Former B-MRS president Osvaldo Novais de Oliveira Junior is the author of a text about Brazilian science published in Folha de São Paulo

Prof. Osvaldo Novais de Oliveira Junior
Prof. Osvaldo Novais de Oliveira Junior

Professor Osvaldo Novais de Oliveira Junior (IFSC-USP), member and former president of SBPMat, is the author of a text published in Folha de São Paulo, one of the main Brazilian newspapers, on the blog ‘Darwin e Deus’ (column by science journalist Reinaldo José Lopes) about the success and impact of Brazilian science. In the text, the professor describes three types of knowledge resulting from science and highlights the importance of increasing the number of scientists and professionals trained in research environments in order to meet the demands of the Brazilian population.

Here follows the text:


The greatest proof of the success of Brazilian science is at the Planalto Palace. Were it not for the excellence of Brazilian medicine, the result of decades of scientific work, today there would be another President of the Republic.

Without the competence of the doctors of Juiz de Fora who promptly attended the then candidate after the stabbing episode, as well as the doctors in São Paulo who performed the other surgeries, President Bolsonaro, even if he survived, would not have recovered so quickly to the point of working normally shortly after the attack.

In my opinion, the connection between facts that change the direction of the country and Brazilian science does not seem to have been made as of yet. This is probably so because the effect of the different forms of knowledge that science creates has not been analyzed in detail.

Doing science generates three types of knowledge. The most visible and tangible is the knowledge that generates, in a relatively short time, technology and solutions for humanity. It is the knowledge transferred from scientists to technology innovators, which in the 21st Century has been accomplished mostly by the great technological powers, that is, the United States, China and other Asian countries, and some countries in Europe. Here, the majority term is essential, as it is not enough to have quality science and technology, as knowledge transfer only occurs effectively when there is a volume of research, products and solutions.

The two other types of knowledge are less visible to society in general. One is the knowledge derived from the curiosity and perseverance of humans in understanding how the universe works, without concern if there will be any practical application. Often, the application exists, but it will only become evident long after such knowledge has been generated. Perhaps the most emblematic example today is Einstein’s theory of relativity. It was created with an abstract conception, incomprehensible even for scientists of the time, to explain the phenomena of nature that had no correlation with people’s daily lives.

As far as I know, Einstein never suggested the possibility of a direct application to his theory. Well, the Theory of Relativity is now essential for positioning systems (GPS). Without taking into account the Theory of Relativity, determining the position of a person or object on Earth would be wrong for about 10 km with the errors accumulated in a week of GPS operation. In short, without the Theory of Relativity there would be no GPS or the navigation systems we use in our daily lives.

The third type of knowledge has so little visibility that it is confused with the result of university education. It is knowledge that does not lead directly to new technologies, but serves to absorb and adapt technologies, develop local solutions and allow high-level functioning of systems that depend on technology. This type of knowledge is incorporated by qualified professionals trained at research universities.

What is not always understood is that professionals with this level of skill and competence can only be trained in an environment where science is done. In medicine, to stay on the initial example, the incorporation and improvement of new technologies are usually done by doctors with sophisticated training, with postgraduate degrees and active participation in research programs conducted at universities of excellence.

For those who consider this third type of knowledge is of little relevance, I emphasize that countries with better quality of life and higher development rates are not on the list of those that generate more technology. I refer to Scandinavian countries and others like Switzerland and Luxembourg, which, due to the size of their population, are not large enough to generate a lot of technology – compared to the largest technology-producing countries. However, without any exception, all these countries with high quality of life have high density in generating knowledge of the third type, with excellent science.

And Brazil? Our country has outstanding examples of knowledge generation of the first type, with science providing competitive technology worldwide in sectors such as aeronautics, oil extraction in deep waters and agribusiness. Other sectors have created relevant technologies, albeit with less economic impact.

Unfortunately, despite the quality of science carried out in these sectors, density is low and we generate very little technology when the dimensions of the country and its population are taken into account. This is explained by the small size of our scientific system. Despite the great advance in recent decades, the number of scientists per inhabitant is still much smaller than that of developed countries. In this regard, Brazil does not appear on the list of the 20 best ranked countries.

A similar situation occurs in knowledge oriented to the development of local solutions, which I classified as a third type. Brazil trains excellent professionals at its research universities, which in turn incorporate new technologies and create solutions for society in many areas. This results in the country’s excellence in areas such as medicine and health, engineering, agriculture and livestock, and in many other areas.

Again, we have the density problem: the number of trained professionals, and their role in generating knowledge, is insufficient to benefit the entire Brazilian population. This insufficiency is at the root of our inequality, since the extremely low productivity at work depends essentially on the good functioning of technologies that demand knowledge of this third type, in which the supply of trained professionals is insufficient.

In short, the problem in Brazil is not low quality of science that is done here, but the low density of scientists and professionals trained to meet the demands of society. In addition to bringing the erroneous perception of lack of quality, the low density in fact makes it difficult (when not preventing) a country to achieve excellence in topics that require concentrated efforts of great importance. It is not for any other reason that Brazil is competitive in technologies, such as those already mentioned, in which there is a density of trained researchers, based on public policies initiated decades ago.

I expect our leaders, at all levels, will realize the direct and indirect benefits of a robust and quality scientific system. Even if it is for their survival in the event they need adequate health care. But mainly to fulfill the dream of transforming Brazil into a less unequal country.


 

B-MRS Newsletter. Year 7, issue 2.

 

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Newsletter of the
Brazilian Materials
Research Society

Year 7, issue 2. March 11, 2020.

B-MRS News

New B-MRS board. Get to know the members of the new executive board: their academic training, research topics, what they like to do when they are not working and more. See here.

