from the Telesio-Galilei Academy of Science (TGAS); the 2006 Almirante Álvaro Alberto Award for Science and Technology, from CNPq and the Conrado Wessel foundation; the 2006 José Pelúcio Ferreira Trophy, from Finep (Brazilian entity for funding of studies and projects); the 2000 Grand Cross of the National Order of Scientific Merit and the 1995 National Commendation of Scientific Merit, both from the President of the Republic of Brazil. He has also received several awards from companies and scientific and business associations, such as CPL,  Petrobras, Union Carbide do Brasil, the Brazilian Paint Manufacturers Association, the  Brazilian Chemical Industry Association, the Union from the Industry of Chemicals for Industrial Use from the State of Rio de Janeiro, the Brazilian Polymer Association, the Brazilian Chemical Society – which created the Fernando Galembeck Award of Technological Innovation, the Engineers Union from the State of São Paulo and the Electrostatic Society of America.

What follows is an interview with the scientist:

SBPMat Newsletter: – Tell us what led you to become a scientist and work on issues in the field of Materials.

Fernando Galembeck: – My interest in research work started during my adolescence, when I comprehended the importance of new knowledge, of discovery. I found this when I was working, after school, at my father’s pharmaceutical laboratory, as I could see how the newest, latest products, were important. I also saw how costly it was, for the lab, to depend on imported products, which were not produced in Brazil, and that in the country there was no competence to manufacture them.  Then I realized the value of new knowledge, as well as the importance and the economic and strategic significance of such breakthroughs.

This feeling was increased when I took my major in Chemistry. I enrolled into the Chemistry course because one of my school teachers had suggested that I should seek a career related to research. He must have seen some inclination, some tendency of mine. So I attended the Chemistry course provided by the Philosophy School, in an environment where the research activity was very vivid. Because of that, I decided to conduct my Doctoral studies at USP. At that time, there were no regular graduate studies in Brazil yet. The advisor with whom I defended my dissertation, Professor Pawel Krumholz, was a great researcher, who also had built a very important career working on a company. He was the industrial director of Orquima, a major company by that time. That boosted my interest in research.

I worked with Chemistry for some years and my interest in materials came from a curious occurring. I was almost graduating, in my last vacations during the undergraduate studies.  I was at an apartment, resting after lunch. I remember looking at the walls of this apartment and noticing that, with all I had learned in the Chemistry course, I did not have much to say about the things I could see: the paint, the coverings etc. That was Chemistry, but also Materials, and there was not much interest in Materials in the Chemistry course. Actually, Materials became very important in Chemistry mainly because of plastic and rubber, which, at the time, did not have the importance they have today. I am talking about 1964, approximately.

Well, then I started to work with Physical Chemistry, to later work a little in a field that is more oriented to Biochemistry, that is Biological Physical Chemistry and, in 1976, I received a task from the USP Department, which was to build a colloids and surfaces laboratory.  One of our first projects was to modify plastic surfaces, in that case, Teflon. Then I realized that a major part of the colloids and surfaces Chemistry existed due to Materials, because the subject lends itself to create and develop new materials. From that moment on, I was getting increasingly involved with Materials, mainly polymers, a little less with ceramics, and even less with metals.

SBPMat Newsletter: – What are, in your own opinion, your main contributions to the field of Materials? Consider, in your answer, all aspects of your professional activity, including cases of knowledge transfer to the industry.

Fernando Galembeck: – I will tell the story in order, more or less. I think that the first important result in the field of Materials was exactly a technique intended to modify the surface of Teflon, that material in which it is very difficult to stick something. There is even that expression, “Teflon politicians”, the ones for which does not matter what you throw at them, they do not stick to anything. But, in certain situations, we want the Teflon to have adhesion; we want some things to stick. So, by a somewhat complicated path, I managed to see that I already knew how to modify Teflon, but I had never realized that is was important. I knew the phenomenon; I had observed it during my PhD defense. I knew that there was a change happening in Teflon. But it was during a visit to a Unilever laboratory in 1976, when I was talking to a researcher, that I saw that there were people striving to modify the surface of Teflon and achieve adhesion. Then, bringing the problem and the solution together, as soon as I returned to Brazil, I tried to see if I what I had previously observed was really useful, and it worked. That led to the first paper I wrote by myself and my first patent application, at a time when almost nobody talked about patents in Brazil, especially in the university environment. I was very enthusiastic about this: I was approached by companies that were interested in applying what I had done; one the modification in Teflon itself, the other in a different polymer. So I felt great, because I had made a discovery, I had a patent, and there were companies which, at least, would like to know what it was to see if there was a way to use it. One more thing:  soon after the paper I wrote was published, I was invited to attend a conference in the United States, which addressed exactly the issue of modifying surfaces. Polymers, plastic and rubber surfaces, a subject with which I was involved for pretty much the rest of my life, up until now.