– Swearing-in ceremony. B-MRS new executive board, chaired by Professor Mônica A. Cotta, took office at a ceremony held at IFGW-Unicamp on the morning of February 14, attended by more than 80 people, including authorities from the Brazilian Ministry of Science and Technology, scientific societies, research centers and universities. In their brief speeches recurrent subjects were women in science and the social impact of research. Know more.

– Note in defense of democracy. B-MRS and dozens of Brazilian scientific entities endorsed SBPC’s note in defense of democracy, published on February 26. Know more.

Featured Paper

A research group from the Brazilian Nanotechnology National Laboratory developed a memristor and a transistor with hybrid materials (organic – inorganic) and microtubes made of self-rolled nanomembrane. The new components can contribute to the development of smaller, flexible and cheaper devices that combine better performance and lower energy consumption. The works were recently reported in Nano Letters and Nature Communications. Know more.

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From Idea to Product

We tell the interesting story of Kevlar, a lightweight and super resistant material used in hundreds of products from dozens of different markets. The story begins with a fundamental science discovery made by a woman without a PhD, who found in the laboratories of the DuPont company, in the middle of the last century, a favorable environment to develop her talent and passion for scientific research. Know more.

stephanie news

News from B-MRS Members

– Prof. Victor Carlos Pandolfelli (DEMa-UFSCar), B-MRS member, received an award from TMS (The Minerals, Metals and Materials Society, USA) for papers that show the application of science in solving practical problems. Know more.

19 encontro_banner_560 px

XIX B-MRS Meeting + IUMRS ICEM 2020
(Foz do Iguaçu, Brazil, August 30 – September 3, 2020)

Website: www.sbpmat.org.br/19encontro/

Abstract submission is open by April 1st!

Abstract submission. Deadline: April 1st. Guidelines for preparing and submiting abstracts, here. Guidelines for oral and poster presentations, here.

Symposia. The event comprises 29 thematic symposia. See the list, here.

Registration. The registration system is open. July 15 is the deadline for early registration (with discount). The fees include three lunches, besides the coffee breaks and the welcome cocktail. Know more, here.

Exhibitors and sponsors. 15 companies have already confirmed their participation as exhibitors-sponsors of the event. Companies and other organizations interested in participating in the event as exhibitors, sponsors or supporters, can contact Alexandre at comercial@sbpmat.org.br before March 31.

Student awards. Authors of works that are undergraduate, master’s or doctoral students may compete for the B-MRS and ACS Publications awards by submitting extended abstracts after receiving notification of acceptance of their conventional abstracts. More information in the instructions for authors, here.

International plenary lectures. Renowned scientists from China, Italy, Japan and USA have already confirmed their presence as speakers at the event. Know more at the event website.

José Arana Varela Lecture (national plenary lecture). Professor Edson Roberto Leite (LNNano – CNPEM) was chosen by B-MRS to receive this distinction and will give the lecture at the event.

Joaquim da Costa Ribeiro Memorial Lecture. The honor goes to Professor Cid Bartolomeu de Araújo (UFPE), who will give the lecture at the event.

Venue. The event will be held at Rafain Palace Hotel and Conventions, located in Foz do Iguaçu (Brazil). Know more.

Accommodations. See accommodation options from the event official travel agency, here.

Joint event. The event brings together the 19th edition of the B-MRS annual meeting and the 17th edition of the International Conference on Electronic Materials organized every two years by the International Union of Materials Research Societies (IUMRS).

Organization. Professor Gustavo Martini Dalpian (UFABC) is the general coordinator, Carlos Cesar Bof Bufon (LNNano) is the program coordinator and Flavio Leandro de Souza (UFABC) is the general secretary. At the international committee, the event features scientists from America, Asia, Europe and Oceania. Know more at the event website.

Reading Tips

– Scientists increase the efficiency of converting CO2 into methanol by developing and using an intelligent membrane, whose nanochannels drain water, but prevent the passage of gases. This membrane can accelerate several industrial processes limited by the presence of water (Science). Know more.

– Brazilian advances in perovskite synthesis and characterization: scientists are able to produce new 2D perovskite and also individually map nanometric grains of perovskite films, opening possibilities for the application of these materials in LEDs and solar cells (Chemistry of Materials and Science Advances). Know more.

Events

Pan American Ceramics Congress and Ferroelectrics Meeting of Americas (PACC-FMAs 2020). Panamá (Panamá). July 19 – 23, 2020. Site.

International Conference on Science and Technology of Synthetic Materials (ICSM 2020). Glasgow (UK). July 26 – 31, 2020. Site.

XVIII International Congress on Rheology. Rio de Janeiro, RJ (Brazil). August 2 – 7, 2020. Site.

XIX B-MRS Meeting + 2020 IUMRS ICEM (International Conference on Electronic Materials). Foz do Iguaçu, PR (Brazil). August 30 – September 3, 2020. Site.

XLI Congresso Brasileiro de Aplicações de Vácuo na Indústria e na Ciência. Foz do Iguaçu, PR (Brazil). October 5 – 7, 2020. Site.

5th International Conference of Surfaces, Coatings and NanoStructured Materials – Americas (NANOSMAT-Americas). Foz do Iguaçu, PR (Brazil). October 7 – 10, 2020. Site.

7th Meeting on Self Assembly Structures in Solution and at Interfaces (AutoOrg). Bento Gonçalves, RS (Brazil). November 4 – 6, 2020. Site.

Follow us on social media

You can suggest news, opportunities, events or reading tips in the materials field to be covered by B-MRS Newsletter. Write to comunicacao@sbpmat.org.br.

 

 

Featured paper: Nanomembrane microtubes and hybrid materials for advanced electronic devices.

Some of the challenges of the next generation of smartphones, sensors and other electronic devices can be solved with the help of nanomembrane microtubes (sheets made from various materials with nanometric thicknesses and micrometric lateral dimensions, which can be self-rolled and form microtubes).

In the city of Campinas (São Paulo State), at the Brazilian Nanotechnology National Laboratory of the National Center for Research in Energy and Materials (LNNano / CNPEM), a group of scientists has developed expertise in processes for the synthesis, manufacture and characterization of nanomembranes and their applications. In papers published in January and February of this year in the journals Nano Letters and Nature Communications, the authors explore some nanomembrane potentials, mainly related to their flexibility and dimensions, to develop new memristors and transistors – two widely used electronic devices.

More precisely, the LNNano researchers show that nanomembrane microtubes can be key parts in the manufacture of promising components using organic and hybrid materials (organic-inorganic) such as memristors and transistors. Thus, the novelties proposed in the articles can contribute to the development of even smaller, flexible, portable, cheaper devices and equipment that combine better performance and more low energy consumption features.

In an interview with the B-MRS Newsletter, Carlos Cesar Bof Bufon, corresponding author of both articles, talks about the scientific, technological and social impact of the research and about the skills and infrastructure involved in carrying it out. Bufon is a researcher and head of the Devices Division at LNNano/CNPEM.

B-MRS Newsletter: The articles present advances, developed at LNNano, in technologies for electronic devices (transistors and memristors). In your opinion, what are the main technological and/or scientific contributions of these articles?

Carlos Cesar Bof Bufon: The work entitled “Ambipolar Resistive Switching in an Ultrathin Surface-Supported Metal–Organic Framework Vertical Heterojunction” published in Nano Letters (DOI: 10.1021/acs.nanolett.9b04355), reports the development of a new type of memristor using structures called Surface-Supported Metal-Organic Frameworks (SURMOFs). SURMOFs are hybrid structures composed of metallic ions connected by organic ligands. The structure is highly organized on surfaces covered with chemically active self-assembled monolayers (SAMs). There are more than 70 thousand types of metal-organic structures (MOFs) that can be prepared as SURMOFs to confer new features to electronic devices. In addition to the unique properties, its considerable mechanical flexibility and low cost arouse interest in the scientific community for applications. However, in the case of a hybrid material consisting of organic and inorganic elements, the integration of this class of nanomaterials becomes a technological challenge. To circumvent this limitation, this work presents a new architecture for the integration of these SURMOFs structures for the development of a new type of memristor. The proposed architecture is based on the upper electrical contact of SURMOF HKUST-1 ultrathin films using self-rolled metal nanomembranes (microtubes). The SURMOF films explored in this work have thicknesses of the order of 20 nanometers. This new architecture opens up promising paths in the area of electronic devices based on SURMOFs, as well as providing a technological platform for conducting studies not yet reported in the literature for this class of materials. For example, the investigation of how electrical charges are conducted in layers of ultrathin SURMOFs.

Photograph of a microchip fabricated using photolithography, and illustration of the electrical contact on the SURMOF performed by the strained metallic nanomembrane after the rolled-up process. The chip has 81 mm2 and contains 32 memristors.
Photograph of a microchip fabricated using photolithography, and illustration of the electrical contact on the SURMOF performed by the strained metallic nanomembrane after the rolled-up process. The chip has 81 mm2 and contains 32 memristors.

The work entitled “Edge-driven nanomembrane-based vertical organic transistors showing a multi-sensing capability” published in Nature Communications (doi: 10.1038/s41467-020-14661-x) presents the development of a vertical organic transistor platform. Transistors are the main components for electronic circuits and processors. Compared to inorganic transistors, the organic ones have the advantages of low-cost and easy fabrication, which makes them attractive for flexible electronic devices in several areas. A significant advantage of vertical transistors is their easy integration with light-emitting devices and photodetectors in the formation of integrated optoelectronic systems. The devices presented in this work were processed entirely using conventional microfabrication and photolithography techniques, which is an advantage of technological feasibility. One of the main differences of these new transistors is related to the use of self-rolled metallic nanomembranes as drain electrodes, thus promoting the formation of a smooth mechanical contact with the organic semiconductor layer. In this architecture, the organic semiconductor layer can reach thicknesses below 50 nanometers. The manufactured devices showed high current densities (~ 0.5 A / cm2) with low operating voltages (≤ 3 V). Based on our theoretical study, it was possible to predict an improvement in the structure of the transistor, resulting in projections of devices with current densities of up to 10 A / cm2. Such values, obtained at low operating voltages on a platform composed of active organic layers, highlights the potential of these devices to be integrated with flexible and portable electronic applications in the future. Besides, the new transistors were able to detect different levels of humidity and light, thanks to the device platform based on self-rolled nanomembranes. Therefore, the developed transistors also have great potential for advancing next-generation sensor technology.

 Scanning electron microscopy image (artificially colored) of the vertical organic transistor based on rolled nanomembrane (yellow tones). The incident radiation and the water molecules (artificially placed) illustrate the multiple sensitivity characteristics of the new electronic device.

Scanning electron microscopy image (artificially colored) of the vertical organic transistor based on rolled nanomembrane (yellow tones). The incident radiation and the water molecules (artificially placed) illustrate the multiple sensitivity characteristics of the new electronic device.

B-MRS Newsletter: How could the results of the articles impact people’s daily lives (social impact)? Do you think that the proposed technologies could replace those currently used or create new applications? If so, what would be the advantages of these new technologies developed at LNNano? Would it still need many steps to bring the results of the articles to the market?