I will mention a second fact that did not have the same effects, so far.  I discovered a method that enables the characterization and separation of very small particles. That was a very interesting paper. It was released, also produced a patent, but had no practical consequences. Recently, there have been some issues related to nanoparticles, which is a very important subject in Materials now, offering a chance to apply what I did over 30 years ago. The name of the technique is osmosedimentation.

Next there was some work that I did by collaborating in projects with Pirelli Cabos. With all this story of surfaces and polymers, I think I had become more or less known and was approached by Pirelli, which contracted me as a consultant and commissioned projects I had at Unicamp. An outcome of these projects, that I think is the most important, was the development of an insulator for very high voltages. This work was not only mine, but rather of a very large team, in which I took part. There were several people from Pirelli, and several from Unicamp. The result of this project was that the Brazilian Pirelli managed to be hired to provide high voltage cables for the Eurotunnel, back in the ‘80s. I think this was a very important case, as it led to a product and brought substantial economic results. I would like to stress that this was done in Brazil, by a Brazilian team. They were not a Brazilian company, but the team was based here.

Then, there were several projects with nanoparticles, at a time when we did not even call them nanoparticles; we used to call them fine particles, or simply small colloidal particles. The first paper I released on nanoparticles was in 1978. There were other things after that, which, ultimately, led to a paper on aluminum phosphate, which resulted in dissertations and papers, as well as a license by a company named Amorphic Solutions, from the Bunge group, that basically explores aluminum phosphate. The subject started at my lab, stayed there for many years, then a company of the Bunge group here in Brazil got interested, started participating, and we collaborated. That became a major development project. Later, Bunge found it infeasible to carry on with the project in Brazil and today is in the United States. I think it is a shame that they are there, but there were some other issues involved, including a disagreement with Unicamp, who holds the patents. If you check Amorphic Solutions page on the internet you may see many applications of the product. As far as I know, they are currently emphasizing its use as an anti-corrosive material to protect steel.

About the same time, in another project on nanoparticles, clay/natural rubber nanocomposites were developed. This was licensed by a Brazilian company called Orbys, which released a product called Imbrik, a product that the company provides, for example, in order to make rubber rolls for paper manufacturing.

Another case with a product. I had done a project with Oxiteno, which manufactures raw materials for latex, the surfactants. They wanted to get an ideia of how much you can change the latex changing the surfactant. I conducted a project with them that I consider one of the most interesting among those in which I have been involved. In the end, we realized that, by changing the surfactant a bit, we changed the latex a lot. These are used in paints, adhesives, resins. So we realized we had a great variability. This work was published and promoted. It did not result in a patent because it was a comprehension project. So, another company, Indústrias Químicas Taubaté (IQT) approached me to produce cationic latex, but using a new path. Cationic latex in general is made of quaternary ammonium salts, which have some environmental restrictions. The company wanted an alternative that did not have those restrictions. By the end of the project, we produced cationic latex without environmental restrictions, and the IQT put the product on the market.

There was another case that was also very interesting, even though it was canceled. Here in Brazil, there was a large manufacturer of polyethylene terephthalate, PET, which is used for many things, including bottles. They knew about the work I had done with nanocomposites, the one with Orbys I mentioned before, so they approached me wanting to produce PET nanocomposites. We had to find out how to escape from what was already patented abroad and discovered a whole new path. The company was called Rhodia-Ster, and today it is part of another Italian company, called Mossi e Ghisolfi. The company was enthusiastic and ended up patenting it in Brazil, and then later abroad. At a certain point, they decided that they would conduct the work internally, and so they did for some years. One day, my contact within the company called me to tell this: “look, we were working with two technologies; the one held by Unicamp and another one, in another country. Both are working, but the company has reached a point where it has chosen to complete the development of only one”.  When coming to the final stage in developing materials, the projects costs are too high. One have to use large amounts of materials, run many tests with customers. So, the company decided to take one project further, and, unfortunately, it was not the one in which I had worked. At the end, it was a little frustrating, but I think that it was interesting, because, during this whole time, the company invested a lot in the path we had started here. Not only that, each project brings resources for the laboratory, brings money to hire people, more jobs etc. So, these projects result in many benefits, even when they are not concluded.

Now, skipping some bits, I will reach the last result, which is fairly recent, happening after I left Unicamp and came to the CNPEM. One of CNPEM’s goals is to explore renewable source materials to produce advanced materials. There is a whole philosophy behind this, based on the depletion of natural resources, sustainability…  We have worked hard in order to make new things with materials derived from biomass, and the main focus is cellulose. It is the most abundant polymer in the world, but it is very hard to work with it. You cannot process cellulose as you process polyethylene, for example.  One of our goals has been to find ways to laminate cellulose, i.e., work it as closely as possible to the way we use to work synthetic polymers. A recent outcome, built upon this idea, is that we managed to produce cellulose adhesives having it as the only polymer, which is new. A patent application was entered in the beginning of the year, and we are submitting a paper on it, while aiming to work with companies that are interested in the subject. We are already discussing a project for a specific application of this modified cellulose with a company.