Carlos Cesar Bof Bufon: Memristor is considered one of the four fundamental electronic components. On a computer, it is capable of performing information processing and storage functions. In this work, the behavior of a memristor was observed in conditions of high relative humidity (between 90-70%). Analogous to a sponge, the water molecules present in the environment are absorbed by SURMOF nanopores. In a given electric field, these molecules facilitate the conduction of electrons within the material by changing its electrical resistance. The difference in electrical resistance can reach 1 million times using low operating voltages, less than 2 V. In a practical application, this difference can correspond to the binary states 0 and 1. The total fabrication of the device was carried out with conventional techniques photolithography, compatible with industrial scale production. The fact that it depends on the humidity for its operation does not limit its commercial application, as this can be easily bypassed through encapsulation processes, common in the electronic device industry.

The manufacture of organic transistors in vertical architecture using curled nanomembranes as drain electrodes allows the reduction of the region of interest to less than 50 nanometers (more than a thousand times less than the thickness of a hair). This implies a significant advance in the electronics industry, because the portability of electronic applications, such as smartphones, computers and televisions, depends on the reduction in the number and size of transistors. The mechanism of operation of the device reported in this work expands the current understanding of vertical organic transistors, showing that current densities can be improved by performing careful manipulations in the spatial structure of the intermediate metallic electrode (source). Besides, the preparation of transistor microchips was carried out using microfabrication techniques compatible with the industrial scale. Thus, these devices can be easily integrated into electronic applications with a few additional steps, such as encapsulating microchips, to prevent degradation of organic materials.

The two concepts of devices based on nanomembranes expand the possibilities for the use of hybrid materials in electronics. As much as there is a tendency to substitute one technology for another, the concepts developed in our works seek to open new frontiers and possibilities through the design of functional structures from their fundamental elements such as atoms and molecules.

All the technologies that we develop in the area of devices at LNNano/CNPEM are firmly grounded in two focus: the understanding of the fundamental concepts that govern the properties of the components, and their technological application. These two papers started fundamentally from scratch. In terms of technology readiness level (TRL), the devices have reached the functional validation of the components in the laboratory environment. Within the TRL scale, we achieved the fourth level out of a total of 9 – the latter being commercialization. It is also worth mentioning that the next level of development must involve the participation of the productive sector, which is who can accelerate the research towards the market.

B-MRS Newsletter: Briefly tell us the story of the works reported in the two articles: how and when the idea came up, whether it was necessary to gather very different skills, the infrastructure used, curiosities etc.

Carlos Cesar Bof Bufon: The works are the result of different stories, but were developed in the same research group sharing the idea of exploring the potential of nanomembranes in the area of functional devices. This theme is part of my Young Researcher project financed in 2016 by FAPESP. The idea of applying SURMOFs as a memristor, using nanomembranes as the top contact, was developed together with the post-doctorate Dr. Luiz Gustavo Simão Albano. Our research group started evaluating the feasibility of using SURMOFs as functional materials in devices about 3 years ago. Since then, the group has been continuously establishing the implementation of synthesis and integration routes for applications in the areas of electronic components. The work was carried out entirely at LNNano/CNPEM, and has a list of co-authors who actively contributed to making this work possible: Tatiana P. Vello (growth of SURMOFs), Davi HS de Camargo (manufacture of devices and illustrations), Ricardo ML da Silva (device manufacturing), Dr. Antonio CM Padilha (DFT simulations) and Prof. Dr. Adalberto Fazzio (DFT simulations).

The work with the transistor follows the same pattern as the memristor – a combination of functional materials and nanomembranes. About 15 years ago, I became interested in the potential of using nanostructured layers as fundamental blocks in vertical electronics. Once I was aware of the work of Prof. Ivo Humlegem, from UFPR (died 2018), in the area of vertical transistors, a series of advantages and challenges caught my attention. The idea of the work came by anticipating that an improvement of the performance of vertical transistors could be achieved with the use of a drain electrode based on nanomembrane combined with a patterned intermediate electrode (source) using photolithography. In May 2018, Dr. Ali Nawaz (a former student of Prof. Ivo!), started the execution of the project at LNNano/CNPEM. Being a complex project, the advanced infrastructures for processing and characterizing LNNano/CNPEM devices were essential. And like the memristor, the research depended on a set of varied expertise. During the project, Dr. Leandro Merces provided critical assistance in the investigation of the theoretical aspects of the devices, while collaborators Davi Camargo (specialist in microfabrication) and Denise de Andrade (graduate trainee at the State University of Ponta Grossa), provided the entire work the necessary technical support.

Main authors of the papers. From the left: Carlos Cesar Bof Bufon, Luíz Gustavo Simão Albano and Ali Nawaz.
Main authors of the papers. From the left: Carlos Cesar Bof Bufon, Luíz Gustavo Simão Albano and Ali Nawaz.

 

[Papers: Ambipolar Resistive Switching in an Ultrathin Surface-Supported Metal–Organic Framework Vertical Heterojunction. Luiz G. S. Albano, Tatiana P. Vello, Davi H. S. de Camargo, Ricardo M. L. da Silva, Antonio C. M. Padilha, Adalberto Fazzio, Carlos C. B. Bufon. Nano Lett. 2020, 20, 2, 1080-1088. https://doi.org/10.1021/acs.nanolett.9b04355 and Edge-driven nanomembrane-based vertical organic transistors showing a multi-sensing capability. Ali Nawaz, Leandro Merces, Denise M. de Andrade, Davi H. S. de Camargo & Carlos C. Bof Bufon. Nature Communications volume 11, Article number: 841 (2020). https://www.nature.com/articles/s41467-020-14661-x ].

From idea to product: Kevlar, the strength of a scientific discovery.

Poliaramide fabric.
Poliaramide fabric.

The bulletproof vests that protect police and military personnel around the world, the cords that held the Pathfinder spacecraft on its descent to the surface of Mars, and the gloves worn by workers in the metalworking industry. What do they have in common?

The answer is Kevlar®, a highly durable polymeric synthetic fiber that combines high strength and low weight (it is five times more resistant than steel per weight module). The fiber can be used as a raw material for cords or flexible and comfortable fabrics. Also, it can be added to other materials to reinforce them. Kevlar® generates products capable of resisting the most diverse aggressions, from shrapnel and stab wounds to firearm shots. Also resistant to extreme temperature and pressure conditions, the fiber has been in the desert, on the mountain, in Antarctica, on the seabed and in space.

The history of this material begins, of course, with a scientific discovery that was made in 1965 in one of the DuPont laboratories by Stephanie Louise Kwolek. Stephanie had a bachelor’s degree in chemistry, without a doctorate and was the only female representative in the laboratory. Her competence and passion found in this place and at that moment a favorable environment, which yielded good results, not only for the company, but also for humanity as a whole.

From walks in the woods to DuPont laboratories

Stephanie Louise Kwolek.
Stephanie Louise Kwolek.

Stephanie Kwolek was born on July 31, 1923 in the United States, the daughter of Polish immigrants. Together with her parents and younger brother, her childhood was in New Kensington, a small town 30 km from Pittsburg, Pennsylvania, in a wooded area she used to walk with her father while trying to discover animals and identify plant species, whose leaves were pasted and classified in a notebook. Her father deceased when she was only 10 years old, but he was responsible for developing a strong curiosity and taste for experimentation in Stephanie. With her mother, who until her father’s death spent much of her time at home in front of the sewing machine (later she started working in the industry to support the family), Stephanie developed her creativity and taste for fashion. The girl loved making paper clothes for her paper  dolls.

After fantasizing about a career as a fashion designer, Stephanie Kwolek discovered that she wanted to be a doctor. However, as medical school was very expensive, she went to study science at Carnegie Mellon University in Pittsburg. More precisely, she attended Margaret Morrison Carnegie College, which was a college for women within that university. During her university years, in addition to an excellent academic performance, Stephanie gathered laboratory experience, doing work for the university and for companies during her summer vacations.

Stephanie graduated in 1946, at the age of 23, with a “major” in chemistry and a “minor” in biology, and went on to look for a job in the field, thinking about working for a few years until she collected the money to start her medical course. Stephanie was quickly hired by DuPont – by then already famous for the invention of nylon, the first synthetic fiber in history, among other products. The young woman then moved to Buffalo, New York, to work as a chemist in the Rayon Department, which would later become the Pioneer Textile Research Laboratory, where she worked with the synthesis of new polyamides and polyesters.

In 1950, the laboratory was transferred to the company’s main “invention site,” the so-called Experimental Station, located in Wilmington, Delaware, where Stephanie moved to in order to contribute with the team that would try to develop new methods of polymer production, performed at low temperatures, to create fibers with the highest possible resistance.

Passionate about the laboratory

By that time, Stephanie had already traded her dream of being a doctor for the passion of being a scientist. It fascinated her to have a new challenge each day and to learn something new every day. Furthermore, the working environment in that DuPont laboratory was very positive for her.

To begin with, the job was stable and there was a certain freedom to choose the research topics, within a list that the director prepared based on the company’s objectives. (Stephanie always liked participating in two projects simultaneously, preferably one that was more fundamental and the other one more applied). To develop her research, Stephanie could work independently, following her own plans, and without the pressure to generate immediate economic results. She just needed to have good sense to know when to stop a project that would not bear fruit in the medium term. This possibility of independent and free research was important not only to satisfy the researcher’s creative and curious nature, but also because she was working on very new lines of research, still lacking fundamental research, which needed to be done within the laboratories of the company.

In addition, there was great equipment and many opportunities to exchange ideas with colleagues. Finally, Stephanie was able to publish her results in articles or books, after the texts were reviewed by professionals from various sectors of the company, who checked whether the publication of that data could harm business. For Stephanie, writing articles was an important moment in her work, when ideas became more organized and results were subjected to scrutiny.

quote1_enIn her view, the set of good working conditions generated a conducive medium for scientific discoveries capable of generating radical innovations (new materials or molecules and new synthesis processes) that could position the company at the forefront of the market. As was the case with Kevlar®.

The discovery that spawned Kevlar®

In the 1960s, the Pioneer Research Laboratory in Textile Fibers became involved in the search for a fiber being very resistant, but also very light. One of DuPont’s goals was to offer the market a material that would replace steel as a rubber additive in tire manufacturing, so as to make tires lighter and thus reduce fuel use, as a period of oil shortage was expected in the following years.

After experimenting with dozens of different polymers, the laboratory decided to start working with the group of polyaramides, or aromatic polyamides, which were promising in terms of properties, but also famous among researchers for the difficulty of dealing with them in the laboratory. The polyaramides were particularly difficult to dissolve due to the rigidity of their rod-shaped molecules, unlike the flexibility of many other polymer molecules.

Persistent, as well as competent, Stephanie Kwolek was cast to participate in the challenge. Or, rather, the challenges, in the plural, that arose daily in each of the stages involved: the choice and synthesis of the compounds that would react to form the polymer (which, at the time, did not readily exist for sale), the polymerization method and, not least, the dissolution of the polymer obtained. In fact, to form the polymer fiber desired by DuPont, it was necessary to spin the polymer. For this, the laboratory had a very simple equipment, called a spinneret, in which a polymeric solution is forced to pass through small holes. In the next step, the solvent is removed and the fibers obtained.