This is the latest case. In the middle of the way, many other projects were conducted with companies, for issues of their interest. Coating something, gluing another, modifying a polymer to achieve a certain result. But these were answers to demands from companies, instead of researches started at the laboratory.

SBPMat Newsletter: – Leave a message for our readers who are starting their careers as scientists.

Fernando Galembeck: – First of all, in any chosen career, there must be a dose of passion. It does not matter if you are going to work in the Stock Market, Healthcare or whatever you may do; above all, your taste must decide. If a person chooses a career because it will give them money or status… I think it is a bad choice. If you do things with pleasure, with interest, the money, prestige and status will come from other paths. The goal is to do what makes you happy, what makes you feel good when you do it, what makes you feel accomplished. It is true not only for the scientific career, but also to any other career. In science, it is crucial.

Another point is that you must be prepared to work hard. There is no easy way. I know some young people who are constantly seeking the great idea that will bring them success with relatively little work. Well, I’d better not count on it. It may even happen, but waiting for it is almost the same as wait to win the Lottery and get rich.

I’m over 70, therefore I have met many people and seen many things happen. Something that strikes me is how young people who seemed very promising end up not working very well.  Frankly, I think it is bad for youngsters to achieve success too early, because I have the impression they get used to this idea that things will always work out fine. And the problem is that there isn’t anything, anyone, any company that will always work. There will always be the moment of failure, the moment of frustration. If the person is prepared for that, when the times come, he or she will overcome it, while others are crushed – they cannot move one. That is why we must be careful not to be deceived by our success and think that, because it worked once, it will always work. You must be prepared to fight.

When I was in college, thinking about doing research seemed a very strange thing to do, crazy talk. People did not know very well what it was, or why would someone choose to do it. Some people said that research was something like priesthood. I have always worked with research, associated with teaching, consulting and, without having ever sought to become rich, I managed to have an economic status that I deem very comfortable. But I insist, my goal was to enable the development, to produce material, not the money I would receive. Money came, as it does. So, I suggest you to focus on your work, on the results and the contribution that said work may give to other people, to the environment, to the community, to the country, to knowledge. The rest comes as a bonus.

In short, my message is: work seriously, earnestly and passionately.

Finally, I would like to point out that I think the research work, the development work, really helps you to grow as a person. It will depart you from ideas that are not very fruitful and guide you towards attitudes that are really important and helpful. A student asked Galileo once: “Master, what is the method?”, and Galileo’s answer was: “The method is the doubt”. I think it is very important in the research activity, which, for Materials in particular, is especially interesting because the final product is something you can hold in your hands. In the research activity you have to always wonder, “I’m thinking like this, but is this right?”, or “This guy wrote this, but what are his bases to write it?”. This attitude is very different from the dogmatic one, which is common in the realms of politics and religion, and very different from the attitude of someone who has to deceive, as the lawyer who works for a mobster or drug dealer. The researchers have to commit themselves to the truth. Of course there are also people who call themselves researchers and spread disinformation.  Some years ago, people were talking about something called “Bush science”, an expression referring to President Bush. This Bush science was the arguments fabricated by people who gained money as scientists, but who produced arguments to sustain Bush’s policies. In other words, the problem exists in science as well, but then we get back to what I said earlier. You cannot enter this field because of money, or to achieve prestige, or to be invited to have dinner with the president; you must enter this field because of your interest in the subject itself.

Inscrições abertas para bolsas de verão do Centro Nacional de Pesquisa em Energia e Materiais (CNPEM).

Estudantes universitários em nível de graduação interessados em participar do 22º Programa Bolsas de Verão do CNPEM devem fazer a inscrição até 30 de outubro.

O objetivo do Programa é incentivar a formação de recursos humanos qualificados para o trabalho científico e tecnológico. O Programa aceita inscrições de alunos da América Latina e Caribe de cursos de Engenharia Elétrica, Engenharia Mecânica, Física, Quimica, Computação, Matemática, dentre outros, que estejam matriculados a partir do 4º semestre e tenham bom desempenho acadêmico.

O CNPEM é composto por quatro laboratórios nacionais: Laboratório Nacional de Luz Síncrotron (LNLS), Laboratório Nacional de Biociências (LNBio), Laboratório Nacional de Ciência e Tecnologia do Bioetanol (CTBE) e Laboratório Nacional de Nanotecnologia (LNNano). Os selecionados passarão os meses de janeiro e fevereiro dedicados a realizar projeto individualizado, sob orientação de pesquisadores do Centro Nacional de Pesquisa em Energia e Materiais (CNPEM), em Campinas, São Paulo.

Os benefícios do Programa incluem a passagem de ida-volta desde o local de origem do estudante até Campinas, hospedagem, alimentação, seguro-saúde e traslado diário para o campus do CNPEM.

Informações completas sobre o 22º Programa Bolsas de Verão do CNPEM estão
em http://www.cnpem.org.br/bolsasdeverao