At this stage of development, Stephanie was testing different compounds to dissolve the difficult polyamides, when she looked at her freshly prepared polymer solution and noticed, with the naked eye, that it was essentially different from all the others she had ever seen. The new solution was opaque and fluid, and not transparent and viscous as expected. In addition, when stirred, it was opalescent (with reflections in the colors of the rainbow).

Instead of throwing it down the drain, she got excited and took it to the spinneret to perform the spinning test. Believing that the milky aspect was due to the presence of particles in suspension that could clog the holes of the spinneret, the equipment technician refused to do the test. The spinning was done a few days later, after Stephanie scientifically proved that there were no particles in the solution. And the result was remarkable. The polyamide fibers obtained with the recipe developed by Stephanie were much more resistant than nylon, and also more resistant than steel, but much lighter. As soon as she confirmed the results of the characterization of the new material, she presented her discovery to her superiors, who joined her enthusiasm.

But what is the explanation for the super strength of polyamide fibers? Here’s the thing. Stephanie Kwolek managed to temper a polyaramide and with it prepare a polymeric solution of rigid macromolecules. During the spinning process, these molecules remained fully stretched and aligned in an orderly fashion. The result was a fiber with a very organized structure, from which the exceptional properties emerged.

quote2_enThe solution she had placed in the spinneret, the scientist would later discover, could be classified as a liquid crystalline solution. From this discovery, several new high-performance fibers were created based on liquid crystalline solutions, mainly Kevlar®.

Product and market development

The development of the Kevlar® product, which started immediately after Stephanie’s discovery in 1965, took several years within DuPont, and involved an interdisciplinary team without the direct participation of Stephanie, who remained in the laboratory in search of new discoveries. The process included the development of the final chemical formula and adjustments to the spinning equipment. The adaptation to the industrial scale took into account economic, practical and ecological issues. In addition, starting in 1972, a marketing plan for Kevlar® was designed and put into practice, based on partnerships with potential customers to customize the product according to the desired application, generating an entire family of fibers.

Thus, it was in 1982 that the product was actually marketed, seventeen years and hundreds of millions of dollars after the initial scientific discovery. Since then, the Kevlar® family has conquered dozens of markets through hundreds of products, such as firemen boots, coatings for armored cars, rackets and components for boats, airplanes and automobiles, to name just a few examples besides those mentioned in the beginning of this story.

As for Stephanie Kwolek, she continued to work at DuPont until her retirement in 1986. She won several awards and honors for her work with liquid crystal solutions. She became a female icon of scientific discovery and “the face” of Kevlar®. After leaving the company, she dedicated time to encouraging girls to work in research, in addition to advising DuPont. She died at the age of 90, in June 2014, in Wilmington.


Some references:

  • Stephanie L. Kwolek, interview by Raymond C. Ferguson in Sharpley, Delaware, 4 May 1986 (Philadelphia: Chemical Heritage Foundation, Oral History Transcript # 0028). Available here.
  • Stephanie L. Kwolek, interview by Bernadette Bensaude-Vincent at Wilmington Delaware, 21 March 1998 (Philadelphia: Chemical Heritage Foundation, Oral History Transcript #0168).
  • Women in Chemistry: Stephanie Kwolek. Canal no YouTube do Science History Institute. Available here.
  • The Kevlar Story – an Advanced Materials Case Study. David Tanner, James A. Fitzgerald, and Brian R. Phillips. Angew. Chem. Int. Ed. Engl. Adv. Mater. 28 (1989) No. 5.
  • Kevlar Technical Guide. Available here.

B-MRS member receives award from TMS (USA)

Prof. Victor C. Pandolfelli
Prof. Victor C. Pandolfelli

Professor Victor Carlos Pandolfelli (DEMa-UFSCar), a B-MRS member, received an award from TMS (The Minerals, Metals and Materials Society, USA) as co-author of the work “Improving the reliability of fluidized bed calciners by suitable refractory lining selection,” presented in 2019 at this society’s annual meeting. The award, whose name is “Light Metals Subject Award – Alumina/Bauxite” is dedicated to research that highlights the application of science in solving practical problems. The award ceremony took place on February 24, 2020, during the 149th TMS Annual Meeting, which was held in San Diego, California (USA).

The award-winning work, coordinated by Pandolfelli, was carried out within a joint project between the company 4 Cast, specialized in ceramic materials for high temperature applications, and UFSCar. Mariana A. L. Braulio (4Cast), J. R. Cunha (Alcoa Alumar – Brazil) and D. Whiteman (Alcoa- Australia) also received the award as co-authors of the work.

New B-MRS Board of Directors took office at a ceremony.

The new board of directors of the Brazilian Materials Research Society (B-MRS) took office on the morning of February 14, in a ceremony held in the auditorium of the Gleb Wataghin Institute of Physics at Unicamp (IFGW – Unicamp), in the city of Campinas (São Paulo state), with the presence of more than 80 people.

Elected by the members of B-MRS in October 2019 for the February 2020 to February 2022 term, the new board is chaired by Prof. Mônica Alonso Cotta (IFGW-Unicamp), who became the first female president of B-MRS.

Another characteristic of this board is the broad representation in geographical terms (directors from the south, southeast, northeast and north Brazilian regions), disciplinary terms (backgrounds in Physics, Chemistry and Materials Engineering) and gender (four men and three women).

Along with the president, Rubem Luis Sommer (CBPF) assumed his duties as director of administration, finance and patrimony, as well as five scientific directors: Prof. Andrea Simone Stucchi de Camargo  (IFSC-USP), Prof. Antonio Eduardo Martinelli (UFRN), Prof. Iêda Maria Garcia dos Santos (UFPB), Prof. Ivan Helmuth Bechtold (UFSC) and Prof. Newton Martins Barbosa Neto (UFPA).

In her speech, the president highlighted the interdisciplinary nature of the materials research community and, in particular, that of B-MRS. “One of our strengths derives precisely from the synergy between the areas, and this requires good communication skills between researchers, respecting complementary expertise, sharing knowledge, to obtain a product that is greater than the sum of its parts,” said Cotta, who added that communication with the lay public will be one of the fronts that the new board will focus on as a priority.

In addition, Professor Cotta highlighted the importance of the scientific community in taking a stand against political decisions with no scientific basis that can affect the lives of millions of people. “B-MRS will continue to support the excellent work that the Brazilian Society for the Advancement of Science and the Brazilian Academy of Sciences have lead in recent years, working with Congress in a purposeful and meaningful way, and demonstrating strong defense of Brazilian research and science,” she added. See full speech here.

Professor Cotta received this position from her predecessor, Prof. Osvaldo Novais de Oliveira Junior (IFSC-USP), who chaired B-MRS for two consecutive terms. The former president, who received praise for his management in the speeches of the authorities, expressed words of gratitude to the B-MRS team, to the directors and members of the deliberative council that accompanied him, and to the B-MRS members who participated in the actions of the society. “I am sure that the next years will be even better,” she said.

Speeches given by the authorities: economic-social development and women in science

The ceremony, which lasted a little over an hour, also included the words of Unicamp authorities (the vice-chancellor, Prof. Teresa Dib Zambon Atvars, and the director of the IFGW-Unicamp, Prof. Pascoal José Giglio Pagliuso) and the representatives of several entities:  Brigadier Maurício Pazini Brandão, from the Brazilian Ministry of Science, Technology, Innovations and Communications (MCTIC); Prof. Marcia Cristina Bernardes Barbosa, director of the Brazilian Academy of Sciences (ABC); Prof. Carola Dobrigkeit Chinellato, board member of the Brazilian Physics Society (SBF); Prof. Antonio José Roque da Silva, director of the Brazilian National Center for Research in Energy and Materials (CNPEM); Prof. Ronald Cintra Shellard, director of the Brazilian Center for Research in Physics (CBPF), and Elson Longo (CDMF-UFSCar), who was president of B-MRS in the 2004-2005 biennium.

In the brief speeches given, some of the constant subjects were the conquest of spaces by women, the need to unite different individuals and organizations for the survival and advancement of science and technology, and the seriousness and impact of the research developed in Brazilian universities. One of the most discussed subjects was the transformation of scientific knowledge into wealth, not only as a desire or need, but also as a fact of the current Brazilian reality, which can be observed mainly in startups and companies resulting from universities and research centers.

The first speaker was Brigadier Maurício Pazini Brandão, professor at the Technological Institute of Aeronautics (ITA), who participated in the ceremony as regional director of the representative office of MCTIC in São Paulo. In his words, he stressed that the materials research community must go beyond the production of scientific articles. “We want products and innovation with invoices,” he said.

Then, the vice-chancellor of Unicamp returned to the question raised by Brandão, with some data on companies founded by former students of that university. Together, these “daughter companies” have an annual turnover of R$ 7.9 million, equivalent to three times the annual budget of Unicamp, informed Professor Atvars, who ended the brief speech highlighting the achievements of women, often obtained by means of “triple shift work.” More examples of companies and innovations from the academic world, in the area of ceramic tiles and cosmetic products, were presented later in the speech by Professor Elson Longo.

Professor Pascoal José Giglio Pagliuso spoke about Professor Mônica Cotta, his colleague at the teaching staff and the IFGW board, where she is the associate director. The IFGW director described the new B-MRS president as tireless, vigilant, with a huge heart and a prominent position in matters involving minorities and human rights. “She is the first woman and the first professor at Unicamp to occupy this impactful position in Brazilian research,” he highlighted.

Afterwards, Marcia Barbosa, professor at UFRGS and director at ABC, took up the issue of transforming knowledge into wealth and affirmed that basic science does in fact generate development. A scientist with outstanding performance in favor of the participation of women in the exact sciences, Barbosa said she was concerned with the present times and called on the scientific community to all work “together.” “The new B-MRS board will know how to build windmills to transform the energy of tsunami and gather together other entities,”she said. Work in partnership was also highlighted in the words of Professor Carola Dobrigkeit Chinellato (Unicamp), who hoped that the new board will make new bonds and extend the scope of B-MRS.

In the penultimate speech of the ceremony, Antonio José Roque da Silva, who directs Sirius (construction of the new Brazilian synchrotron light source), commented on the budgetary difficulties he has faced to carry out the project, sometimes linked to the difficulty of politicians and society in general in understanding the times and actors involved in scientific research and its transformation into social development and wealth. “We need to better explain this time scale,” he urged.

Concluding the speches, Ronald Cintra Shellard brought some data that show the imbalance, in Brazil, between the research carried out in the universities (where there is more freedom to choose a theme) and in the research institutes (in which the scientific work aims to fulfill a determined mission). The ratio of university/institute researchers, which in the world ranges from 1/1 to 4/1, in Brazil it is 12/1, said the director of CBPF. According to the scientist, this does not reflect an excess of professionals at the university, but a lack of researchers in the country, particularly in research institutes.

B-MRS Newsletter. Year 7, issue 1.

 

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Newsletter of the
Brazilian Materials
Research Society

Year 7, issue 1. February 7, 2020.

B-MRS News

Swearing in of the new B-MRS board. The members of the new B-MRS Executive Board, chaired by Professor Mônica Cotta, will take office on February 14 in a ceremony open to the public, which will be held in the auditorium of the Physics Institute Gleb Wataghin (Unicamp). Know more.

Featured Paper

A Brazilian scientific team made an important contribution to the development of solid electrolytes for lithium-ion batteries, which are safer than liquid or gel electrolytes that are currently widely used. The researchers have developed a polymer-based material that surpasses all those reported so far in some parameters related to conductivity, which can generate fast-charging batteries. The work was recently published in The Journal of Physical Chemistry Letters. Know more.

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Featured Scientists

Oxides for better and cheaper electronics. Ceramics obtained from polymers that catalyze the conversion of CO2 into methane. A material that enables the use of ethanol in fuel cells. Fibers obtained from an Amazonian plant for bulletproof vests. Learn more about the doctoral dissertations that were awarded the Brazilian Capes Theses Award, and get to know their authors Miguel Boratto, Heloísa de Macedo, Bernardo Sarruf and Fábio Braga. Here.

capes_news

News from B-MRS Members

– Prof. Felipe de Almeida La Porta (UTFPR), B-MRS member, is co-editor of a Springer book on computational-experimental research on materials and biomolecules. Know more.

Community

– B-MRS regrets the death of Antonio Ricardo Droher Rodrigues, leader of the Engineering Division at LNLS/CNPEM. Ricardo Rodrigues was the technical and scientific leader of the design and construction of the two Brazilian synchrotron light sources: UVX (developed in the 1980s and 1990s) and Sirius (fourth generation source developed since 2009, currently in the testing phase). Rodrigues passed away on January 3, 2020, at the age of 68. B-MRS’s Executive Board expresses its regret at the premature departure of this Brazilian scientist who made great contributions to our community. Know more about Ricardo Rodrigues.

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XIX B-MRS Meeting + IUMRS ICEM 2020
(Foz do Iguaçu, Brazil, August 30 – September 3, 2020)

Website: www.sbpmat.org.br/19encontro/

Submissions. Abstract submission is open until April 1st. Guidelines for preparing abstracts are available here.

Symposia. The event comprises 29 thematic symposia. See the list.

Registration. The registration system is open. July 15 is the deadline for early registration (with discount). The fees, which include three lunches, are already on the website. Know more, here.

Exhibitors and sponsors. 12 companies have already confirmed their participation as exhibitors-sponsors of the event. Companies and other organizations interested in participating in the event as exhibitors, sponsors or supporters, can contact Alexandre at comercial@sbpmat.org.br before March 31.

International plenary lectures. Renowned scientists from China, Italy, Japan and USA have already confirmed their presence as speakers at the event. Learn more at the event website.

José Arana Varela Lecture (national plenary lecture). Professor Edson Roberto Leite (LNNano – CNPEM) was chosen by B-MRS to receive this distinction and give a lecture at the event.

Joaquim da Costa Ribeiro Memorial Lecture. The honor goes to Professor Cid Bartolomeu de Araújo (UFPE), who will give the lecture at the event.

Venue. The event will be held at Rafain Palace Hotel and Conventions, located in Foz do Iguaçu (Brazil). Know more.

Accommodations. See accommodation options from the event official travel agency, here.

Joint event. The event brings together the 19th edition of the B-MRS annual meeting and the 17th edition of the International Conference on Electronic Materials organized every two years by the International Union of Materials Research Societies (IUMRS).

Organization. Professor Gustavo Martini Dalpian (UFABC) is the general coordinator, Carlos Cesar Bof Bufon (LNNANO) is the program coordinator and Flavio Leandro de Souza (UFABC) is the general secretary. At the international committee, the event features scientists from America, Asia, Europe and Oceania. Know more.

Reading tips

– Perovskites, superconductors at room temperature and solid-state electrolytes: materials that are worth keeping an eye on in 2020, according to Nature. Know more.

– 2D future: the two-dimensional technologies that scientists from some of the most renowned laboratories in the world are developing, from graphene nanofibers that store combustible hydrogen, to molybdenum disulfide devices that collect the remains of electromagnetic energy from Wi-Fi and cell phones and transform into usable energy. Know more.

– Scientists are surprised to discover that spherical drops of liquid crystal turn into structures of complex and beautiful shapes when the temperature decreases. This discovery generates advances in fundamental science and opens up possibilities for new materials (Nature). Know more.

Events

World Forum for Women in Science – Brazil 2020 + 4th International Conference for Women in Science without Borders: Energy, Water, Health, Agriculture and Environment for Sustainable Development. Rio de Janeiro, RJ (Brazil). February 10 – 14, 2020. Site.

Pan American Ceramics Congress and Ferroelectrics Meeting of Americas (PACC-FMAs 2020). Panama (Panama). July 19 – 23, 2020. Site.

XVIII International Congress on Rheology. Rio de Janeiro, RJ (Brazil). August 2 – 7, 2020. Site.

XIX B-MRS Meeting + 2020 IUMRS ICEM (International Conference on Electronic Materials). Foz do Iguaçu, PR (Brazil). August 30 – September 3, 2020. Site.

11th International Conference of Microwave Materials and their Applications. Aveiro (Portugal). August 30 – September 2, 2020. Site.

XLI Congresso Brasileiro de Aplicações de Vácuo na Indústria e na Ciência. Foz do Iguaçu, PR (Brazil). October 5 – 7, 2020. Site.

5th International Conference of Surfaces, Coatings and NanoStructured Materials – Americas (NANOSMAT-Americas). Foz do Iguaçu, PR (Brazil). October 7 – 10, 2020. Site.

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You can suggest news, opportunities, events or reading tips in the materials field to be covered by B-MRS Newsletter. Write to comunicacao@sbpmat.org.br.